From 5b9454a1ac6cd04e7f3f9b42774be9a53b34f3a6 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Sun, 22 May 2022 14:20:38 -0600 Subject: [PATCH 01/40] Investigate database lookup --- dev/generate_sqlite_database.py | 76 +++++++++++++++++++++++++++++++++ 1 file changed, 76 insertions(+) create mode 100644 dev/generate_sqlite_database.py diff --git a/dev/generate_sqlite_database.py b/dev/generate_sqlite_database.py new file mode 100644 index 00000000..585ce611 --- /dev/null +++ b/dev/generate_sqlite_database.py @@ -0,0 +1,76 @@ +# -*- coding: utf-8 -*- +"""Chemical Engineering Design Library (ChEDL). Utilities for process modeling. +Copyright (C) 2022, Caleb Bell + +Permission is hereby granted, free of charge, to any person obtaining a copy +of this software and associated documentation files (the "Software"), to deal +in the Software without restriction, including without limitation the rights +to use, copy, modify, merge, publish, distribute, sublicense, and/or sell +copies of the Software, and to permit persons to whom the Software is +furnished to do so, subject to the following conditions: + +The above copyright notice and this permission notice shall be included in all +copies or substantial portions of the Software. + +THE SOFTWARE IS PROVIDED "AS IS", WITHOUT WARRANTY OF ANY KIND, EXPRESS OR +IMPLIED, INCLUDING BUT NOT LIMITED TO THE WARRANTIES OF MERCHANTABILITY, +FITNESS FOR A PARTICULAR PURPOSE AND NONINFRINGEMENT. IN NO EVENT SHALL THE +AUTHORS OR COPYRIGHT HOLDERS BE LIABLE FOR ANY CLAIM, DAMAGES OR OTHER +LIABILITY, WHETHER IN AN ACTION OF CONTRACT, TORT OR OTHERWISE, ARISING FROM, +OUT OF OR IN CONNECTION WITH THE SOFTWARE OR THE USE OR OTHER DEALINGS IN THE +SOFTWARE. +""" + +from thermo import * +from chemicals import * +from chemicals.identifiers import pubchem_db +import pandas as pd +import numpy as np + +try: + Chemical('asdfsdaf') +except: + pass + +props = ['MW', 'Tt', 'Tm', 'Tb', 'Tc', 'Pt', 'Pc', 'Vc', + 'Zc','omega', 'Tflash', 'Tautoignition', 'LFL', 'UFL', + 'Hfs', 'Hfl', 'Hfg', 'S0s', 'S0l', 'S0g', + 'RI', 'Hfus', + 'Dipole', 'logP', 'RG', 'RON', 'MON', 'IGNITION_DELAY'] + +funcs = [MW, Tt, Tm, Tb, Tc, Pt, Pc, Vc, + Zc,omega, T_flash, T_autoignition, LFL, UFL, + Hfs, Hfl, Hfg, S0s, S0l, S0g, + RI, Hfus, + dipole_moment, logP, RG, RON, MON, ignition_delay] +props = [f.__name__ for f in funcs] +CASs = [] +prop_array = [[] for _ in range(len(props))] + +objs = list(pubchem_db.CAS_index.values()) +stuff = [] +hits = 0 +for v in objs: + CAS = v.CASs + CASs.append(CAS) + for i, p in enumerate(props): + if p == 'MW': + lookedup_constant = v.MW + else: + lookedup_constant = funcs[i](CASRN=CAS) + if p == 'RI': + lookedup_constant = lookedup_constant[0] + prop_array[i].append(lookedup_constant) + + + +prop_array_T = np.array(prop_array).T +CASs_ints = [CAS_to_int(i) for i in CASs] +df = pd.DataFrame(prop_array_T, columns=props, index=CASs_ints) +df = df.fillna(value=np.nan).astype(np.float32) +# df.sort_values(by=['logP'], inplace=True) +df.sort_index(inplace=True) + +from sqlalchemy import create_engine +engine = create_engine('sqlite:///../chemicals/Misc/default.sqlite', echo=False) +df.to_sql('constants', con=engine) From 17b163a24c10352389516ff2308809b16d4c1e20 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Sun, 22 May 2022 15:30:49 -0600 Subject: [PATCH 02/40] Better performance --- chemicals/critical.py | 4 ++- chemicals/data_reader.py | 55 ++++++++++++++++++++++++++++++++- dev/generate_sqlite_database.py | 8 +++++ 3 files changed, 65 insertions(+), 2 deletions(-) diff --git a/chemicals/critical.py b/chemicals/critical.py index ec985f23..a1210ae0 100644 --- a/chemicals/critical.py +++ b/chemicals/critical.py @@ -104,7 +104,7 @@ from chemicals import miscdata from chemicals.data_reader import (data_source, list_available_methods_from_df_dict, - register_df_source, + register_df_source, database_constant_lookup, retrieve_any_from_df_dict, retrieve_from_df_dict) from chemicals.utils import ( @@ -405,6 +405,8 @@ def Tc(CASRN, method=None): Estimation Based on Zero, First and Second Order Methods." In Proceedings of the AIChE Spring Meeting, 21, 1996. ''' + val = database_constant_lookup(CASRN, 'Tc') if method is None else None + if val is not None: return val if not _critical_data_loaded: _load_critical_data() if method: return retrieve_from_df_dict(Tc_sources, CASRN, 'Tc', method) diff --git a/chemicals/data_reader.py b/chemicals/data_reader.py index 7ba8f316..b78b0354 100644 --- a/chemicals/data_reader.py +++ b/chemicals/data_reader.py @@ -53,6 +53,7 @@ except: pass from chemicals.identifiers import CAS_to_int +from chemicals.utils import source_path # %% Loading data from local databanks @@ -210,4 +211,56 @@ def list_available_methods_from_df(df, index, keys_by_method): return [method for method, key in keys_by_method.items() if not pd.isnull(df.at[index, key])] else: - return [] \ No newline at end of file + return [] + +### Database + +USE_CONSTANTS_DATABASE = True + +CONSTANT_DATABASE_COLUMNS = ['index', 'MW', 'Tt', 'Tm', 'Tb', 'Tc', 'Pt', 'Pc', 'Vc', + 'Zc','omega', 'Tflash', 'Tautoignition', 'LFL', 'UFL', + 'Hfs', 'Hfl', 'Hfg', 'S0s', 'S0l', 'S0g', + 'RI', 'Hfus', + 'Dipole', 'logP', 'RG', 'RON', 'MON', 'IGNITION_DELAY'] + + +CONSTANT_DATABASE_NAME_TO_IDX = {k: i for i, k in enumerate(CONSTANT_DATABASE_COLUMNS)} +CONSTANTS_CURSOR = None + +DATABASE_CONSTANTS_CACHE = {} +def cached_constant_lookup(CASi, prop): + if CONSTANTS_CURSOR is None: + init_constants_db() + prop_idx = CONSTANT_DATABASE_NAME_TO_IDX[prop] + try: + return DATABASE_CONSTANTS_CACHE[CASi][prop_idx] + except KeyError: + pass + # Fetch and store the whole row + CONSTANTS_CURSOR.execute("SELECT * FROM constants WHERE `index`=?", (str(CASi),)) + result = CONSTANTS_CURSOR.fetchone() + DATABASE_CONSTANTS_CACHE[CASi] = result + if result is not None: + return result[prop_idx] + +def init_constants_db(): + global CONSTANTS_CURSOR + import sqlite3 + conn = sqlite3.connect(path_join(source_path, 'Misc', 'default.sqlite')) + CONSTANTS_CURSOR = conn.cursor() + +def database_constant_lookup(CAS, prop): + if not USE_CONSTANTS_DATABASE: + return None + try: + CASi = CAS_to_int(CAS) + except: + if type(CAS) is not int: + return None + else: + # Was already an int + CASi = CAS + try: + return cached_constant_lookup(CASi, prop) + except: + return None diff --git a/dev/generate_sqlite_database.py b/dev/generate_sqlite_database.py index 585ce611..3ad09968 100644 --- a/dev/generate_sqlite_database.py +++ b/dev/generate_sqlite_database.py @@ -32,6 +32,9 @@ except: pass +# Can't use the database +data_reader.USE_CONSTANTS_DATABASE = False + props = ['MW', 'Tt', 'Tm', 'Tb', 'Tc', 'Pt', 'Pc', 'Vc', 'Zc','omega', 'Tflash', 'Tautoignition', 'LFL', 'UFL', 'Hfs', 'Hfl', 'Hfg', 'S0s', 'S0l', 'S0g', @@ -66,6 +69,11 @@ prop_array_T = np.array(prop_array).T CASs_ints = [CAS_to_int(i) for i in CASs] + +# Would not be good if there were multiple values +assert len(CASs_ints) == len(set(CASs_ints)) + + df = pd.DataFrame(prop_array_T, columns=props, index=CASs_ints) df = df.fillna(value=np.nan).astype(np.float32) # df.sort_values(by=['logP'], inplace=True) From 85e36a6b449bac4987074e419a27e541fcc09f88 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Sun, 22 May 2022 15:36:54 -0600 Subject: [PATCH 03/40] Allow to not load data by saying if in db or not --- chemicals/critical.py | 4 ++-- chemicals/data_reader.py | 13 ++++++++----- 2 files changed, 10 insertions(+), 7 deletions(-) diff --git a/chemicals/critical.py b/chemicals/critical.py index a1210ae0..06f4ae3d 100644 --- a/chemicals/critical.py +++ b/chemicals/critical.py @@ -405,8 +405,8 @@ def Tc(CASRN, method=None): Estimation Based on Zero, First and Second Order Methods." In Proceedings of the AIChE Spring Meeting, 21, 1996. ''' - val = database_constant_lookup(CASRN, 'Tc') if method is None else None - if val is not None: return val + val, found = database_constant_lookup(CASRN, 'Tc') if method is None else (None, False) + if found: return val if not _critical_data_loaded: _load_critical_data() if method: return retrieve_from_df_dict(Tc_sources, CASRN, 'Tc', method) diff --git a/chemicals/data_reader.py b/chemicals/data_reader.py index b78b0354..7346503c 100644 --- a/chemicals/data_reader.py +++ b/chemicals/data_reader.py @@ -233,7 +233,7 @@ def cached_constant_lookup(CASi, prop): init_constants_db() prop_idx = CONSTANT_DATABASE_NAME_TO_IDX[prop] try: - return DATABASE_CONSTANTS_CACHE[CASi][prop_idx] + return DATABASE_CONSTANTS_CACHE[CASi][prop_idx], True except KeyError: pass # Fetch and store the whole row @@ -241,7 +241,10 @@ def cached_constant_lookup(CASi, prop): result = CONSTANTS_CURSOR.fetchone() DATABASE_CONSTANTS_CACHE[CASi] = result if result is not None: - return result[prop_idx] + return result[prop_idx], True + + # Result the value, and whether the compound was in the index + return result, False def init_constants_db(): global CONSTANTS_CURSOR @@ -251,16 +254,16 @@ def init_constants_db(): def database_constant_lookup(CAS, prop): if not USE_CONSTANTS_DATABASE: - return None + return None, False try: CASi = CAS_to_int(CAS) except: if type(CAS) is not int: - return None + return None, False else: # Was already an int CASi = CAS try: return cached_constant_lookup(CASi, prop) except: - return None + return None, False From 5fa5e6d51bfdb62243762c7f269f0005b686313c Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Sun, 22 May 2022 18:53:55 -0600 Subject: [PATCH 04/40] There is a bug with critical pressure --- chemicals/Critical Properties/IUPACOrganicCriticalProps.tsv | 2 +- chemicals/critical.py | 6 ++++++ chemicals/data_reader.py | 5 +++-- dev/generate_sqlite_database.py | 4 ++++ 4 files changed, 14 insertions(+), 3 deletions(-) diff --git a/chemicals/Critical Properties/IUPACOrganicCriticalProps.tsv b/chemicals/Critical Properties/IUPACOrganicCriticalProps.tsv index ca45534a..dc6f6df4 100644 --- a/chemicals/Critical Properties/IUPACOrganicCriticalProps.tsv +++ b/chemicals/Critical Properties/IUPACOrganicCriticalProps.tsv @@ -478,7 +478,7 @@ CAS Chemical MW Tc Pc Vc Zc Reference 462-95-3 diethoxymethane 104.149 531.7 7 463-49-0 propadiene 40.065 394 5250000 6 463-82-1 2,2-dimethylpropane 72.15 433.8 3196000 0.0003070 0.272 5 -0464-06-02 2,2,3-trimethylbutane 100.204 531.1 2950000 0.0003980 0.265 5 +464-06-02 2,2,3-trimethylbutane 100.204 531.1 2950000 0.0003980 0.265 5 493-01-6 cis-bicyclo[4.4.0]decane 138.253 703.6 3200000 5 493-02-7 trans-bicyclo[4.4.0]decane 138.253 687 5 496-11-7 indan 118.178 684.9 3950000 3 diff --git a/chemicals/critical.py b/chemicals/critical.py index 06f4ae3d..d21fde31 100644 --- a/chemicals/critical.py +++ b/chemicals/critical.py @@ -583,6 +583,8 @@ def Pc(CASRN, method=None): Estimation Based on Zero, First and Second Order Methods." In Proceedings of the AIChE Spring Meeting, 21, 1996. ''' + val, found = database_constant_lookup(CASRN, 'Pc') if method is None else (None, False) + if found: return val if not _critical_data_loaded: _load_critical_data() if method: return retrieve_from_df_dict(Pc_sources, CASRN, 'Pc', method) @@ -753,6 +755,8 @@ def Vc(CASRN, method=None): .. [20] Fedors, R. F. "A Method to Estimate Critical Volumes." AIChE Journal 25, no. 1 (1979): 202-202. https://doi.org/10.1002/aic.690250129. ''' + val, found = database_constant_lookup(CASRN, 'Vc') if method is None else (None, False) + if found: return val if not _critical_data_loaded: _load_critical_data() if method: return retrieve_from_df_dict(Vc_sources, CASRN, 'Vc', method) @@ -920,6 +924,8 @@ def Zc(CASRN, method=None): Tc-PR." AIChE Journal n/a, no. n/a (n.d.): e17518. https://doi.org/10.1002/aic.17518. ''' + val, found = database_constant_lookup(CASRN, 'Zc') if method is None else (None, False) + if found: return val if not _critical_data_loaded: _load_critical_data() if method: return retrieve_from_df_dict(Zc_sources, CASRN, 'Zc', method) diff --git a/chemicals/data_reader.py b/chemicals/data_reader.py index 7346503c..c9862838 100644 --- a/chemicals/data_reader.py +++ b/chemicals/data_reader.py @@ -112,11 +112,12 @@ def load_df(key): example https://commonchemistry.cas.org/detail?cas_rn=2222298-66-8 or 2627558-64-7 - The maximum value of an unsigned integer is 4294967295. + The maximum value of an unsigned 32 bit integer is 4294967295. + For 64 bit it is 18446744073709551615. It would be possible to remove the check digit of the CAS number, which would allow all 10-digit current CAS format integers to fit - into an unsigned integer. + into an unsigned 32 bit integer. https://www.cas.org/support/documentation/chemical-substances/faqs CAS says they are only "up to ten digits". However, before 2008 all CAS numbers were "up to nine digits"; and they are already 25% of the diff --git a/dev/generate_sqlite_database.py b/dev/generate_sqlite_database.py index 3ad09968..20f5bcdc 100644 --- a/dev/generate_sqlite_database.py +++ b/dev/generate_sqlite_database.py @@ -23,8 +23,10 @@ from thermo import * from chemicals import * +from chemicals import data_reader from chemicals.identifiers import pubchem_db import pandas as pd +import os import numpy as np try: @@ -81,4 +83,6 @@ from sqlalchemy import create_engine engine = create_engine('sqlite:///../chemicals/Misc/default.sqlite', echo=False) +if os.path.exists("../chemicals/Misc/default.sqlite"): + os.remove("../chemicals/Misc/default.sqlite") df.to_sql('constants', con=engine) From 6573f428dee1756b0c3641e44d9867661d10697c Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Sun, 22 May 2022 18:58:37 -0600 Subject: [PATCH 05/40] . --- dev/generate_sqlite_database.py | 4 +++- 1 file changed, 3 insertions(+), 1 deletion(-) diff --git a/dev/generate_sqlite_database.py b/dev/generate_sqlite_database.py index 20f5bcdc..25f3e481 100644 --- a/dev/generate_sqlite_database.py +++ b/dev/generate_sqlite_database.py @@ -77,7 +77,9 @@ df = pd.DataFrame(prop_array_T, columns=props, index=CASs_ints) -df = df.fillna(value=np.nan).astype(np.float32) + +# Does not save memory except when compressed and causes many test failures +#df = df.fillna(value=np.nan).astype(np.float32) # df.sort_values(by=['logP'], inplace=True) df.sort_index(inplace=True) From 1a1dffc155fa74486186c3cda514e6668c1f0e75 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 09:42:01 -0600 Subject: [PATCH 06/40] Add one more check to CASs --- .../Critical Properties/IUPACOrganicCriticalProps.tsv | 2 +- ...libakhshi one-coefficient enthalpy of vaporization.tsv | 6 +++--- chemicals/identifiers.py | 2 ++ tests/test_critical.py | 8 +++++--- 4 files changed, 11 insertions(+), 7 deletions(-) diff --git a/chemicals/Critical Properties/IUPACOrganicCriticalProps.tsv b/chemicals/Critical Properties/IUPACOrganicCriticalProps.tsv index dc6f6df4..9e5d25fc 100644 --- a/chemicals/Critical Properties/IUPACOrganicCriticalProps.tsv +++ b/chemicals/Critical Properties/IUPACOrganicCriticalProps.tsv @@ -781,7 +781,7 @@ CAS Chemical MW Tc Pc Vc Zc Reference 52447-22-0 tridecafluoroheptanoyl chloride 382.507 519.8 1450000 0.0006520 0.219 11 53772-78-4 difluoro-bis(trifluoromethoxy)methane 220.018 372.4 2330000 0.0003610 0.271 11 54822-22-9 2,2,3,3,4,4,5,5-octafluoropentanoic acid methyl ester 260.082 559 2320000 0.0005020 0.251 11 -56567-3 2-methyl-3-pentanol 102.177 576 3460000 4 +565-67-3 2-methyl-3-pentanol 102.177 576 3460000 4 56860-81-2 3-difluoromethoxy-1,1,1,2,2-pentafluoropropane 200.055 455.1 2773000 0.0003470 0.255 11 57041-67-5 1,1,1,2-tetrafluoro-2-(difluoromethoxy)ethane 168.038 428.9 3042000 0.0003150 0.269 11 59426-77-6 1,1,1,2,2,3,3-heptafluoro-3-(trifluoromethoxy)propane 254.026 391.7 1870000 0.0004030 0.232 11 diff --git a/chemicals/Phase Change/Alibakhshi one-coefficient enthalpy of vaporization.tsv b/chemicals/Phase Change/Alibakhshi one-coefficient enthalpy of vaporization.tsv index 1742feda..32173a7d 100644 --- a/chemicals/Phase Change/Alibakhshi one-coefficient enthalpy of vaporization.tsv +++ b/chemicals/Phase Change/Alibakhshi one-coefficient enthalpy of vaporization.tsv @@ -1860,7 +1860,7 @@ CAS Chemical C 2550-06-3 3-chloropropyltrichlorosilane -9.9532 2690-08-6 di-n-octyl sulfide 14.1556 2768-02-7 vinyltrimethoxysilane -1.3664 -354381 2-ethyl-m-xylene -11.3303 +2870-04-4 2-ethyl-m-xylene -11.3303 2884-06-2 2,3-dimethylnonane -5.9718 2998-08-5 sec-butyl acrylate -6.0883 3228-02-2 1-methyl-3-hydroxy-6-isopropyl benzene 0.5831 @@ -1868,7 +1868,7 @@ CAS Chemical C 3452-07-1 1-eicosene 11.4798 3452-09-3 1-nonyne -5.911 3454-07-7 p-ethylstyrene -10.7628 -735273 2-butyl-octan-1-ol 25.3024 +3913-02-8 2-butyl-octan-1-ol 25.3024 4038-04-4 3-ethyl-1-pentene -17.1925 857237-25-3 2-(alpha-methylbenzyloxy)-1-propanol 4.4764 871518-84-2 propylene glycol alpha-methylbenzyl ether 3.7714 @@ -1878,7 +1878,7 @@ CAS Chemical C 1243297-10-0 1-tert-butoxy-2-[2-(tert-butoxy)propoxy]propane 2.9151 5911-04-6 3-methylnonane -6.7824 6094-02-6 2-methyl-1-hexene -16.6413 -1766990 sec-butenyl acetate -9.1697 +6737-11-7 sec-butenyl acetate -9.1697 7058-01-7 sec-butylcyclohexane -13.7287 7440-09-7 potassium -48.1091 7446-09-5 sulfur dioxide -20.2358 diff --git a/chemicals/identifiers.py b/chemicals/identifiers.py index fad4abb7..b82e825e 100644 --- a/chemicals/identifiers.py +++ b/chemicals/identifiers.py @@ -115,6 +115,8 @@ def check_CAS(CASRN): >>> check_CAS('77332-18-5') False """ + if CASRN.count('-') != 2: + return False try: check = CASRN[-1] # Don't store the int - it is not necessary and is slower diff --git a/tests/test_critical.py b/tests/test_critical.py index 9960980b..c787a5c9 100644 --- a/tests/test_critical.py +++ b/tests/test_critical.py @@ -25,7 +25,7 @@ import pandas as pd from fluids.numerics import assert_close, assert_close1d from chemicals.miscdata import webbook_data -from chemicals import int_to_CAS +from chemicals import int_to_CAS, data_reader from chemicals.critical import * from chemicals.critical import (critical_data_IUPAC, critical_data_Matthews, @@ -35,6 +35,8 @@ critical_data_PassutDanner, critical_data_PinaMartines) +data_reader.USE_CONSTANTS_DATABASE = False + def test_data_IUPAC(): Tc_sum = critical_data_IUPAC['Tc'].sum() assert_close(Tc_sum, 462157.51300000004) @@ -197,7 +199,7 @@ def test_Tc_all_values(): # Use the default method for each chemical in this file Tcs = [Tc(i) for i in CASs] Tcs_default_sum = pd.Series(Tcs).sum() - assert_close(Tcs_default_sum, 6247147.3661222225) + assert_close(Tcs_default_sum, 6246571.366122) def test_Tc(): Tc_val = Tc(CASRN='64-17-5') @@ -254,7 +256,7 @@ def test_Pc_all_values(): # Use the default method for each chemical in this file Pcs = [Pc(i) for i in CASs] Pcs_default_sum = pd.Series(Pcs).sum() - assert_close(Pcs_default_sum, 64608461266.18326) + assert_close(Pcs_default_sum, 64604961266.18326) def test_Vc(): assert_close(0.000168, Vc(CASRN='64-17-5')) From aa1816f87267202895b56af9444b257146da3089 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 09:44:17 -0600 Subject: [PATCH 07/40] Correct one CAS --- chemicals/Safety/DIPPR T_flash Serat.csv | 2 +- tests/test_critical.py | 2 +- 2 files changed, 2 insertions(+), 2 deletions(-) diff --git a/chemicals/Safety/DIPPR T_flash Serat.csv b/chemicals/Safety/DIPPR T_flash Serat.csv index 180270fb..3b5e0e69 100644 --- a/chemicals/Safety/DIPPR T_flash Serat.csv +++ b/chemicals/Safety/DIPPR T_flash Serat.csv @@ -292,7 +292,7 @@ CAS Name T_flash 97-99-4 TETRAHYDROFURFURYL ALCOHOL 343.15 107-18-6 ALLYL ALCOHOL 278.147241546418 617-94-7 2-PHENYL-2-PROPANOL 349.191906811578 -735273 2-BUTYL-OCTAN-1-OL 382.15 +201057-93-4 2-BUTYL-OCTAN-1-OL 382.15 526-75-0 2,3-XYLENOL 368.15 105-67-9 2,4-XYLENOL 355.973792760292 34885-03-5 4-METHYL-CYCLOHEXANE-METHANOL 343.581999775808 diff --git a/tests/test_critical.py b/tests/test_critical.py index c787a5c9..e824849f 100644 --- a/tests/test_critical.py +++ b/tests/test_critical.py @@ -35,7 +35,7 @@ critical_data_PassutDanner, critical_data_PinaMartines) -data_reader.USE_CONSTANTS_DATABASE = False +# data_reader.USE_CONSTANTS_DATABASE = False def test_data_IUPAC(): Tc_sum = critical_data_IUPAC['Tc'].sum() From cd038485323a923e548f21b51e7d8f4675980c00 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 09:53:49 -0600 Subject: [PATCH 08/40] Few more files --- chemicals/Misc/Muller Supporting Info Dipoles.csv | 2 +- chemicals/Misc/Poling Dipole.csv | 2 +- chemicals/Misc/cccbdb.nist.gov Dipoles.csv | 2 +- chemicals/Misc/psi4_dipoles.tsv | 2 +- chemicals/acentric.py | 3 +++ chemicals/combustion.py | 8 +++++++- chemicals/dipole.py | 10 ++++++---- chemicals/phase_change.py | 6 +++++- dev/predictions/generate_psi4_files.py | 4 ++-- tests/test_dipole.py | 6 +++--- 10 files changed, 30 insertions(+), 15 deletions(-) diff --git a/chemicals/Misc/Muller Supporting Info Dipoles.csv b/chemicals/Misc/Muller Supporting Info Dipoles.csv index 11a3fae1..9ae9b2f7 100644 --- a/chemicals/Misc/Muller Supporting Info Dipoles.csv +++ b/chemicals/Misc/Muller Supporting Info Dipoles.csv @@ -1,4 +1,4 @@ -CAS Chemical Dipole +CAS Chemical dipole_moment 56-81-5 glycerol 4.21 57-55-6 1,2-propanediol 3.62988811742274 60-12-8 2-phenylethanol 1.65 diff --git a/chemicals/Misc/Poling Dipole.csv b/chemicals/Misc/Poling Dipole.csv index d546605d..f7ebe0d8 100644 --- a/chemicals/Misc/Poling Dipole.csv +++ b/chemicals/Misc/Poling Dipole.csv @@ -1,4 +1,4 @@ -CAS Chemical Dipole +CAS Chemical dipole_moment 56-23-5 tetrachloromethane 0 60-29-7 diethyl ether 1.3 62-53-3 benzeneamine (aniline) 1.6 diff --git a/chemicals/Misc/cccbdb.nist.gov Dipoles.csv b/chemicals/Misc/cccbdb.nist.gov Dipoles.csv index db7d6fd2..f45269c1 100644 --- a/chemicals/Misc/cccbdb.nist.gov Dipoles.csv +++ b/chemicals/Misc/cccbdb.nist.gov Dipoles.csv @@ -1,4 +1,4 @@ -CAS Chemical Dipole +CAS Chemical dipole_moment -20-4 Methane selenol 1.29 -2-2 Ammonia Dimer 1.99 50-00-0 Formaldehyde 2.33 diff --git a/chemicals/Misc/psi4_dipoles.tsv b/chemicals/Misc/psi4_dipoles.tsv index 72d9bbb9..536b0845 100644 --- a/chemicals/Misc/psi4_dipoles.tsv +++ b/chemicals/Misc/psi4_dipoles.tsv @@ -1,4 +1,4 @@ -CAS Dipole +CAS dipole_moment 24304-00-5 2.939 22831-39-6 1.5712 10049-06-6 0.7316 diff --git a/chemicals/acentric.py b/chemicals/acentric.py index 92e2df50..e1a05cbd 100644 --- a/chemicals/acentric.py +++ b/chemicals/acentric.py @@ -53,6 +53,7 @@ from chemicals import critical from chemicals.data_reader import (list_available_methods_from_df_dict, + database_constant_lookup, retrieve_any_from_df_dict, retrieve_from_df_dict) from chemicals.utils import log, log10, mark_numba_incompatible @@ -149,6 +150,8 @@ def omega(CASRN, method=None): Hydrocarbons, Second Edition. Amsterdam Boston: Gulf Professional Publishing, 2014. ''' + val, found = database_constant_lookup(CASRN, 'omega') if method is None else (None, False) + if found: return val if method: return retrieve_from_df_dict(critical.omega_sources, CASRN, 'omega', method) else: diff --git a/chemicals/combustion.py b/chemicals/combustion.py index 98ac1e2b..481a3bd4 100644 --- a/chemicals/combustion.py +++ b/chemicals/combustion.py @@ -76,7 +76,7 @@ from fluids.numerics import normalize -from chemicals.data_reader import (data_source, +from chemicals.data_reader import (data_source, database_constant_lookup, list_available_methods_from_df_dict, register_df_source, retrieve_any_from_df_dict, @@ -260,6 +260,8 @@ def RON(CASRN, method=None): Learning Projects for Fuel Property Prediction." Journal of Open Source Software 2, no. 17 (2017): 401. ''' + val, found = database_constant_lookup(CASRN, 'RON') if method is None else (None, False) + if found: return val if not _combustion_data_loaded: _load_combustion_data() if method: value = retrieve_from_df_dict(RON_sources, CASRN, 'RON', method) @@ -352,6 +354,8 @@ def MON(CASRN, method=None): Learning Projects for Fuel Property Prediction." Journal of Open Source Software 2, no. 17 (2017): 401. ''' + val, found = database_constant_lookup(CASRN, 'MON') if method is None else (None, False) + if found: return val if not _combustion_data_loaded: _load_combustion_data() if method: value = retrieve_from_df_dict(MON_sources, CASRN, 'MON', method) @@ -383,6 +387,8 @@ def ignition_delay_methods(CASRN): -------- ignition_delay """ + val, found = database_constant_lookup(CASRN, 'IGNITION_DELAY') if method is None else (None, False) + if found: return val if not _combustion_data_loaded: _load_combustion_data() return list_available_methods_from_df_dict(ignition_delay_sources, CASRN, 'IGNITION_DELAY') diff --git a/chemicals/dipole.py b/chemicals/dipole.py index c7a555f9..db58058c 100644 --- a/chemicals/dipole.py +++ b/chemicals/dipole.py @@ -39,7 +39,7 @@ 'dipole_moment_methods', 'dipole_moment_all_methods'] -from chemicals.data_reader import (data_source, +from chemicals.data_reader import (data_source, database_constant_lookup, list_available_methods_from_df_dict, register_df_source, retrieve_any_from_df_dict, @@ -113,7 +113,7 @@ def dipole_moment_methods(CASRN): dipole_moment """ if not _dipole_data_loaded: _load_dipole_data() - return list_available_methods_from_df_dict(dipole_sources, CASRN, 'Dipole') + return list_available_methods_from_df_dict(dipole_sources, CASRN, 'dipole_moment') @mark_numba_incompatible def dipole_moment(CASRN, method=None): @@ -186,8 +186,10 @@ def dipole_moment(CASRN, method=None): Program." WIREs Computational Molecular Science 2, no. 4 (2012): 556-65. https://doi.org/10.1002/wcms.93. ''' + val, found = database_constant_lookup(CASRN, 'dipole_moment') if method is None else (None, False) + if found: return val if not _dipole_data_loaded: _load_dipole_data() if method: - return retrieve_from_df_dict(dipole_sources, CASRN, 'Dipole', method) + return retrieve_from_df_dict(dipole_sources, CASRN, 'dipole_moment', method) else: - return retrieve_any_from_df_dict(dipole_sources, CASRN, 'Dipole') + return retrieve_any_from_df_dict(dipole_sources, CASRN, 'dipole_moment') diff --git a/chemicals/phase_change.py b/chemicals/phase_change.py index 80189b47..203cd195 100644 --- a/chemicals/phase_change.py +++ b/chemicals/phase_change.py @@ -138,7 +138,7 @@ from fluids.numerics import numpy as np from chemicals import miscdata -from chemicals.data_reader import (data_source, +from chemicals.data_reader import (data_source, database_constant_lookup, list_available_methods_from_df_dict, register_df_source, retrieve_any_from_df_dict, @@ -339,6 +339,8 @@ def Tb(CASRN, method=None): .. [6] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' + val, found = database_constant_lookup(CASRN, 'Tb') if method is None else (None, False) + if found: return val if not _phase_change_const_loaded: _load_phase_change_constants() if method: return retrieve_from_df_dict(Tb_sources, CASRN, 'Tb', method) @@ -441,6 +443,8 @@ def Tm(CASRN, method=None): .. [6] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' + val, found = database_constant_lookup(CASRN, 'Tm') if method is None else (None, False) + if found: return val if not _phase_change_const_loaded: _load_phase_change_constants() if method: return retrieve_from_df_dict(Tm_sources, CASRN, 'Tm', method) diff --git a/dev/predictions/generate_psi4_files.py b/dev/predictions/generate_psi4_files.py index e63b56bd..9aed57fc 100644 --- a/dev/predictions/generate_psi4_files.py +++ b/dev/predictions/generate_psi4_files.py @@ -205,8 +205,8 @@ def get_data(f): def write_dipole_file(): - dump_oder = ['Dipole',] - keys = ['CAS', 'Dipole'] + dump_oder = ['dipole_moment',] + keys = ['CAS', 'dipole_moment'] lines = ['\t'.join(keys) + '\n'] for CAS, dipole in dipoles.items(): values = [dipole] diff --git a/tests/test_dipole.py b/tests/test_dipole.py index 7e4a7979..bea1ce9d 100644 --- a/tests/test_dipole.py +++ b/tests/test_dipole.py @@ -29,13 +29,13 @@ def test_dipole_moment_methods(): - tot = dipole.dipole_data_Poling['Dipole'].sum() + tot = dipole.dipole_data_Poling['dipole_moment'].sum() assert_close(tot, 248.59999999999999) - tot = dipole.dipole_data_CCDB['Dipole'].sum() + tot = dipole.dipole_data_CCDB['dipole_moment'].sum() assert_close(tot, 632.97000000000003) - tot = dipole.dipole_data_Muller['Dipole'].sum() + tot = dipole.dipole_data_Muller['dipole_moment'].sum() assert_close(tot, 420.05190108045235) def test_dipole(): From b65ecde19cab78286f2cfe588c14755644c21c08 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 10:07:32 -0600 Subject: [PATCH 09/40] More data --- chemicals/Viscosity/MagalhaesLJ.tsv | 2 +- chemicals/Viscosity/PolingLJ.tsv | 2 +- chemicals/__init__.py | 2 +- chemicals/data_reader.py | 9 +++++---- chemicals/environment.py | 4 +++- chemicals/lennard_jones.py | 12 ++++++------ dev/generate_sqlite_database.py | 7 +------ tests/test_lennard_jones.py | 8 ++++---- 8 files changed, 22 insertions(+), 24 deletions(-) diff --git a/chemicals/Viscosity/MagalhaesLJ.tsv b/chemicals/Viscosity/MagalhaesLJ.tsv index f7721c8a..f5488f4b 100644 --- a/chemicals/Viscosity/MagalhaesLJ.tsv +++ b/chemicals/Viscosity/MagalhaesLJ.tsv @@ -1,4 +1,4 @@ -CASRN Chemical sigma epsilon +CASRN Chemical molecular_diameter Stockmayer 50-99-7 Glucose 5.56833 584.37 56-23-5 Carbon tetrachloride 5.2924 418.84 56-40-6 Glycine 5.51083 790.25 diff --git a/chemicals/Viscosity/PolingLJ.tsv b/chemicals/Viscosity/PolingLJ.tsv index 06aff99e..04b29f6d 100644 --- a/chemicals/Viscosity/PolingLJ.tsv +++ b/chemicals/Viscosity/PolingLJ.tsv @@ -1,4 +1,4 @@ -CASRN Formula Name sigma epsilon +CASRN Formula Name molecular_diameter Stockmayer 56-23-5 CCl4 Carbon tetrachloride 5.947 322.7 60-29-7 C2H5OC2H5 Ethyl ether 5.678 313.8 64-17-5 C2H5OH Ethanol 4.53 362.6 diff --git a/chemicals/__init__.py b/chemicals/__init__.py index 31df6bca..83383e90 100644 --- a/chemicals/__init__.py +++ b/chemicals/__init__.py @@ -173,7 +173,7 @@ def constant_statistics(): properties = ['Tt', 'Pt', 'Tm', 'Tb', 'Tc', 'Pc', 'Vc', 'Zc', 'omega', 'T_flash', 'T_autoignition', 'LFL', 'UFL', 'Hfs', 'Hfl', 'Hfg', 'S0s', 'S0l', 'S0g', - 'RI', 'Hfus', + 'RI', 'Hfus', 'Stockmayer', 'molecular_diameter' 'Dipole', 'logP', 'RG', 'RON', 'MON', 'IGNITION_DELAY'] for df in data_reader.df_sources.values(): for p in properties: diff --git a/chemicals/data_reader.py b/chemicals/data_reader.py index c9862838..05928ef2 100644 --- a/chemicals/data_reader.py +++ b/chemicals/data_reader.py @@ -219,10 +219,11 @@ def list_available_methods_from_df(df, index, keys_by_method): USE_CONSTANTS_DATABASE = True CONSTANT_DATABASE_COLUMNS = ['index', 'MW', 'Tt', 'Tm', 'Tb', 'Tc', 'Pt', 'Pc', 'Vc', - 'Zc','omega', 'Tflash', 'Tautoignition', 'LFL', 'UFL', - 'Hfs', 'Hfl', 'Hfg', 'S0s', 'S0l', 'S0g', - 'RI', 'Hfus', - 'Dipole', 'logP', 'RG', 'RON', 'MON', 'IGNITION_DELAY'] +'Zc', 'omega', 'T_flash', 'T_autoignition', 'LFL', 'UFL', +'Hfs', 'Hfl', 'Hfg', 'S0s', 'S0l', 'S0g', +'RI', 'Hfus', 'Stockmayer', 'molecular_diameter', +'dipole_moment', 'logP', 'RG', 'RON', 'MON', 'ignition_delay'] + CONSTANT_DATABASE_NAME_TO_IDX = {k: i for i, k in enumerate(CONSTANT_DATABASE_COLUMNS)} diff --git a/chemicals/environment.py b/chemicals/environment.py index abfedfdb..9a05db95 100644 --- a/chemicals/environment.py +++ b/chemicals/environment.py @@ -56,7 +56,7 @@ 'GWP_methods', 'ODP_methods', 'logP_methods'] from chemicals import miscdata from chemicals.data_reader import ( - data_source, list_available_methods_from_df, + data_source, list_available_methods_from_df, database_constant_lookup, list_available_methods_from_df_dict, register_df_source, retrieve_any_from_df, retrieve_any_from_df_dict, retrieve_from_df, retrieve_from_df_dict) @@ -444,6 +444,8 @@ def logP(CASRN, method=None): .. [2] Haynes, W.M., Thomas J. Bruno, and David R. Lide. CRC Handbook of Chemistry and Physics, 95E. Boca Raton, FL: CRC press, 2014. ''' + val, found = database_constant_lookup(CASRN, 'logP') if method is None else (None, False) + if found: return val if not _logP_data_loaded: _load_logP_data() if method: return retrieve_from_df_dict(logP_sources, CASRN, 'logP', method) diff --git a/chemicals/lennard_jones.py b/chemicals/lennard_jones.py index 816b3e82..6a1716b7 100644 --- a/chemicals/lennard_jones.py +++ b/chemicals/lennard_jones.py @@ -176,7 +176,7 @@ def Stockmayer_methods(CASRN=None, Tm=None, Tb=None, Tc=None, Zc=None, omega=Non Stockmayer """ if not _LJ_data_loaded: _load_LJ_data() - methods = list_available_methods_from_df_dict(LJ_sources, CASRN, 'epsilon') + methods = list_available_methods_from_df_dict(LJ_sources, CASRN, 'Stockmayer') if Tc: if omega: methods.append(TEEGOTOSTEWARD2) if Zc: methods.append(STIELTHODOS) @@ -269,9 +269,9 @@ def Stockmayer(CASRN='', Tm=None, Tb=None, Tc=None, Zc=None, omega=None, elif method == TEEGOTOSTEWARD2: return epsilon_Tee_Gotoh_Steward_2(Tc, omega) else: - return retrieve_from_df_dict(LJ_sources, CASRN, 'epsilon', method) + return retrieve_from_df_dict(LJ_sources, CASRN, 'Stockmayer', method) else: - epsilon = retrieve_any_from_df_dict(LJ_sources, CASRN, 'epsilon') + epsilon = retrieve_any_from_df_dict(LJ_sources, CASRN, 'Stockmayer') if epsilon is not None: return epsilon if Tc: if omega: return epsilon_Tee_Gotoh_Steward_2(Tc, omega) @@ -325,7 +325,7 @@ def molecular_diameter_methods(CASRN=None, Tc=None, Pc=None, Vc=None, Zc=None, -------- molecular_diameter """ - methods = list_available_methods_from_df_dict(LJ_sources, CASRN, 'sigma') + methods = list_available_methods_from_df_dict(LJ_sources, CASRN, 'molecular_diameter') if Tc: if Pc: if omega: methods.append(TEEGOTOSTEWARD4) @@ -430,9 +430,9 @@ def molecular_diameter(CASRN=None, Tc=None, Pc=None, Vc=None, Zc=None, omega=Non elif method == TEEGOTOSTEWARD4: return sigma_Tee_Gotoh_Steward_2(Tc, Pc, omega) else: - return retrieve_from_df_dict(LJ_sources, CASRN, 'sigma', method) + return retrieve_from_df_dict(LJ_sources, CASRN, 'molecular_diameter', method) else: - epsilon = retrieve_any_from_df_dict(LJ_sources, CASRN, 'sigma') + epsilon = retrieve_any_from_df_dict(LJ_sources, CASRN, 'molecular_diameter') if epsilon is not None: return epsilon if Tc: if Pc: diff --git a/dev/generate_sqlite_database.py b/dev/generate_sqlite_database.py index 25f3e481..0c524d3e 100644 --- a/dev/generate_sqlite_database.py +++ b/dev/generate_sqlite_database.py @@ -37,16 +37,11 @@ # Can't use the database data_reader.USE_CONSTANTS_DATABASE = False -props = ['MW', 'Tt', 'Tm', 'Tb', 'Tc', 'Pt', 'Pc', 'Vc', - 'Zc','omega', 'Tflash', 'Tautoignition', 'LFL', 'UFL', - 'Hfs', 'Hfl', 'Hfg', 'S0s', 'S0l', 'S0g', - 'RI', 'Hfus', - 'Dipole', 'logP', 'RG', 'RON', 'MON', 'IGNITION_DELAY'] funcs = [MW, Tt, Tm, Tb, Tc, Pt, Pc, Vc, Zc,omega, T_flash, T_autoignition, LFL, UFL, Hfs, Hfl, Hfg, S0s, S0l, S0g, - RI, Hfus, + RI, Hfus, Stockmayer, molecular_diameter, dipole_moment, logP, RG, RON, MON, ignition_delay] props = [f.__name__ for f in funcs] CASs = [] diff --git a/tests/test_lennard_jones.py b/tests/test_lennard_jones.py index 8c52aa7f..5c0e9ee6 100644 --- a/tests/test_lennard_jones.py +++ b/tests/test_lennard_jones.py @@ -33,18 +33,18 @@ def test_LJ_data(): # Two instances of 174899-66-2 were present; # the apparently more common one, [Bmim][CF 3SO 3], was kept. - tot = LJ_data_Magalhaes['epsilon'].abs().sum() + tot = LJ_data_Magalhaes['Stockmayer'].abs().sum() assert_close(tot, 187099.82029999999) - tot = LJ_data_Magalhaes['sigma'].abs().sum() + tot = LJ_data_Magalhaes['molecular_diameter'].abs().sum() assert_close(tot, 1995.8174799999997) assert LJ_data_Magalhaes.shape == (322, 3) - tot = LJ_data_Poling['epsilon'].abs().sum() + tot = LJ_data_Poling['Stockmayer'].abs().sum() assert_close(tot, 24742.620000000003) - tot = LJ_data_Poling['sigma'].abs().sum() + tot = LJ_data_Poling['molecular_diameter'].abs().sum() assert_close(tot, 329.24199999999996) assert LJ_data_Poling.shape == (75, 4) From 7c171ace5c30a04fbfd041a31b0c3a2ef13c1904 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 10:21:39 -0600 Subject: [PATCH 10/40] More of them --- chemicals/__init__.py | 3 ++- chemicals/data_reader.py | 2 +- chemicals/molecular_geometry.py | 6 +++++- chemicals/phase_change.py | 2 ++ chemicals/reaction.py | 14 +++++++++++++- dev/generate_sqlite_database.py | 2 +- 6 files changed, 24 insertions(+), 5 deletions(-) diff --git a/chemicals/__init__.py b/chemicals/__init__.py index 83383e90..377cab9a 100644 --- a/chemicals/__init__.py +++ b/chemicals/__init__.py @@ -174,7 +174,8 @@ def constant_statistics(): 'omega', 'T_flash', 'T_autoignition', 'LFL', 'UFL', 'Hfs', 'Hfl', 'Hfg', 'S0s', 'S0l', 'S0g', 'RI', 'Hfus', 'Stockmayer', 'molecular_diameter' - 'Dipole', 'logP', 'RG', 'RON', 'MON', 'IGNITION_DELAY'] + 'Dipole', 'logP', 'RG', 'RON', 'MON', 'IGNITION_DELAY', + 'linear'] for df in data_reader.df_sources.values(): for p in properties: if p in df.columns: diff --git a/chemicals/data_reader.py b/chemicals/data_reader.py index 05928ef2..239bce20 100644 --- a/chemicals/data_reader.py +++ b/chemicals/data_reader.py @@ -222,7 +222,7 @@ def list_available_methods_from_df(df, index, keys_by_method): 'Zc', 'omega', 'T_flash', 'T_autoignition', 'LFL', 'UFL', 'Hfs', 'Hfl', 'Hfg', 'S0s', 'S0l', 'S0g', 'RI', 'Hfus', 'Stockmayer', 'molecular_diameter', -'dipole_moment', 'logP', 'RG', 'RON', 'MON', 'ignition_delay'] +'dipole_moment', 'logP', 'RG', 'RON', 'MON', 'ignition_delay', 'linear'] diff --git a/chemicals/molecular_geometry.py b/chemicals/molecular_geometry.py index fa6640c2..16335b90 100644 --- a/chemicals/molecular_geometry.py +++ b/chemicals/molecular_geometry.py @@ -44,7 +44,7 @@ from fluids.numerics import horner, interp -from chemicals.data_reader import (data_source, +from chemicals.data_reader import (data_source, database_constant_lookup, list_available_methods_from_df_dict, register_df_source, retrieve_any_from_df_dict, @@ -171,6 +171,8 @@ def RG(CASRN, method=None): .. [2] Kooijman, Harry A., and Ross Taylor. The ChemSep Book. Books on Demand Norderstedt, Germany, 2000. ''' + val, found = database_constant_lookup(CASRN, 'RG') if method is None else (None, False) + if found: return val if not _RG_data_loaded: _load_RG_data() if method: value = retrieve_from_df_dict(RG_sources, CASRN, 'RG', method) @@ -254,6 +256,8 @@ def linear(CASRN, method=None): Program." WIREs Computational Molecular Science 2, no. 4 (2012): 556-65. https://doi.org/10.1002/wcms.93. ''' + val, found = database_constant_lookup(CASRN, 'linear') if method is None else (None, False) + if found: return bool(val) if not _RG_data_loaded: _load_RG_data() if method: value = retrieve_from_df_dict(linear_sources, CASRN, 'linear', method) diff --git a/chemicals/phase_change.py b/chemicals/phase_change.py index 203cd195..7511784c 100644 --- a/chemicals/phase_change.py +++ b/chemicals/phase_change.py @@ -1317,6 +1317,8 @@ def Hfus(CASRN, method=None): .. [4] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' + val, found = database_constant_lookup(CASRN, 'Hfus') if method is None else (None, False) + if found: return val if not _phase_change_const_loaded: _load_phase_change_constants() if method: return retrieve_from_df_dict(Hfus_sources, CASRN, 'Hfus', method) diff --git a/chemicals/reaction.py b/chemicals/reaction.py index c7f8441e..4e49e1a4 100644 --- a/chemicals/reaction.py +++ b/chemicals/reaction.py @@ -87,7 +87,7 @@ 'balance_stoichiometry', 'stoichiometric_matrix'] from chemicals import heat_capacity, miscdata -from chemicals.data_reader import (data_source, +from chemicals.data_reader import (data_source, database_constant_lookup, list_available_methods_from_df_dict, register_df_source, retrieve_any_from_df_dict, @@ -243,6 +243,8 @@ def Hfs(CASRN, method=None): .. [2] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' + val, found = database_constant_lookup(CASRN, 'Hfs') if method is None else (None, False) + if found: return val if not _reaction_data_loaded: _load_reaction_data() if method: return retrieve_from_df_dict(Hfs_sources, CASRN, 'Hfs', method) @@ -327,6 +329,8 @@ def Hfl(CASRN, method=None): .. [3] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' + val, found = database_constant_lookup(CASRN, 'Hfl') if method is None else (None, False) + if found: return val if not _reaction_data_loaded: _load_reaction_data() if method: return retrieve_from_df_dict(Hfl_sources, CASRN, 'Hfl', method) @@ -435,6 +439,8 @@ def Hfg(CASRN, method=None): .. [6] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' + val, found = database_constant_lookup(CASRN, 'Hfg') if method is None else (None, False) + if found: return val if not _reaction_data_loaded: _load_reaction_data() if method: return retrieve_from_df_dict(Hfg_sources, CASRN, 'Hfg', method) @@ -515,6 +521,8 @@ def S0s(CASRN, method=None): .. [2] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' + val, found = database_constant_lookup(CASRN, 'S0s') if method is None else (None, False) + if found: return val if not _reaction_data_loaded: _load_reaction_data() if method: return retrieve_from_df_dict(S0s_sources, CASRN, 'S0s', method) @@ -592,6 +600,8 @@ def S0l(CASRN, method=None): .. [1] Haynes, W.M., Thomas J. Bruno, and David R. Lide. CRC Handbook of Chemistry and Physics. [Boca Raton, FL]: CRC press, 2014. ''' + val, found = database_constant_lookup(CASRN, 'S0l') if method is None else (None, False) + if found: return val if not _reaction_data_loaded: _load_reaction_data() if method: return retrieve_from_df_dict(S0l_sources, CASRN, 'S0l', method) @@ -678,6 +688,8 @@ def S0g(CASRN, method=None): .. [3] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' + val, found = database_constant_lookup(CASRN, 'S0g') if method is None else (None, False) + if found: return val if not _reaction_data_loaded: _load_reaction_data() if method: return retrieve_from_df_dict(S0g_sources, CASRN, 'S0g', method) diff --git a/dev/generate_sqlite_database.py b/dev/generate_sqlite_database.py index 0c524d3e..5f1c9814 100644 --- a/dev/generate_sqlite_database.py +++ b/dev/generate_sqlite_database.py @@ -42,7 +42,7 @@ Zc,omega, T_flash, T_autoignition, LFL, UFL, Hfs, Hfl, Hfg, S0s, S0l, S0g, RI, Hfus, Stockmayer, molecular_diameter, - dipole_moment, logP, RG, RON, MON, ignition_delay] + dipole_moment, logP, RG, RON, MON, ignition_delay, linear] props = [f.__name__ for f in funcs] CASs = [] prop_array = [[] for _ in range(len(props))] From 34849651db319a533a0c5ac7a79356cfdacb02f3 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 10:26:54 -0600 Subject: [PATCH 11/40] Half of safety --- chemicals/refractivity.py | 2 +- chemicals/safety.py | 10 +++++++++- 2 files changed, 10 insertions(+), 2 deletions(-) diff --git a/chemicals/refractivity.py b/chemicals/refractivity.py index 7a850fbe..b646b3ef 100644 --- a/chemicals/refractivity.py +++ b/chemicals/refractivity.py @@ -65,7 +65,7 @@ from fluids.numerics import horner, interp from chemicals import miscdata -from chemicals.data_reader import (data_source, +from chemicals.data_reader import (data_source, database_constant_lookup, list_available_methods_from_df_dict, register_df_source, retrieve_any_from_df_dict, diff --git a/chemicals/safety.py b/chemicals/safety.py index 90ac3413..3e9ce1b5 100644 --- a/chemicals/safety.py +++ b/chemicals/safety.py @@ -135,7 +135,7 @@ from fluids.core import F2K from chemicals import miscdata -from chemicals.data_reader import (data_source, +from chemicals.data_reader import (data_source, database_constant_lookup, list_available_methods_from_df_dict, register_df_source, retrieve_any_from_df_dict, @@ -855,6 +855,8 @@ def T_flash(CASRN, method=None): (October 15, 2017): 52-59. doi:10.1016/j.fluid.2017.06.008. .. [4] Wikidata. Wikidata. Accessed via API. https://www.wikidata.org/ ''' + val, found = database_constant_lookup(CASRN, 'T_flash') if method is None else (None, False) + if found: return val if not _safety_data_loaded: _load_safety_data() if method: return retrieve_from_df_dict(Tflash_sources, CASRN, 'T_flash', method) @@ -938,6 +940,8 @@ def T_autoignition(CASRN, method=None): and of Hazardous. NFPA, 2008. .. [3] Wikidata. Wikidata. Accessed via API. https://www.wikidata.org/ ''' + val, found = database_constant_lookup(CASRN, 'T_autoignition') if method is None else (None, False) + if found: return val if not _safety_data_loaded: _load_safety_data() if method: return retrieve_from_df_dict(Tautoignition_sources, CASRN, 'T_autoignition', method) @@ -1040,6 +1044,8 @@ def LFL(Hc=None, atoms=None, CASRN='', method=None): and of Hazardous. NFPA, 2008. .. [3] Wikidata. Wikidata. Accessed via API. https://www.wikidata.org/ ''' + val, found = database_constant_lookup(CASRN, 'LFL') if method is None else (None, False) + if found: return val if not _safety_data_loaded: _load_safety_data() if not method: LFL = retrieve_any_from_df_dict(LFL_sources, CASRN, 'LFL') @@ -1153,6 +1159,8 @@ def UFL(Hc=None, atoms=None, CASRN='', method=None): and of Hazardous. NFPA, 2008. .. [3] Wikidata. Wikidata. Accessed via API. https://www.wikidata.org/ ''' + val, found = database_constant_lookup(CASRN, 'UFL') if method is None else (None, False) + if found: return val if not _safety_data_loaded: _load_safety_data() if not method: UFL = retrieve_any_from_df_dict(UFL_sources, CASRN, 'UFL') From a1519849f70839ee125604861bccbf43ffc8c992 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 10:28:32 -0600 Subject: [PATCH 12/40] Triple --- chemicals/triple.py | 6 +++++- 1 file changed, 5 insertions(+), 1 deletion(-) diff --git a/chemicals/triple.py b/chemicals/triple.py index 0da0c99a..b5ba284f 100644 --- a/chemicals/triple.py +++ b/chemicals/triple.py @@ -49,7 +49,7 @@ import os from chemicals import miscdata -from chemicals.data_reader import (data_source, +from chemicals.data_reader import (data_source, database_constant_lookup, list_available_methods_from_df_dict, register_df_source, retrieve_any_from_df_dict, @@ -169,6 +169,8 @@ def Tt(CASRN, method=None): .. [2] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' + val, found = database_constant_lookup(CASRN, 'Tt') if method is None else (None, False) + if found: return val if not _triple_data_loaded: _load_triple_data() if method: if method == MELTING: @@ -256,6 +258,8 @@ def Pt(CASRN, method=None): .. [2] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' + val, found = database_constant_lookup(CASRN, 'Pt') if method is None else (None, False) + if found: return val if not _triple_data_loaded: _load_triple_data() if method: return retrieve_from_df_dict(Pt_sources, CASRN, 'Pt', method) From 40262c92e975678323b743a9bdd09d970fc81b83 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 12:57:25 -0600 Subject: [PATCH 13/40] Bug fix --- chemicals/vapor_pressure.py | 2 ++ 1 file changed, 2 insertions(+) diff --git a/chemicals/vapor_pressure.py b/chemicals/vapor_pressure.py index 26425adf..ac5b84f0 100644 --- a/chemicals/vapor_pressure.py +++ b/chemicals/vapor_pressure.py @@ -226,6 +226,8 @@ def load_vapor_pressure_dfs(): global Psat_data_Perrys2_8, Psat_values_Perrys2_8, Psat_data_VDI_PPDS_3, Psat_values_VDI_PPDS_3 global Psat_data_Alcock_elements, Psat_values_Alcock_elements global _vapor_pressure_dfs_loaded + if _vapor_pressure_dfs_loaded: + return # 57463 bytes for df; 13720 bytes for numpy Psat_data_WagnerMcGarry = data_source('Wagner Original McGarry.tsv') From 61b5523c8ada55be56aede6e8c3acc3779f4c702 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 13:24:44 -0600 Subject: [PATCH 14/40] Update wikidata properties --- chemicals/Misc/wikidata_properties.tsv | 16 +++++++++++----- 1 file changed, 11 insertions(+), 5 deletions(-) diff --git a/chemicals/Misc/wikidata_properties.tsv b/chemicals/Misc/wikidata_properties.tsv index 0a84fe64..5b1a3df4 100644 --- a/chemicals/Misc/wikidata_properties.tsv +++ b/chemicals/Misc/wikidata_properties.tsv @@ -480,7 +480,7 @@ CAS Tm Tb Hfus Hvap Hf S0 LFL UFL T_flash T_autoignition RI RIT logP 107-18-6 144.26111 370.05 0.025 0.18 294.26111 651.15 1.4135 0.17 107-19-7 220.92778 387.03889 309.26111 1.4322 -0.38 107-20-0 358.70556 -107-21-1 260.37222 470.92778 50500 0.032 0.153 384.26111 1.4318 +107-21-1 260.37222 470.92778 50500 0.032 0.153 384.26111 1.3811 107-27-7 465.15 107-30-2 169.81667 332.03889 273.15 107-31-3 173.15 304.81667 0.045 0.23 254.26111 @@ -1368,6 +1368,7 @@ CAS Tm Tb Hfus Hvap Hf S0 LFL UFL T_flash T_autoignition RI RIT logP 125-20-2 525.15 125-29-1 471.15 12510-90-6 -14500 +125133-94-0 446.65 125471-00-3 365.15 1256483-00-7 359.15 125650-44-4 508.15 @@ -2397,6 +2398,7 @@ CAS Tm Tb Hfus Hvap Hf S0 LFL UFL T_flash T_autoignition RI RIT logP 1684-14-6 399.15 16842-03-8 247.03889 16851-82-4 362.15 +16853-85-3 -107000 168618-42-6 433.15 16867-03-1 443.15 16869-24-2 323.15 @@ -2880,6 +2882,7 @@ CAS Tm Tb Hfus Hvap Hf S0 LFL UFL T_flash T_autoignition RI RIT logP 19727-83-4 341.15 19728-63-3 371.15 1973-22-4 205.15 +19735-89-8 401.15 1975-50-4 457.15 1975-51-5 427.15 1975-52-6 452.15 @@ -3403,7 +3406,6 @@ CAS Tm Tb Hfus Hvap Hf S0 LFL UFL T_flash T_autoignition RI RIT logP 23056-39-5 326.15 23074-42-2 468.15 23088-23-5 371.15 -2309-07-1 337.15 2309-48-0 372.15 23095-05-8 387.15 23095-31-0 341.15 @@ -3502,6 +3504,7 @@ CAS Tm Tb Hfus Hvap Hf S0 LFL UFL T_flash T_autoignition RI RIT logP 2403-88-5 404.15 24036-52-0 496.15 2404-55-9 429.15 +2406-56-6 1.449 24065-33-6 424.15 24078-21-5 354.15 24083-19-0 301.15 @@ -5585,6 +5588,7 @@ CAS Tm Tb Hfus Hvap Hf S0 LFL UFL T_flash T_autoignition RI RIT logP 4733-39-5 555.15 4742-89-6 442.15 4743-58-2 424.15 +4743-82-2 397.15 474898-23-2 440.15 4755-50-4 418.15 476-66-4 723.15 @@ -7674,6 +7678,7 @@ CAS Tm Tb Hfus Hvap Hf S0 LFL UFL T_flash T_autoignition RI RIT logP 64321-96-6 360.15 64354-45-6 320.65 6436-59-5 328.15 +64365-11-3 3823.15 64372-62-9 332.15 64379-92-6 383.65 6439-91-4 350.15 @@ -8465,7 +8470,7 @@ CAS Tm Tb Hfus Hvap Hf S0 LFL UFL T_flash T_autoignition RI RIT logP 74800-62-7 330.15 7481-89-2 491.15 7487-88-9 1410.15 -1288800 -7487-94-7 549.15 577.15 +7487-94-7 549.15 577.15 -228300 74896-66-5 361.15 749230-37-3 425.15 749230-47-5 456.15 @@ -8647,7 +8652,7 @@ CAS Tm Tb Hfus Hvap Hf S0 LFL UFL T_flash T_autoignition RI RIT logP 7646-78-8 240.15 387.3 7646-79-9 1008.15 1322.15 7646-85-7 563.15 1005.3722 -7647-01-0 243.15 321.15 -605220 +7647-01-0 158.70556 188.15 186.9 7647-14-5 1073.95 1686.15 -234800 72.1 1.544202 7647-17-8 919.15 1568.15 -443000 1.6418 7647-18-9 275.95 413.15 1.59255 @@ -9071,7 +9076,6 @@ CAS Tm Tb Hfus Hvap Hf S0 LFL UFL T_flash T_autoignition RI RIT logP 821-95-4 224.15 822-06-0 205.92778 485.92778 413.15 822-36-6 324.15 -82228-96-4 3823.15 823-22-3 291.15 823-36-9 442.15 823-40-5 378.15 @@ -9303,6 +9307,7 @@ CAS Tm Tb Hfus Hvap Hf S0 LFL UFL T_flash T_autoignition RI RIT logP 870244-34-1 423.15 87031-30-9 422.15 870704-14-6 306.15 +871-33-0 1.4679 871-78-3 447.15 871-83-0 439.9 87120-72-7 319.15 @@ -10051,6 +10056,7 @@ CAS Tm Tb Hfus Hvap Hf S0 LFL UFL T_flash T_autoignition RI RIT logP 99584-85-7 432.15 996-50-9 263.15 99627-05-1 327.15 +997-50-2 1.472 99726-99-5 328.15 99768-12-4 496.15 99769-19-4 409.15 From 664b2bd86334e6a959e5e27d2ea817f335e7f744 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 14:25:12 -0600 Subject: [PATCH 15/40] Switch GWP default value to 20 year given the current climate situation and add GWP and ODP to database --- chemicals/data_reader.py | 3 ++- chemicals/environment.py | 14 +++++++++----- dev/generate_sqlite_database.py | 3 ++- tests/test_environment.py | 2 +- 4 files changed, 14 insertions(+), 8 deletions(-) diff --git a/chemicals/data_reader.py b/chemicals/data_reader.py index 239bce20..73fdbbe5 100644 --- a/chemicals/data_reader.py +++ b/chemicals/data_reader.py @@ -222,7 +222,8 @@ def list_available_methods_from_df(df, index, keys_by_method): 'Zc', 'omega', 'T_flash', 'T_autoignition', 'LFL', 'UFL', 'Hfs', 'Hfl', 'Hfg', 'S0s', 'S0l', 'S0g', 'RI', 'Hfus', 'Stockmayer', 'molecular_diameter', -'dipole_moment', 'logP', 'RG', 'RON', 'MON', 'ignition_delay', 'linear'] +'dipole_moment', 'logP', 'RG', 'RON', 'MON', 'ignition_delay', 'linear', +'GWP', 'ODP'] diff --git a/chemicals/environment.py b/chemicals/environment.py index 9a05db95..6d9cdbfc 100644 --- a/chemicals/environment.py +++ b/chemicals/environment.py @@ -97,14 +97,14 @@ def _load_GWP_ODP_data(): ODP_data = data_source('Ozone Depletion Potentials.tsv') _GWP_ODP_data_loaded = True _IPCC_2007_GWP_keys_by_method = { + IPCC_2007_20YR_GWP: '20yr GWP', IPCC_2007_100YR_GWP : '100yr GWP', IPCC_1995_100YR_GWP: 'SAR 100yr', - IPCC_2007_20YR_GWP: '20yr GWP', IPCC_2007_500YR_GWP: '500yr GWP', } _IPCC_2014_GWP_keys_by_method = { - IPCC_2014_100YR_GWP: '100yr GWP', IPCC_2014_20YR_GWP : '20yr GWP', + IPCC_2014_100YR_GWP: '100yr GWP', } _ODP_keys_by_method = { @@ -183,7 +183,7 @@ def GWP(CASRN, method=None): * IPCC Fourth Assessment Report (AR4) from 2007 [1]_ * IPCC Second Assesment Report or (SAR) from 1995 [1]_ - This function returns the GWP for the 100yr outlook from the AR5 by default. + This function returns the GWP for the 20yr outlook from the AR5 by default. Parameters ---------- @@ -214,10 +214,10 @@ def GWP(CASRN, method=None): Examples -------- - Methane, 100-yr outlook AR5 + Methane, 20-yr outlook AR5 >>> GWP(CASRN='74-82-8') - 28.0 + 84.0 Methane, specifying the default method explicitly (this is recommended the default data source may be updated in the future) @@ -248,6 +248,8 @@ def GWP(CASRN, method=None): Other Weak Atmospheric Absorbers." Reviews of Geophysics 58, no. 3 (2020): e2019RG000691. https://doi.org/10.1029/2019RG000691. ''' + val, found = database_constant_lookup(CASRN, 'GWP') if method is None else (None, False) + if found: return val if not _GWP_ODP_data_loaded: _load_GWP_ODP_data() if method: if method in _IPCC_2014_GWP_keys_by_method: @@ -362,6 +364,8 @@ def ODP(CASRN, method=None): Project-Report No. 52, Geneva, Switzerland, 516 p. https://www.wmo.int/pages/prog/arep/gaw/ozone_2010/documents/Ozone-Assessment-2010-complete.pdf ''' + val, found = database_constant_lookup(CASRN, 'ODP') if method is None else (None, False) + if found: return val if not _GWP_ODP_data_loaded: _load_GWP_ODP_data() if method: key = _ODP_keys_by_method[method] diff --git a/dev/generate_sqlite_database.py b/dev/generate_sqlite_database.py index 5f1c9814..c923f8ed 100644 --- a/dev/generate_sqlite_database.py +++ b/dev/generate_sqlite_database.py @@ -42,7 +42,8 @@ Zc,omega, T_flash, T_autoignition, LFL, UFL, Hfs, Hfl, Hfg, S0s, S0l, S0g, RI, Hfus, Stockmayer, molecular_diameter, - dipole_moment, logP, RG, RON, MON, ignition_delay, linear] + dipole_moment, logP, RG, RON, MON, ignition_delay, linear, + GWP, ODP] props = [f.__name__ for f in funcs] CASs = [] prop_array = [[] for _ in range(len(props))] diff --git a/tests/test_environment.py b/tests/test_environment.py index 9915cffb..fc26e03b 100644 --- a/tests/test_environment.py +++ b/tests/test_environment.py @@ -52,7 +52,7 @@ def test_only_removed_GWPs(): def test_GWP(): GWP1_calc = GWP(CASRN='74-82-8') - assert_close(GWP1_calc, 28.0) # methane 100 year + assert_close(GWP1_calc, 84.0) # methane 20 year GWP2_calc = GWP(CASRN='74-82-8', method='IPCC (1995) 100yr') assert_close(GWP2_calc, 21.0) From 7bda40d0bfeb0299bac5855220c7f7ba6bb5df89 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 14:31:37 -0600 Subject: [PATCH 16/40] Add refractivity table --- chemicals/data_reader.py | 4 ++-- dev/generate_sqlite_database.py | 11 +++++++---- 2 files changed, 9 insertions(+), 6 deletions(-) diff --git a/chemicals/data_reader.py b/chemicals/data_reader.py index 73fdbbe5..826e18ac 100644 --- a/chemicals/data_reader.py +++ b/chemicals/data_reader.py @@ -221,9 +221,9 @@ def list_available_methods_from_df(df, index, keys_by_method): CONSTANT_DATABASE_COLUMNS = ['index', 'MW', 'Tt', 'Tm', 'Tb', 'Tc', 'Pt', 'Pc', 'Vc', 'Zc', 'omega', 'T_flash', 'T_autoignition', 'LFL', 'UFL', 'Hfs', 'Hfl', 'Hfg', 'S0s', 'S0l', 'S0g', -'RI', 'Hfus', 'Stockmayer', 'molecular_diameter', +'Hfus', 'Stockmayer', 'molecular_diameter', 'dipole_moment', 'logP', 'RG', 'RON', 'MON', 'ignition_delay', 'linear', -'GWP', 'ODP'] +'GWP', 'ODP', 'RI', 'RIT'] diff --git a/dev/generate_sqlite_database.py b/dev/generate_sqlite_database.py index c923f8ed..3c10c658 100644 --- a/dev/generate_sqlite_database.py +++ b/dev/generate_sqlite_database.py @@ -36,14 +36,19 @@ # Can't use the database data_reader.USE_CONSTANTS_DATABASE = False +_RI = RI +def RI(CASRN): + return _RI(CAS)[0] +def RIT(CASRN): + return _RI(CAS)[1] funcs = [MW, Tt, Tm, Tb, Tc, Pt, Pc, Vc, Zc,omega, T_flash, T_autoignition, LFL, UFL, Hfs, Hfl, Hfg, S0s, S0l, S0g, - RI, Hfus, Stockmayer, molecular_diameter, + Hfus, Stockmayer, molecular_diameter, dipole_moment, logP, RG, RON, MON, ignition_delay, linear, - GWP, ODP] + GWP, ODP, RI, RIT] props = [f.__name__ for f in funcs] CASs = [] prop_array = [[] for _ in range(len(props))] @@ -59,8 +64,6 @@ lookedup_constant = v.MW else: lookedup_constant = funcs[i](CASRN=CAS) - if p == 'RI': - lookedup_constant = lookedup_constant[0] prop_array[i].append(lookedup_constant) From db83f1c205d842d6c7e4a64c78b1712d814d1a3b Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 14:33:11 -0600 Subject: [PATCH 17/40] Refractivity --- chemicals/refractivity.py | 3 +++ 1 file changed, 3 insertions(+) diff --git a/chemicals/refractivity.py b/chemicals/refractivity.py index b646b3ef..0c9f43a6 100644 --- a/chemicals/refractivity.py +++ b/chemicals/refractivity.py @@ -179,6 +179,9 @@ def RI(CASRN, method=None): Chemistry and Physics, 95E. Boca Raton, FL: CRC press, 2014. .. [2] Wikidata. Wikidata. Accessed via API. https://www.wikidata.org/ ''' + RI, found = database_constant_lookup(CASRN, 'RI') if method is None else (None, False) + RIT, _ = database_constant_lookup(CASRN, 'RIT') if method is None else (None, False) + if found: return (RI, RIT) if not _RI_data_loaded: _load_RI_data() key = ('RI', 'RIT') if method: From d873449d51ff716971d40e56c67745628cd811a4 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 14:35:17 -0600 Subject: [PATCH 18/40] Missed some --- chemicals/lennard_jones.py | 6 +++++- 1 file changed, 5 insertions(+), 1 deletion(-) diff --git a/chemicals/lennard_jones.py b/chemicals/lennard_jones.py index 6a1716b7..3d78a2ae 100644 --- a/chemicals/lennard_jones.py +++ b/chemicals/lennard_jones.py @@ -96,7 +96,7 @@ from fluids.constants import k -from chemicals.data_reader import (data_source, +from chemicals.data_reader import (data_source, database_constant_lookup, list_available_methods_from_df_dict, register_df_source, retrieve_any_from_df_dict, @@ -252,6 +252,8 @@ def Stockmayer(CASRN='', Tm=None, Tb=None, Tc=None, Zc=None, omega=None, Ranges of Temperature and Density." The Journal of Supercritical Fluids 76 (April 2013): 94-114. doi:10.1016/j.supflu.2013.02.002. ''' + val, found = database_constant_lookup(CASRN, 'Stockmayer') if method is None else (None, False) + if found: return val if not _LJ_data_loaded: _load_LJ_data() if method is not None: if method == FLYNN: @@ -409,6 +411,8 @@ def molecular_diameter(CASRN=None, Tc=None, Pc=None, Vc=None, Zc=None, omega=Non Ranges of Temperature and Density." The Journal of Supercritical Fluids 76 (April 2013): 94-114. doi:10.1016/j.supflu.2013.02.002. ''' + val, found = database_constant_lookup(CASRN, 'molecular_diameter') if method is None else (None, False) + if found: return val if not _LJ_data_loaded: _load_LJ_data() if method is not None: if method == FLYNN: From 0fd1463ca40660695f017dfea1a2ff5fccb726b7 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 14:55:22 -0600 Subject: [PATCH 19/40] Look at getting the CAS as an integer read in by pandas --- chemicals/data_reader.py | 7 ++++++- dev/predictions/generate_joback_predictions.py | 5 ++--- 2 files changed, 8 insertions(+), 4 deletions(-) diff --git a/chemicals/data_reader.py b/chemicals/data_reader.py index 826e18ac..416444cc 100644 --- a/chemicals/data_reader.py +++ b/chemicals/data_reader.py @@ -98,6 +98,10 @@ def load_df(key): import pandas as pd folder, name, sep, index_col, csv_kwargs, postload, sparsify, int_CAS = load_cmds[key] path = path_join(folder, name) + # if int_CAS: + # dtype = csv_kwargs.get('dtype', {}) + # dtype['CASRN'] = int64_dtype + # csv_kwargs['dtype'] = dtype df = pd.read_csv(path, sep=sep, index_col=index_col, **csv_kwargs) if postload: postload(df) if sparsify: @@ -107,7 +111,8 @@ def load_df(key): if col_name in spurious_columns: df[col_name] = pd.Series([], dtype=float).astype(pd.SparseDtype("float", nan)) - if int_CAS: + if int_CAS and df.index.dtype is object_dtype: + # If the index is already an int, leave it be '''Most CAS numbers fit in 32 bits. Not all of them do though, for example https://commonchemistry.cas.org/detail?cas_rn=2222298-66-8 or 2627558-64-7 diff --git a/dev/predictions/generate_joback_predictions.py b/dev/predictions/generate_joback_predictions.py index 924cafcb..5810c031 100644 --- a/dev/predictions/generate_joback_predictions.py +++ b/dev/predictions/generate_joback_predictions.py @@ -1,6 +1,6 @@ import os from thermo import Joback -from chemicals.identifiers import pubchem_db +from chemicals.identifiers import pubchem_db, CAS_to_int import rdkit from rdkit import Chem from joblib import Parallel, delayed @@ -16,7 +16,6 @@ lines = ['\t'.join(keys) + '\n'] def generate_line(CASi): chem_info = pubchem_db.CAS_index[CASi] - CAS = chem_info.CASs mol = Chem.MolFromSmiles(chem_info.smiles) if mol is None: # rdkit coult not parse @@ -30,7 +29,7 @@ def generate_line(CASi): return False values = [estimates[k] for k in dump_oder] line = values - line.insert(0, CAS) + line.insert(0, CASi) if estimates['Cpig_coeffs'] is not None: line.extend(estimates['Cpig_coeffs']) else: From 96e268bd8b7fffe6101b0f2a1504abd759fc452c Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 15:00:39 -0600 Subject: [PATCH 20/40] Fix index naming --- chemicals/data_reader.py | 2 +- 1 file changed, 1 insertion(+), 1 deletion(-) diff --git a/chemicals/data_reader.py b/chemicals/data_reader.py index 416444cc..79a07abd 100644 --- a/chemicals/data_reader.py +++ b/chemicals/data_reader.py @@ -131,7 +131,7 @@ def load_df(key): likely be well before that. Therefore, it does not justify removing the check digit. ''' - df.index = pd.Index([CAS_to_int(s) for s in df.index], dtype=int64_dtype) + df.index = pd.Index([CAS_to_int(s) for s in df.index], dtype=int64_dtype, name=df.index.name) df_sources[key] = df From 7a503d27afc3970ff0f89f09f67ec6d15538ce00 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 15:04:24 -0600 Subject: [PATCH 21/40] Start consistenly naming dataframe columns with CAS --- .../Critical Properties/PassutDanner1973.tsv | 2 +- .../Critical Properties/Yaws Collection.tsv | 2 +- chemicals/Environment/CRC logP table.tsv | 2 +- ...fficial Global Warming Potentials 2007.tsv | 2 +- ...fficial Global Warming Potentials 2014.tsv | 2 +- .../Ozone Depletion Potentials.tsv | 2 +- chemicals/Environment/Syrres logP data.csv.gz | Bin 168478 -> 168471 bytes ...sical Constants of Inorganic Compounds.csv | 2 +- ...hysical Constants of Organic Compounds.csv | 2 +- 9 files changed, 8 insertions(+), 8 deletions(-) diff --git a/chemicals/Critical Properties/PassutDanner1973.tsv b/chemicals/Critical Properties/PassutDanner1973.tsv index b2de18ca..c1fe8ff7 100644 --- a/chemicals/Critical Properties/PassutDanner1973.tsv +++ b/chemicals/Critical Properties/PassutDanner1973.tsv @@ -1,4 +1,4 @@ -CASRN Chemical Tc Pc omega +CAS Chemical Tc Pc omega 71-43-2 Benzene 562.161111111111 4898035.58106655 0.21 74-82-8 Methane 190.577777777778 4604318.92037759 0.0072 74-84-0 Ethane 305.422222222222 4880109.21210431 0.0908 diff --git a/chemicals/Critical Properties/Yaws Collection.tsv b/chemicals/Critical Properties/Yaws Collection.tsv index 2b11340c..b1a586b9 100644 --- a/chemicals/Critical Properties/Yaws Collection.tsv +++ b/chemicals/Critical Properties/Yaws Collection.tsv @@ -1,4 +1,4 @@ -CASRN Chemical Tc Pc Vc omega +CAS Chemical Tc Pc Vc omega 50-00-0 formaldehyde 408 6586000 0.000105 0.282 50-21-5 lactic acid 675 5960000 0.000251 1.022 50-70-4 sorbitol 868 4640000 0.000483 2.213 diff --git a/chemicals/Environment/CRC logP table.tsv b/chemicals/Environment/CRC logP table.tsv index ec664617..b0453ab5 100644 --- a/chemicals/Environment/CRC logP table.tsv +++ b/chemicals/Environment/CRC logP table.tsv @@ -1,4 +1,4 @@ -CASRN Name logP +CAS Name logP 50-00-0 Formaldehyde 0.35 50-32-8 Benzo[a]pyrene 6.2 56-23-5 Tetrachloromethane 2.64 diff --git a/chemicals/Environment/Official Global Warming Potentials 2007.tsv b/chemicals/Environment/Official Global Warming Potentials 2007.tsv index 9559f775..bbe0c519 100644 --- a/chemicals/Environment/Official Global Warming Potentials 2007.tsv +++ b/chemicals/Environment/Official Global Warming Potentials 2007.tsv @@ -1,4 +1,4 @@ -CASRN Name Formula Lifetime, years Radiative efficiency, W/m^2/ppb SAR 100yr 20yr GWP 100yr GWP 500yr GWP +CAS Name Formula Lifetime, years Radiative efficiency, W/m^2/ppb SAR 100yr 20yr GWP 100yr GWP 500yr GWP 56-23-5 Carbon tetrachloride CCl4 26 0.13 1400 2700 1400 435 71-55-6 Methyl chloroform CH3CCl3 5 0.06 506 146 45 74-82-8 Methanec CH4 12 0.00037 21 72 25 7.6 diff --git a/chemicals/Environment/Official Global Warming Potentials 2014.tsv b/chemicals/Environment/Official Global Warming Potentials 2014.tsv index a281cb4e..58bd6042 100644 --- a/chemicals/Environment/Official Global Warming Potentials 2014.tsv +++ b/chemicals/Environment/Official Global Warming Potentials 2014.tsv @@ -1,4 +1,4 @@ -"CASRN" "Name" "Formula" "Lifetime, years" "Radiative efficiency, W/m^2/ppb" "20yr GWP" "100yr GWP" "20yr GTP" "50yr GTP" "100yr GTP" "20yr AGWP" "100yr AGWP" "20yr AGTP" "50yr AGTP" "100yr AGTP" +"CAS" "Name" "Formula" "Lifetime, years" "Radiative efficiency, W/m^2/ppb" "20yr GWP" "100yr GWP" "20yr GTP" "50yr GTP" "100yr GTP" "20yr AGWP" "100yr AGWP" "20yr AGTP" "50yr AGTP" "100yr AGTP" "10024-97-2" "Nitrous Oxide" "N2O" 121 0 264 265 277 282 234 6.58E-12 2.43E-11 1.89E-13 1.74E-13 1.28E-13 "102687-65-0" "(E)-1-Chloro-3,3,3- trifluoroprop-1-ene" "trans-CF3CH=CHCl" 0.07 0.04 5 1 2 0.25 0.205 1.37E-13 1.37E-13 1.09E-15 1.54E-16 1.12E-16 "107-06-2" "1,2-Dichloroethane" "CH2ClCH2Cl" 0.18 0.01 3 0.899 0.975 0.151 0.124 8.24E-14 8.24E-14 6.67E-16 9.29E-17 6.77E-17 diff --git a/chemicals/Environment/Ozone Depletion Potentials.tsv b/chemicals/Environment/Ozone Depletion Potentials.tsv index a9cbeb4b..8fdfa1c0 100644 --- a/chemicals/Environment/Ozone Depletion Potentials.tsv +++ b/chemicals/Environment/Ozone Depletion Potentials.tsv @@ -1,4 +1,4 @@ -CASRN ODP2 Max ODP1 Max ODP1 Name ODP2 Lifetime ODP2 Min ODP1 Min ODP2 Design ODP1 Design +CAS ODP2 Max ODP1 Max ODP1 Name ODP2 Lifetime ODP2 Min ODP1 Min ODP2 Design ODP1 Design 56-23-5 0.82 1.1 1.1 CCl4 Carbon tetrachloride 0.82 26.0 0.82 1.1 0.82 1.1 71-55-6 0.16 0.1 0.1 Methyl Chloroform (C2H3Cl3) 1,1,1-trichloroethane 0.16 5.0 0.16 0.1 0.16 0.1 74-83-9 0.66 0.7 0.7 Methyl Bromide (CH3Br) 0.66 0.8 0.66 0.7 0.66 0.7 diff --git a/chemicals/Environment/Syrres logP data.csv.gz b/chemicals/Environment/Syrres logP data.csv.gz index 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Inorganic Compounds.csv +++ b/chemicals/Misc/Physical Constants of Inorganic Compounds.csv @@ -1,4 +1,4 @@ -CASRN Chemical Tm Tb rho +CAS Chemical Tm Tb rho 62-54-4 Calcium acetate 1500 62-76-0 Sodium oxalate 2340 74-90-8 Hydrogen cyanide 259.86 299.15 687.62 diff --git a/chemicals/Misc/Physical Constants of Organic Compounds.csv b/chemicals/Misc/Physical Constants of Organic Compounds.csv index 1b27707f..097e300f 100644 --- a/chemicals/Misc/Physical Constants of Organic Compounds.csv +++ b/chemicals/Misc/Physical Constants of Organic Compounds.csv @@ -1,4 +1,4 @@ -CASRN Name Tm Tb rho RI +CAS Name Tm Tb rho RI 50-00-0 Formaldehyde 181.15 254.05 50-01-1 Guanidine monohydrochloride 457.15 1354.2 50-02-2 Dexamethasone 535.15 From 86cf853555681eb4ab250c24772a86cc566ad931 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 15:11:46 -0600 Subject: [PATCH 22/40] Clean up index column name to CAS --- chemicals/Density/COSTALD Parameters.tsv | 2 +- ...RC Inorganics densties of molten compounds and salts.tsv | 2 +- .../Density/CRC Liquid Inorganic Constant Densities.tsv | 2 +- .../Density/CRC Solid Inorganic Constant Densities.tsv | 2 +- chemicals/Density/CRC Virial polynomials.tsv | 2 +- chemicals/Density/Mchaweh SN0 deltas.tsv | 2 +- chemicals/Density/Perry Parameters 105.tsv | 2 +- .../Permittivity (Dielectric Constant) of Liquids.tsv | 2 +- ...Thermodynamics of Organic Compounds in the Gas State.tsv | 2 +- chemicals/Interface/Jasper-Lange.tsv | 2 +- chemicals/Interface/MuleroCachadinaParameters.tsv | 2 +- chemicals/Interface/Somayajulu.tsv | 2 +- chemicals/Interface/SomayajuluRevised.tsv | 2 +- chemicals/Misc/CRC Handbook Organic RI.csv | 2 +- chemicals/Phase Change/CRC Handbook Heat of Fusion.tsv | 2 +- .../Phase Change/CRC Handbook Heat of Vaporization.tsv | 2 +- .../Ghazerati Appendix Sublimation Enthalpy.tsv | 2 +- .../Ghazerati Appendix Vaporization Enthalpy.tsv | 2 +- chemicals/Phase Change/OpenNotebook Melting Points.tsv | 2 +- chemicals/Phase Change/Yaws Boiling Points.tsv | 2 +- chemicals/Reactions/API TDB Albahri Hf (g).tsv | 2 +- chemicals/Reactions/ATcT 1.112 (g).tsv | 2 +- chemicals/Reactions/ATcT 1.112 (l).tsv | 2 +- chemicals/Safety/IARC Carcinogen Database.tsv | 2 +- chemicals/Safety/IS IEC 60079-20-1 2010.tsv | 2 +- chemicals/Safety/NFPA 497 2008.tsv | 2 +- .../Safety/National Toxicology Program Carcinogens.tsv | 2 +- chemicals/Triple Properties/Staveley 1981.tsv | 2 +- chemicals/Vapor Pressure/Antoine Collection Poling.tsv | 2 +- .../Vapor Pressure/Antoine Extended Collection Poling.tsv | 2 +- chemicals/Vapor Pressure/Wagner Collection Poling.tsv | 2 +- chemicals/Vapor Pressure/Wagner Original McGarry.tsv | 2 +- chemicals/Viscosity/Dutt Prasad 3 term.tsv | 2 +- chemicals/Viscosity/MagalhaesLJ.tsv | 2 +- chemicals/Viscosity/PolingLJ.tsv | 2 +- .../Viswanath Natarajan Dynamic 2 term Exponential.tsv | 2 +- chemicals/Viscosity/Viswanath Natarajan Dynamic 2 term.tsv | 2 +- chemicals/Viscosity/Viswanath Natarajan Dynamic 3 term.tsv | 2 +- dev/data/update_IARC.py | 2 +- tests/test_data_reader.py | 6 +++++- 40 files changed, 44 insertions(+), 40 deletions(-) diff --git a/chemicals/Density/COSTALD Parameters.tsv b/chemicals/Density/COSTALD Parameters.tsv index 60bfae09..97ce612b 100644 --- a/chemicals/Density/COSTALD Parameters.tsv +++ b/chemicals/Density/COSTALD Parameters.tsv @@ -1,4 +1,4 @@ -CASRN Chemical omega_SRK Vchar Z_RA +CAS Chemical omega_SRK Vchar Z_RA 60-29-7 ethyl ether 0.28 0.0002812 0.2632 64-17-5 ethyl alcohol 0.6378 0.0001752 0.2502 67-56-1 methyl alcohol 0.5536 0.0001198 0.2334 diff --git a/chemicals/Density/CRC Inorganics densties of molten compounds and salts.tsv b/chemicals/Density/CRC Inorganics densties of molten compounds and salts.tsv index 18e6fcaf..f5885b11 100644 --- a/chemicals/Density/CRC Inorganics densties of molten compounds and salts.tsv +++ b/chemicals/Density/CRC Inorganics densties of molten compounds and salts.tsv @@ -1,4 +1,4 @@ -CASRN Chemical MW rho k Tm Tmax +CAS Chemical MW rho k Tm Tmax 497-19-8 Sodium carbonate 105.989 1972 0.448 1129.15 1277.15 584-09-8 Rubidium carbonate 230.945 2840 0.64 1110.15 1280.15 7429-90-5 Aluminum 26.982 2377 0.311 933.47 1190.15 diff --git a/chemicals/Density/CRC Liquid Inorganic Constant Densities.tsv b/chemicals/Density/CRC Liquid Inorganic Constant Densities.tsv index 60727a6f..978fd0eb 100644 --- a/chemicals/Density/CRC Liquid Inorganic Constant Densities.tsv +++ b/chemicals/Density/CRC Liquid Inorganic Constant Densities.tsv @@ -1,4 +1,4 @@ -CASRN Chemical Vm +CAS Chemical Vm 74-90-8 Hydrogen cyanide 0.000039304828388598 75-15-0 Carbon disulfide 0.0000602762824572514 96-10-6 Chlorodiethylaluminum 0.000125580208333333 diff --git a/chemicals/Density/CRC Solid Inorganic Constant Densities.tsv b/chemicals/Density/CRC Solid Inorganic Constant Densities.tsv index e51d1178..64d119c5 100644 --- a/chemicals/Density/CRC Solid Inorganic Constant Densities.tsv +++ b/chemicals/Density/CRC Solid Inorganic Constant Densities.tsv @@ -1,4 +1,4 @@ -CASRN Chemical Vm +CAS Chemical Vm 62-54-4 Calcium acetate 0.000105444666666667 62-76-0 Sodium oxalate 0.0000572645299145299 75-20-7 Calcium carbide 0.0000288734234234234 diff --git a/chemicals/Density/CRC Virial polynomials.tsv b/chemicals/Density/CRC Virial polynomials.tsv index 08eec63b..0ce9efa3 100644 --- a/chemicals/Density/CRC Virial polynomials.tsv +++ b/chemicals/Density/CRC Virial polynomials.tsv @@ -1,4 +1,4 @@ -CASRN Chemical a1 a2 a3 a4 a5 +CAS Chemical a1 a2 a3 a4 a5 56-23-5 Tetrachloromethane -1600 -4059 -4653 0 0 60-29-7 Diethyl ether -1226 -4458 -7746 -10005 0 64-17-5 Ethanol -4475 -29719 -56716 0 0 diff --git a/chemicals/Density/Mchaweh SN0 deltas.tsv b/chemicals/Density/Mchaweh SN0 deltas.tsv index 0d4445eb..a226b459 100644 --- a/chemicals/Density/Mchaweh SN0 deltas.tsv +++ b/chemicals/Density/Mchaweh SN0 deltas.tsv @@ -1,4 +1,4 @@ -CASRN Chemical delta_SRK +CAS Chemical delta_SRK 56-23-5 Tetrachlouromethane, R-10 -0.0131517 60-29-7 Ethylether 0.0010621 64-19-7 Acetic acid -0.0103473 diff --git a/chemicals/Density/Perry Parameters 105.tsv b/chemicals/Density/Perry Parameters 105.tsv index dd0b2922..b37fced2 100644 --- a/chemicals/Density/Perry Parameters 105.tsv +++ b/chemicals/Density/Perry Parameters 105.tsv @@ -1,4 +1,4 @@ -CASRN Chemical C1 C2 C3 C4 Tmin Tmax +CAS Chemical C1 C2 C3 C4 Tmin Tmax 50-00-0 Formaldehyde 1941.5 0.22309 408 0.28571 181.15 408 55-21-0 Benzamide 737.1 0.25487 824 0.28571 403 824 56-23-5 Carbon tetrachloride 998.35 0.274 556.35 0.287 250.33 556.35 diff --git a/chemicals/Electrolytes/Permittivity (Dielectric Constant) of Liquids.tsv b/chemicals/Electrolytes/Permittivity (Dielectric Constant) of Liquids.tsv index f47af9d5..bf12ffba 100644 --- a/chemicals/Electrolytes/Permittivity (Dielectric Constant) of Liquids.tsv +++ b/chemicals/Electrolytes/Permittivity (Dielectric Constant) of Liquids.tsv @@ -1,4 +1,4 @@ -CASRN Chemical T Permittivity A B C D Tmin Tmax +CAS Chemical T Permittivity A B C D Tmin Tmax 50-70-4 D-Glucitol 353.2 35.5 50-78-2 2-(Acetyloxy)benzoic acid 333.2 6.55 6.9994 -0.0014553 333 416 51-79-6 Ethyl carbamate 328.2 14.14 32.431 -0.065097 0.000028571 328 368 diff --git a/chemicals/Heat Capacity/TRC Thermodynamics of Organic Compounds in the Gas State.tsv b/chemicals/Heat Capacity/TRC Thermodynamics of Organic Compounds in the Gas State.tsv index ce7a166f..f312cffd 100644 --- a/chemicals/Heat Capacity/TRC Thermodynamics of Organic Compounds in the Gas State.tsv +++ b/chemicals/Heat Capacity/TRC Thermodynamics of Organic Compounds in the Gas State.tsv @@ -1,4 +1,4 @@ -CASRN Chemical Tmin Tmax a0 a1 a2 a3 a4 a5 a6 a7 I J Hfg +CAS Chemical Tmin Tmax a0 a1 a2 a3 a4 a5 a6 a7 I J Hfg 50-00-0 Methanal 50 3000 4 29000 613 7.31 -0.881 -10600000 241 206 -0.2 3.46 -104700 50-32-8 Benzo[a]pyrene 298 1500 4 1180000 267 120.377 -29.08 4340000 137 113 -211.7 13.44 324000 53-70-3 Dibenz[a,h]anthracene 298 1500 4 4023000 395 126.374 -16.581 -7730000 99 143 -80.2 16.63 375000 diff --git a/chemicals/Interface/Jasper-Lange.tsv b/chemicals/Interface/Jasper-Lange.tsv index 3110a7bf..d967f9a7 100644 --- a/chemicals/Interface/Jasper-Lange.tsv +++ b/chemicals/Interface/Jasper-Lange.tsv @@ -1,4 +1,4 @@ -CASRN Name a b Tmin Tmax +CAS Name a b Tmin Tmax 55-21-0 Benzamide 47.26 0.0705 402.15 563.15 55-63-0 Glycerol tris(nitrate) 55.74 0.2504 286.15 433.15 56-23-5 Carbon tetrachloride 29.49 0.1224 250.15 349.85 diff --git a/chemicals/Interface/MuleroCachadinaParameters.tsv b/chemicals/Interface/MuleroCachadinaParameters.tsv index 6599baf4..c6cb7c59 100644 --- a/chemicals/Interface/MuleroCachadinaParameters.tsv +++ b/chemicals/Interface/MuleroCachadinaParameters.tsv @@ -1,4 +1,4 @@ -CASRN Fluid sigma0 n0 sigma1 n1 sigma2 n2 Tc Tmin Tmax +CAS Fluid sigma0 n0 sigma1 n1 sigma2 n2 Tc Tmin Tmax 60-29-7 Diethyl ether 1.2348 1.4846 -1.1808 1.5021 0 0 466.7 156.85 453.15 64-17-5 Ethanol 0.05 0.952 0 0 0 0 513.9 180.12 513.15 67-56-1 Methanol 0.22421 1.3355 -0.21408 1.677 0.083233 4.4402 513.38 175.61 508.15 diff --git a/chemicals/Interface/Somayajulu.tsv b/chemicals/Interface/Somayajulu.tsv index d4d17997..1a679221 100644 --- a/chemicals/Interface/Somayajulu.tsv +++ b/chemicals/Interface/Somayajulu.tsv @@ -1,4 +1,4 @@ -CASRN Chemical Tt Tc A B C +CAS Chemical Tt Tc A B C 60-29-7 Ethyl ether 157 466.74 61.0417 -6.7908 0.14046 64-17-5 Ethanol 159 513.92 111.4452 -146.0229 89.5703 64-19-7 Acetic acid 290 592.7 91.902 -91.7035 77.5072 diff --git a/chemicals/Interface/SomayajuluRevised.tsv b/chemicals/Interface/SomayajuluRevised.tsv index e8f4a1b9..6cda04f7 100644 --- a/chemicals/Interface/SomayajuluRevised.tsv +++ b/chemicals/Interface/SomayajuluRevised.tsv @@ -1,4 +1,4 @@ -CASRN Chemical Tt Tc A B C +CAS Chemical Tt Tc A B C 60-29-7 Ethyl ether 157 466.74 61.0417 -6.7908 0.14046 64-17-5 Ethanol 159 513.92 111.4452 -146.0229 89.5703 64-19-7 Acetic acid 290 592.7 91.902 -91.7035 77.5072 diff --git a/chemicals/Misc/CRC Handbook Organic RI.csv b/chemicals/Misc/CRC Handbook Organic RI.csv index 09e197ad..92cdafd2 100644 --- a/chemicals/Misc/CRC Handbook Organic RI.csv +++ b/chemicals/Misc/CRC Handbook Organic RI.csv @@ -1,4 +1,4 @@ -CASRN RI RIT +CAS RI RIT 50-36-2 1.5022 371.15 50-70-4 1.333 293.15 51-64-9 1.4704 293.15 diff --git a/chemicals/Phase Change/CRC Handbook Heat of Fusion.tsv b/chemicals/Phase Change/CRC Handbook Heat of Fusion.tsv index 9766f167..7724a9f7 100644 --- a/chemicals/Phase Change/CRC Handbook Heat of Fusion.tsv +++ b/chemicals/Phase Change/CRC Handbook Heat of Fusion.tsv @@ -1,4 +1,4 @@ -CASRN Chemical Formula Hfus +CAS Chemical Formula Hfus 50-06-6 Phenobarbital C12H12N2O3 27800 50-32-8 Benzo[a]pyrene C20H12 17300 50-33-9 Phenylbutazone C19H20N2O2 27700 diff --git a/chemicals/Phase Change/CRC Handbook Heat of Vaporization.tsv b/chemicals/Phase Change/CRC Handbook Heat of Vaporization.tsv index 1d844b4b..5ef8cc6e 100644 --- a/chemicals/Phase Change/CRC Handbook Heat of Vaporization.tsv +++ b/chemicals/Phase Change/CRC Handbook Heat of Vaporization.tsv @@ -1,4 +1,4 @@ -CASRN Chemical Formula Tb HvapTb Hvap298 +CAS Chemical Formula Tb HvapTb Hvap298 100-41-4 Ethylbenzene C8H10 409.31 35570 42240 100-42-5 Styrene C8H8 418.15 38700 100-46-9 Benzylamine C7H9N 458.15 60160 diff --git a/chemicals/Phase Change/Ghazerati Appendix Sublimation Enthalpy.tsv b/chemicals/Phase Change/Ghazerati Appendix Sublimation Enthalpy.tsv index 34b9ae01..361adf9d 100644 --- a/chemicals/Phase Change/Ghazerati Appendix Sublimation Enthalpy.tsv +++ b/chemicals/Phase Change/Ghazerati Appendix Sublimation Enthalpy.tsv @@ -1,4 +1,4 @@ -CASRN Chemical Hsub error +CAS Chemical Hsub error 51-17-2 benzimidazole 98470 51-20-7 5-bromouracil 151400 2500 51-21-8 5-fluorouracil 133200 2100 diff --git a/chemicals/Phase Change/Ghazerati Appendix Vaporization Enthalpy.tsv b/chemicals/Phase Change/Ghazerati Appendix Vaporization Enthalpy.tsv index 9aa13bd6..fff6abe4 100644 --- a/chemicals/Phase Change/Ghazerati Appendix Vaporization Enthalpy.tsv +++ b/chemicals/Phase Change/Ghazerati Appendix Vaporization Enthalpy.tsv @@ -1,4 +1,4 @@ -CASRN Chemical Hvap298 +CAS Chemical Hvap298 50-32-8 benzo[a]pyrene 111400 51-66-1 p-methoxyacetanilide 92000 51-80-9 bis(dimethylamino)methane 32700 diff --git a/chemicals/Phase Change/OpenNotebook Melting Points.tsv b/chemicals/Phase Change/OpenNotebook Melting Points.tsv index 8a20b4bf..c53ee7bd 100644 --- a/chemicals/Phase Change/OpenNotebook Melting Points.tsv +++ b/chemicals/Phase Change/OpenNotebook Melting Points.tsv @@ -1,4 +1,4 @@ -CASRN Tm +CAS Tm 50-00-0 181.15 50-02-2 536.15 50-04-4 495.15 diff --git a/chemicals/Phase Change/Yaws Boiling Points.tsv b/chemicals/Phase Change/Yaws Boiling Points.tsv index c6a7a1a4..8b103062 100644 --- a/chemicals/Phase Change/Yaws Boiling Points.tsv +++ b/chemicals/Phase Change/Yaws Boiling Points.tsv @@ -1,4 +1,4 @@ -CASRN Tb +CAS Tb 50-00-0 254.05 50-07-7 807.15 50-29-3 533.15 diff --git a/chemicals/Reactions/API TDB Albahri Hf (g).tsv b/chemicals/Reactions/API TDB Albahri Hf (g).tsv index 4f02858b..8603a336 100644 --- a/chemicals/Reactions/API TDB Albahri Hf (g).tsv +++ b/chemicals/Reactions/API TDB Albahri Hf (g).tsv @@ -1,4 +1,4 @@ -CASRN Compound Hfg +CAS Compound Hfg 50-00-0 Formaldehyde -115910 56-23-5 Carbon Tetrachloride -95980 57-13-6 Urea -245620 diff --git a/chemicals/Reactions/ATcT 1.112 (g).tsv b/chemicals/Reactions/ATcT 1.112 (g).tsv index 2397cf15..e8d6a84b 100644 --- a/chemicals/Reactions/ATcT 1.112 (g).tsv +++ b/chemicals/Reactions/ATcT 1.112 (g).tsv @@ -1,4 +1,4 @@ -CASRN Chemical Formula Hfg_0K Hfg uncertainty +CAS Chemical Formula Hfg_0K Hfg uncertainty 50-00-0 Formaldehyde H2CO (g) -105330 -109160 110 56-23-5 Tetrachloromethane CCl4 (g) -95420 -97590 750 57-12-5 Cyanide [CN]- (g) 63971 67257 99 diff --git a/chemicals/Reactions/ATcT 1.112 (l).tsv b/chemicals/Reactions/ATcT 1.112 (l).tsv index d6b9e62e..11da1795 100644 --- a/chemicals/Reactions/ATcT 1.112 (l).tsv +++ b/chemicals/Reactions/ATcT 1.112 (l).tsv @@ -1,4 +1,4 @@ -CASRN Chemical Formula Hfl_0K Hfl uncertainty +CAS Chemical Formula Hfl_0K Hfl uncertainty 56-23-5 Tetrachloromethane CCl4 (l) -110680 -130090 750 64-17-5 Ethanol CH3CH2OH (l) -269270 -277030 220 64-19-7 Acetic acid CH3C(O)OH (l) -484000 -483580 200 diff --git a/chemicals/Safety/IARC Carcinogen Database.tsv b/chemicals/Safety/IARC Carcinogen Database.tsv index 5c4d95b1..9115a455 100644 --- a/chemicals/Safety/IARC Carcinogen Database.tsv +++ b/chemicals/Safety/IARC Carcinogen Database.tsv @@ -1,4 +1,4 @@ -CASRN description group volumes year +CAS description group volumes year 50-00-0 Formaldehyde 1 Sup 7, 62, 88, 100F 2012 50-06-6 Phenobarbital 12 Sup 7, 79 2001 50-07-7 Mitomycin C 12 10, Sup 7 1987 diff --git a/chemicals/Safety/IS IEC 60079-20-1 2010.tsv b/chemicals/Safety/IS IEC 60079-20-1 2010.tsv index 64f0bbae..631243fb 100644 --- a/chemicals/Safety/IS IEC 60079-20-1 2010.tsv +++ b/chemicals/Safety/IS IEC 60079-20-1 2010.tsv @@ -1,4 +1,4 @@ -CASRN Names T_flash T_autoignition LFL UFL +CAS Names T_flash T_autoignition LFL UFL 50-00-0 Formaldehyde; (Methanal); (Methyl aldehyde); (Methylene oxide); HCHO 333.15 697.15 0.07 0.73 51-80-9 N,N,N1,N1-Tetramethyl; methanediamine; (CH3)2NCH2N(CH3)2 260.15 453.15 0.0161 57-14-7 1.1-Dimethylhydrazine; (CH3)2NNH2 255.15 513.15 0.024 0.2 diff --git a/chemicals/Safety/NFPA 497 2008.tsv b/chemicals/Safety/NFPA 497 2008.tsv index 7847179f..d622de2b 100644 --- a/chemicals/Safety/NFPA 497 2008.tsv +++ b/chemicals/Safety/NFPA 497 2008.tsv @@ -1,4 +1,4 @@ -CASRN Name T_flash T_autoignition LFL UFL +CAS Name T_flash T_autoignition LFL UFL 50-00-0 Formaldehyde (Gas) 703.15 0.07 0.73 57-14-7 Unsymmetrical Dimethyl Hydrazine 258.15 522.15 0.02 0.95 57-57-8 Propiolactone 0.029 diff --git a/chemicals/Safety/National Toxicology Program Carcinogens.tsv b/chemicals/Safety/National Toxicology Program Carcinogens.tsv index 90b71ffe..33cc538f 100644 --- a/chemicals/Safety/National Toxicology Program Carcinogens.tsv +++ b/chemicals/Safety/National Toxicology Program Carcinogens.tsv @@ -1,4 +1,4 @@ -CASRN Chemical Listing +CAS Chemical Listing 50-00-0 Formaldehyde 1 50-18-0 Cyclophosphamide 1 50-29-3 Dichlorodiphenyltrichloroethane 2 diff --git a/chemicals/Triple Properties/Staveley 1981.tsv b/chemicals/Triple Properties/Staveley 1981.tsv index c729b1f4..e7b0a791 100644 --- a/chemicals/Triple Properties/Staveley 1981.tsv +++ b/chemicals/Triple Properties/Staveley 1981.tsv @@ -1,4 +1,4 @@ -CASRN Chemical Formula Tt Pt Pt_uncertainty +CAS Chemical Formula Tt Pt Pt_uncertainty 56-23-5 Carbon tetrachloride COl4 250.534883 57-14-7 N, N-Dimethylhydrazine C2HsN2 215.959417 60-29-7 Diethyl ether C4HloO 156.864079 diff --git a/chemicals/Vapor Pressure/Antoine Collection Poling.tsv b/chemicals/Vapor Pressure/Antoine Collection Poling.tsv index 123a0dbf..6b7f7586 100644 --- a/chemicals/Vapor Pressure/Antoine Collection Poling.tsv +++ b/chemicals/Vapor Pressure/Antoine Collection Poling.tsv @@ -1,4 +1,4 @@ -CASRN Chemical A B C Tmin Tmax +CAS Chemical A B C Tmin Tmax 56-23-5 tetrachloromethane 9.10445 1265.632 -41.002 259 373.76 60-29-7 diethyl ether 9.10962 1090.64 -41.95 229.71 328.31 62-53-3 benzeneamine 9.4087 1692.77 -72.71 349.86 484.81 diff --git a/chemicals/Vapor Pressure/Antoine Extended Collection Poling.tsv b/chemicals/Vapor Pressure/Antoine Extended Collection Poling.tsv index 694ff624..096dbb8e 100644 --- a/chemicals/Vapor Pressure/Antoine Extended Collection Poling.tsv +++ b/chemicals/Vapor Pressure/Antoine Extended Collection Poling.tsv @@ -1,4 +1,4 @@ -CASRN Chemical A B C Tc to n E F Tmin Tmax +CAS Chemical A B C Tc to n E F Tmin Tmax 62-53-3 benzeneamine 9.4087 1692.77 -72.71 699 197 4.906 452.8 -239100 488.15 673.15 74-85-1 ethene 8.91382 596.53 -16.78 282.34 -99 2.79132 9.717 52.77 188.15 273.15 74-89-5 methanamine 9.213 899.03 -53.15 430 0 2.139 -151.85 7356 288.15 423.15 diff --git a/chemicals/Vapor Pressure/Wagner Collection Poling.tsv b/chemicals/Vapor Pressure/Wagner Collection Poling.tsv index e8c488b9..3267fb09 100644 --- a/chemicals/Vapor Pressure/Wagner Collection Poling.tsv +++ b/chemicals/Vapor Pressure/Wagner Collection Poling.tsv @@ -1,4 +1,4 @@ -CASRN Name A B C D Tc Pc Tmin Tmax +CAS Name A B C D Tc Pc Tmin Tmax 60-29-7 diethyl ether -7.43301 1.78847 -2.4793 -3.2811 466.74 3650000 156.85 466.74 64-17-5 ethanol -8.68587 1.17831 -4.8762 1.588 513.92 6132000 159.05 513.92 64-18-6 methanoic acid -7.24917 0.44255 -0.35558 -0.96906 588 5807000 281.45 588 diff --git a/chemicals/Vapor Pressure/Wagner Original McGarry.tsv b/chemicals/Vapor Pressure/Wagner Original McGarry.tsv index 67ea0c59..ba1e8ba1 100644 --- a/chemicals/Vapor Pressure/Wagner Original McGarry.tsv +++ b/chemicals/Vapor Pressure/Wagner Original McGarry.tsv @@ -1,4 +1,4 @@ -CASRN Name A B C D Pc Tc Tmin +CAS Name A B C D Pc Tc Tmin 50-00-0 formaldehyde -7.29343 1.08395 -1.63882 -2.30677 6586100 408 184 56-23-5 carbon tetrachloride -7.07139 1.71497 -2.8993 -2.49466 4550780 556.4 250 60-29-7 diethylether -7.29916 1.24828 -2.91931 -3.3674 3646100 466.74 250 diff --git a/chemicals/Viscosity/Dutt Prasad 3 term.tsv b/chemicals/Viscosity/Dutt Prasad 3 term.tsv index 9d8a2bd2..d46bff5f 100644 --- a/chemicals/Viscosity/Dutt Prasad 3 term.tsv +++ b/chemicals/Viscosity/Dutt Prasad 3 term.tsv @@ -1,4 +1,4 @@ -CASRN Chemical A B C Tmin Tmax +CAS Chemical A B C Tmin Tmax 56-23-5 Carbon tetrachloride -1.4708 -324.45 71.19 273 373 60-29-7 Ethyl ether -4.4735 -3623.26 -648.55 273 373 62-53-3 Aniline -1.1835 -224.31 170.82 268 393 diff --git a/chemicals/Viscosity/MagalhaesLJ.tsv b/chemicals/Viscosity/MagalhaesLJ.tsv index f5488f4b..d7417dbe 100644 --- a/chemicals/Viscosity/MagalhaesLJ.tsv +++ b/chemicals/Viscosity/MagalhaesLJ.tsv @@ -1,4 +1,4 @@ -CASRN Chemical molecular_diameter Stockmayer +CAS Chemical molecular_diameter Stockmayer 50-99-7 Glucose 5.56833 584.37 56-23-5 Carbon tetrachloride 5.2924 418.84 56-40-6 Glycine 5.51083 790.25 diff --git a/chemicals/Viscosity/PolingLJ.tsv b/chemicals/Viscosity/PolingLJ.tsv index 04b29f6d..deba4b50 100644 --- a/chemicals/Viscosity/PolingLJ.tsv +++ b/chemicals/Viscosity/PolingLJ.tsv @@ -1,4 +1,4 @@ -CASRN Formula Name molecular_diameter Stockmayer +CAS Formula Name molecular_diameter Stockmayer 56-23-5 CCl4 Carbon tetrachloride 5.947 322.7 60-29-7 C2H5OC2H5 Ethyl ether 5.678 313.8 64-17-5 C2H5OH Ethanol 4.53 362.6 diff --git a/chemicals/Viscosity/Viswanath Natarajan Dynamic 2 term Exponential.tsv b/chemicals/Viscosity/Viswanath Natarajan Dynamic 2 term Exponential.tsv index 1abe264e..2662990d 100644 --- a/chemicals/Viscosity/Viswanath Natarajan Dynamic 2 term Exponential.tsv +++ b/chemicals/Viscosity/Viswanath Natarajan Dynamic 2 term Exponential.tsv @@ -1,4 +1,4 @@ -CASRN Substance Formula C D Tmin Tmax +CAS Substance Formula C D Tmin Tmax 60-29-7 Ether C4H10O 950.69 -2.6785 270 410 64-19-7 Acetic acid C2H4O2 1210600 -3.6612 270 390 75-07-0 Acetaldehyde C2H4O2 730 -2.6402 270 300 diff --git a/chemicals/Viscosity/Viswanath Natarajan Dynamic 2 term.tsv b/chemicals/Viscosity/Viswanath Natarajan Dynamic 2 term.tsv index 58eb6552..19641701 100644 --- a/chemicals/Viscosity/Viswanath Natarajan Dynamic 2 term.tsv +++ b/chemicals/Viscosity/Viswanath Natarajan Dynamic 2 term.tsv @@ -1,4 +1,4 @@ -CASRN Name Formula A B Tmin Tmax +CAS Name Formula A B Tmin Tmax 71-36-3 1-Butanol C4 H10O -5.9719 1007 220 390 74-87-3 Methyl chloride CH3Cl -4.0591 140.54 250 310 74-88-4 Iodo methane CH3I -4.4564 336.11 270 320 diff --git a/chemicals/Viscosity/Viswanath Natarajan Dynamic 3 term.tsv b/chemicals/Viscosity/Viswanath Natarajan Dynamic 3 term.tsv index 0b8c8472..7ae94643 100644 --- a/chemicals/Viscosity/Viswanath Natarajan Dynamic 3 term.tsv +++ b/chemicals/Viscosity/Viswanath Natarajan Dynamic 3 term.tsv @@ -1,4 +1,4 @@ -CASRN Name Formula A B C Tmin Tmax +CAS Name Formula A B C Tmin Tmax 57-10-3 Palmitic acid C16H32O2 -0.8383 -267.36 188.83 340 370 57-50-1 Sucrose C = 26, H2O -1.3736 -327.15 102.69 290 330 60-12-8 Phenethyl alcohol C8H10O -1.4593 -324.57 168.71 270 380 diff --git a/dev/data/update_IARC.py b/dev/data/update_IARC.py index 52de91ed..b0b48d0a 100644 --- a/dev/data/update_IARC.py +++ b/dev/data/update_IARC.py @@ -68,6 +68,6 @@ 'year': years}, index=CASRNs) df.fillna('', inplace=True) df = df.reindex(index=natsorted(df.index)) -df.index.name = 'CASRN' +df.index.name = 'CAS' df.to_csv('../../chemicals/Safety/IARC Carcinogen Database.tsv', sep='\t') diff --git a/tests/test_data_reader.py b/tests/test_data_reader.py index 9ee559e8..9d8b2d1d 100644 --- a/tests/test_data_reader.py +++ b/tests/test_data_reader.py @@ -42,4 +42,8 @@ def test_CAS_numbers_valid_and_unique(): assert check_CAS(CAS) CAS_int = CAS_to_int(CAS) # Check that the CAS number fits in a 64 bit int - assert CAS_int < 9223372036854775807 \ No newline at end of file + assert CAS_int < 9223372036854775807 + + # Check that the name is CAS + for k, df in chemicals.data_reader.df_sources.items(): + assert df.index.name == 'CAS' From e753a886c84d81a06ec0aa1e178956f0baaba045 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 15:23:10 -0600 Subject: [PATCH 23/40] Go ahead and change the default behavior to be expecting integer CASs --- .../fedors_Vc_predictions.tsv | 114890 +++++------ .../omega_Psat_Tc_predictions.tsv | 59570 +++--- .../wilson_jasperson_Tc_Pc_predictions.tsv | 59452 +++--- chemicals/Misc/common_chemistry_data.tsv | 158582 +++++++-------- chemicals/Misc/joback_predictions.tsv | 46136 ++--- chemicals/Misc/webbook_constants.tsv | 27558 +-- chemicals/Misc/wikidata_properties.tsv | 20134 +- chemicals/data_reader.py | 12 +- 8 files changed, 243168 insertions(+), 243166 deletions(-) diff --git a/chemicals/Critical Properties/fedors_Vc_predictions.tsv b/chemicals/Critical Properties/fedors_Vc_predictions.tsv index c98271b3..5aec98cb 100644 --- a/chemicals/Critical Properties/fedors_Vc_predictions.tsv +++ b/chemicals/Critical Properties/fedors_Vc_predictions.tsv @@ -1,57446 +1,57446 @@ CAS Vc -50-00-0 0.000104689 -50-01-1 0.000320452 -50-02-2 0.001171342 -50-03-3 0.001233624 -50-04-4 0.001222599 -50-06-6 0.000715475 -50-07-7 0.001038613 -50-10-2 0.001165184 -50-11-3 0.000599001 -50-12-4 0.000708882 -50-13-5 0.000882639 -50-14-6 0.001385114 -50-19-1 0.000615823 -50-21-5 0.000246229 -50-22-6 0.001100818 -50-23-7 0.001118818 -50-24-8 0.001105502 -50-27-1 0.000904842 -50-28-2 0.000886842 -50-29-3 0.000776101 -50-30-6 0.000413683 -50-31-7 0.000457312 -50-32-8 0.000805264 -50-33-9 0.001000912 -50-34-0 0.001266703 -50-35-1 0.000753274 -50-36-2 0.000896002 -50-37-3 0.001104345 -50-39-5 0.00075574 -50-41-9 0.001613399 -50-42-0 0.001020409 -50-43-1 0.000457312 -50-44-2 0.000479146 -50-45-3 0.000413683 -50-50-0 0.001152614 -50-52-2 0.001133134 -50-53-3 0.000972669 -50-54-4 0.002247662 -50-55-5 0.001759444 -50-59-9 0.00112185 -50-60-2 0.000836128 -50-62-4 0.001815688 -50-65-7 0.000760739 -50-66-8 0.000526888 -50-67-9 0.000589048 -50-70-4 0.000469564 -50-71-5 0.000342126 -50-73-7 0.000457312 -50-78-2 0.000459231 -50-79-3 0.000413683 -50-81-7 0.000390044 -50-82-8 0.000457312 -50-84-0 0.000413683 -50-85-1 0.000397195 -50-89-5 0.000696321 -50-90-8 0.00068718 -50-91-9 0.000656621 -50-99-7 0.000458539 -51-02-5 0.000838118 -51-03-6 0.001049723 -51-05-8 0.00082193 -51-06-9 0.000797693 -51-12-7 0.000909554 -51-14-9 0.000858934 -51-15-0 0.000500103 -51-17-2 0.000412738 -51-18-3 0.000794744 -51-19-4 0.00038668 -51-20-7 0.000372434 -51-21-8 0.000322902 -51-26-3 0.000935682 -51-28-5 0.000437266 -51-30-9 0.00068653 -51-34-3 0.000908383 -51-35-4 0.000352326 -51-36-5 0.000413683 -51-40-1 0.000781621 -51-41-2 0.000466247 -51-42-3 0.000834391 -51-43-4 0.000519017 -51-44-5 0.000413683 -51-45-6 0.000388717 -51-48-9 0.001080939 -51-49-0 0.001080939 -51-50-3 0.000763719 -51-52-5 0.000498717 -51-55-8 0.000886736 -51-56-9 0.000833966 -51-57-0 0.00057976 -51-58-1 0.000727253 -51-59-2 0.000514967 -51-60-5 0.000920387 -51-61-6 0.000448247 -51-64-9 0.000465017 -51-65-0 0.000503062 -51-66-1 0.000492283 -51-67-2 0.000430247 -51-68-3 0.00071308 -51-71-8 0.000470274 -51-73-0 0.0006405413 -51-75-2 0.000452646 -51-77-4 0.00143042 -51-78-5 0.00038668 -51-79-6 0.000288547 -51-80-9 0.000424848 -51-82-1 0.000566034 -51-83-2 0.000565424 -51-84-3 0.000507366 -51-85-4 0.00047381 -51-92-3 0.00032179 -51-93-4 0.000470962 -51-98-9 0.0011019883 -52-01-7 0.001279314 -52-21-1 0.001220308 -52-26-6 0.000937286 -52-31-3 0.000757191 -52-39-1 0.001107793 -52-43-7 0.000625139 -52-49-3 0.001008323 -52-51-7 0.000387149 -52-52-8 0.000387096 -52-53-9 0.0014038603 -52-62-0 0.001470072 -52-66-4 0.000442662 -52-67-5 0.000442662 -52-76-6 0.0009802073 -52-78-8 0.001023073 -52-86-8 0.00107881 -52-88-0 0.001063434 -52-89-1 0.000399095 -52-90-4 0.000337122 -53-02-1 0.001143159 -53-03-2 0.001094477 -53-05-4 0.001132134 -53-06-5 0.001107793 -53-16-7 0.000875817 -53-18-9 0.002132658 -53-19-0 0.000732472 -53-21-4 0.000957975 -53-36-1 0.001273078 -53-38-3 0.0010646753 -53-39-4 0.00100391 -53-43-0 0.000970303 -53-44-1 0.0011246403 -53-46-3 0.001161163 -53-60-1 0.000991013 -53-63-4 0.000868842 -53-64-5 0.0008712083 -53-69-0 0.000851193 -53-70-3 0.00089246 -53-79-2 0.00144315 -53-85-0 0.000816191 -53-86-1 0.000970937 -53-89-4 0.001132645 -53-94-1 0.000632606 -53-95-2 0.000745121 -53-96-3 0.00072483 -54-04-6 0.00063143 -54-05-7 0.001074705 -54-06-8 0.000537512 -54-12-6 0.000648793 -54-16-0 0.000555996 -54-20-6 0.000401812 -54-25-1 0.000666808 -54-30-8 0.001076577 -54-31-9 0.000777595 -54-32-0 0.000880531 -54-35-3 0.001693569 -54-36-4 0.000680985 -54-42-2 0.000730781 -54-49-9 0.000501017 -54-62-6 0.001319455 -54-71-7 0.000679079 -54-77-3 0.000797258 -54-80-8 0.000776145 -54-84-2 0.001095695 -54-85-3 0.000429736 -54-88-6 0.000770058 -54-91-1 0.00077 -54-92-2 0.000588046 -54-96-6 0.000369991 -55-10-7 0.000488256 -55-18-5 0.000379053 -55-21-0 0.000366452 -55-22-1 0.000331682 -55-27-6 0.00052822 -55-31-2 0.00058099 -55-43-6 0.000825692 -55-48-1 0.001047166 -55-51-6 0.000656382 -55-52-7 0.000523044 -55-56-1 0.00159438 -55-57-2 0.000679696 -55-63-0 0.000520006 -55-73-2 0.000620525 -55-80-1 0.000770058 -55-81-2 0.000485308 -55-86-7 0.000514619 -55-92-5 0.000560136 -55-93-6 0.000698298 -55-98-1 0.000605154 -55-99-2 0.000666304 -56-03-1 0.000413987 -56-04-2 0.000393177 -56-05-3 0.000404479 -56-06-4 0.000400567 -56-09-7 0.00036054 -56-12-2 0.000339026 -56-18-8 0.000535645 -56-23-5 0.00027223 -56-25-7 0.000561338 -56-29-1 0.000757191 -56-34-8 0.000585671 -56-37-1 0.000736637 -56-40-6 0.000233486 -56-41-7 0.000286256 -56-45-1 0.000304256 -56-47-3 0.001197624 -56-49-5 0.00087676 -56-53-1 0.00079172 -56-55-3 0.000740396 -56-57-5 0.000547109 -56-75-7 0.000786083 -56-81-5 0.000257254 -56-82-6 0.000246229 -56-84-8 0.000364001 -56-85-9 0.000456798 -56-86-0 0.000416771 -56-87-1 0.000502593 -56-91-7 0.000437222 -56-92-8 0.000512663 -56-93-9 0.000578327 -56-94-0 0.001953482 -56-97-3 0.001045978 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0.000558861 -1999-33-3 0.00057457 -1999-34-4 0.000613204 -1999-45-7 0.000713304 -1999-46-8 0.000615108 -1999-85-5 0.0006013 -2000-40-0 0.00047517 -2000-43-3 0.000503107 -2001-29-8 0.000627533 -2001-32-3 0.000517258 -2001-81-2 0.00115021 -2001-91-4 0.001036353 -2001-93-6 0.000370982 -2002-24-6 0.000288484 -2002-59-7 0.000504465 -2002-92-8 0.000497315 -2003-31-8 0.0002331286 -2003-32-9 0.0002767296 -2003-82-9 0.0002299653 -2004-03-7 0.000476022 -2004-06-0 0.000783076 -2004-07-1 0.000841103 -2004-67-3 0.000366248 -2004-70-8 0.000282162 -2005-08-5 0.000576081 -2005-10-9 0.000581172 -2008-39-1 0.000668655 -2008-41-5 0.000741282 -2008-58-4 0.00045371 -2008-59-5 0.0004088793 -2008-62-0 0.0004819403 -2008-75-5 0.000518678 -2009-03-2 0.000696879 -2009-52-1 0.000586819 -2009-74-7 0.000460763 -2009-83-8 0.000423193 -2009-84-9 0.000651773 -2010-06-2 0.0005508 -2010-61-9 0.00055618 -2011-66-7 0.00069911 -2012-74-0 0.000581134 -2012-81-9 0.0005782953 -2013-12-9 0.000391796 -2014-22-4 0.000818106 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+500023961 0.00034913 +500026380 0.001201848 +500033421 0.000353239 +500041112 0.000774476 +500116881 0.0004893863 +727411247 0.000466195 +778611646 0.000412938 +782393764 0.000505081 +850411211 0.000572115 +857237253 0.000550821 +858830963 0.000682744 +869495249 0.001042284 +871518842 0.000550821 +929976329 0.000512629 +1243297100 0.000844597 diff --git a/chemicals/Critical Properties/omega_Psat_Tc_predictions.tsv b/chemicals/Critical Properties/omega_Psat_Tc_predictions.tsv index 2aaa668e..f4f393f6 100644 --- a/chemicals/Critical Properties/omega_Psat_Tc_predictions.tsv +++ b/chemicals/Critical Properties/omega_Psat_Tc_predictions.tsv @@ -1,29786 +1,29786 @@ CAS omega -50-00-0 0.27549204 -50-01-1 0.65295072 -50-02-2 1.4554455 -50-03-3 1.3320131 -50-04-4 1.2567065 -50-07-7 0.097038256 -50-11-3 0.82072778 -50-14-6 0.87948193 -50-21-5 1.0220005 -50-22-6 1.3766644 -50-23-7 1.5332837 -50-24-8 1.561861 -50-28-2 0.79030639 -50-29-3 0.4027072 -50-32-8 0.38554112 -50-36-2 0.45585612 -50-48-6 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0.67970049 +339152953 0.65360741 +339152964 0.73441296 +352356388 0.97226909 +357188740 0.26437043 +369403087 1.3674455 +489446857 0.96731417 +500003010 0.60647421 +500005276 0.40946753 +500015532 0.70531087 +500023950 0.47203384 +500023961 0.38185116 +500033421 0.36630603 +500116881 0.71528613 +727411247 0.67498583 +850411211 0.91738876 +1235106667 0.85081603 +1243297100 0.95752065 diff --git a/chemicals/Critical Properties/wilson_jasperson_Tc_Pc_predictions.tsv b/chemicals/Critical Properties/wilson_jasperson_Tc_Pc_predictions.tsv index 2895f893..ae76d521 100644 --- a/chemicals/Critical Properties/wilson_jasperson_Tc_Pc_predictions.tsv +++ b/chemicals/Critical Properties/wilson_jasperson_Tc_Pc_predictions.tsv @@ -1,29727 +1,29727 @@ CAS Tc Pc -50-00-0 418.20247 9264942.3 -50-01-1 723.75476 7006956.1 -50-02-2 1473.809 2234782 -50-03-3 1473.8803 2048073.8 -50-04-4 1541.1355 2180277 -50-07-7 1189.9851 2706881.4 -50-11-3 912.15263 3288464 -50-14-6 1199.7508 1299825.4 -50-21-5 673.2262 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index fd7718f0..baf80f5a 100644 --- a/chemicals/Misc/common_chemistry_data.tsv +++ b/chemicals/Misc/common_chemistry_data.tsv @@ -1,79292 +1,79292 @@ CAS Tm Tb Vms Vml -100-00-5 356.15 515.15 0.00010365132 -100-01-6 419.15 605.15 9.6994382e-05 -100-02-7 386.65 552.15 9.274e-05 -100-03-8 372.15 -100-05-0 508.65 -100-06-1 311.65 531.15 0.00013881494 -100-07-2 297.65 535.65 0.00013528152 -100-09-4 458.15 549.65 -100-10-7 347.65 449.65 -100-11-8 372.15 -100-12-9 260.85 518.65 0.0001346517 -100-13-0 291.65 -100-14-1 344.15 344.65 -100-15-2 425.15 -100-16-3 431.15 -100-17-4 327.15 547.15 0.00012674005 -100-18-5 256.05 483.45 0.00018939076 -100-19-6 354.95 438.15 -100-20-9 356.15 532.15 -100-21-0 675.15 0.00011001987 -100-22-1 324.15 533.15 -100-23-2 437.15 -100-25-4 447.15 570.15 0.00010345231 -100-26-5 527.15 -100-27-6 336.15 450.15 -100-28-7 330.15 436.15 -100-29-8 333.15 556.15 0.00014957051 -100-31-2 626.15 -100-32-3 454.15 -100-34-5 467.15 -100-35-6 447.15 0.00014798167 -100-36-7 458.15 -100-37-8 203.15 436.15 0.0001313642 -100-38-9 0.00015227974 -100-39-0 270.15 474.15 9.8406214e-05 -100-40-3 164.25 401.15 0.00013035305 -100-41-4 178.25 409.25 0.00012245675 -100-42-5 242.15 418.15 0.00011495585 -100-43-6 0.00010728571 -100-44-7 228.15 452.15 0.00011507273 -100-45-8 0.00011214024 -100-46-9 283.15 458.15 0.00010900305 -100-47-0 260.05 463.85 0.00010209901 -100-48-1 352.15 486.65 -100-49-2 230.15 456.15 0.00012089995 -100-50-5 275.15 378.15 0.00011362699 -100-51-6 257.95 478.45 0.00010379115 -100-52-7 247.15 452.15 0.00010106667 -100-53-8 243.15 467.65 0.00011828571 -100-54-9 324.15 480.05 8.9827437e-05 -100-55-0 266.65 539.15 -100-56-1 524.15 -100-57-2 463.15 -100-58-3 426.65 -100-59-4 362.65 -100-60-7 420.15 -100-61-8 216.15 469.4 0.00010834176 -100-62-9 473.15 -100-63-0 292.65 9.8506103e-05 -100-64-1 362.65 481.15 -100-65-2 355.15 -100-66-3 235.85 428.65 0.00010861792 -100-67-4 376.65 -100-68-5 400.15 466.15 0.00011791512 -100-69-6 432.65 -100-70-9 302.15 497.65 9.6308973e-05 -100-71-0 210.05 421.75 0.00011490617 -100-72-1 458.15 -100-73-2 143.15 9.5316219e-05 -100-74-3 210.37 411.65 0.00012802357 -100-75-4 443.15 492.15 0.00010737466 -100-76-5 431.15 -100-79-8 246.75 461.15 0.00012467925 -100-80-1 186.85 445.15 0.00012986813 -100-81-2 474.15 476.65 -100-82-3 520.65 -100-83-4 381.15 513.15 0.00010808036 -100-84-5 226.15 448.65 0.00012573075 -100-85-6 353.15 -100-86-7 297.15 488.15 0.00016635659 -100-88-9 442.65 -100-89-0 -100-90-3 513.9 -100-91-4 386.15 -100-92-5 -100-93-6 420.15 -100-94-7 367.15 -100-95-8 420.65 -100-97-0 536.15 553.15 0.00010532682 -100-99-2 273.15 0.00025393639 -1000-05-1 442.65 -1000-30-2 -1000-50-6 412.15 -1000-68-6 434.15 -1000-70-0 250.15 437.15 0.00022704019 -1000-82-4 384.15 -1000-83-5 377.65 -1000-84-6 366.65 -1000-86-8 159.15 366.35 0.00013052389 -1000-87-9 356.15 -10000-56-3 435.65 -1000007-16-8 380.25 -100003-85-8 478.15 -10001-43-1 384.65 -1000341-18-3 539.15 -1000342-22-2 -10004-39-4 397.15 -10004-44-1 359.65 -10004-45-2 318.65 -10004-46-3 314.4 -10004-48-5 312.15 -100041-05-2 492.15 -100046-59-1 -100047-36-7 538.15 -100047-44-7 423.15 -100050-04-2 -1000573-68-1 479.15 -100058-37-5 -100059-52-7 475.65 -100060-09-1 422.15 -100060-86-4 499.15 -100061-24-3 354.15 -1000623-98-2 388.4 -100063-13-6 -100063-41-0 367.15 -100074-11-1 323.15 -10008-73-8 -10008-90-9 0.00015542638 -10009-20-8 526.15 -1000932-32-0 485.15 -1000932-44-4 368.15 -100097-71-0 494.4 -1001-20-3 349.65 -1001-25-8 0.00017057282 -1001-26-9 0.00014504024 -1001-45-2 306.65 -1001-55-4 473.15 -1001-56-5 388.15 7.4365714e-05 -1001-58-7 318.15 -1001-89-4 413.65 -1001057-06-2 312.65 -100114-53-2 388.15 -100114-58-7 387.65 -10012-47-2 394.15 -10012-73-4 472.65 -100124-07-0 430.05 -100130-06-1 599.4 -100132-04-5 307.4 -100134-82-5 370.15 -100144-91-0 291.15 -10015-69-7 356.5 -1001518-99-5 372.65 -1001519-38-5 412.15 -10016-32-7 323.15 -1001620-76-3 348.65 -10017-11-5 369.65 -10017-18-2 -10017-37-5 564.15 -10017-39-7 490.65 -10017-44-4 409.15 -10017-49-9 475.15 -100189-17-1 311.15 -10019-24-6 456.15 -10019-60-0 392.65 -100198-09-2 468.15 -1002-16-0 430.15 -1002-18-2 -1002-23-9 -1002-28-4 436.15 0.00010944575 -1002-29-5 0.00017926023 -1002-33-1 403.65 -1002-35-3 393.15 -1002-36-4 0.0001266885 -1002-37-5 -1002-57-9 467.15 -1002-58-0 332.15 -1002-62-6 591.15 -1002-67-1 452.15 -1002-68-2 211.05 466.65 0.00020528206 -1002-69-3 241.85 496.55 0.00020323137 -1002-84-2 325.45 612.25 -1002-89-7 295.15 -1002-96-6 306.5 -10020-43-6 0.00019779821 -10021-35-9 526.15 -10022-31-8 863.15 6.1833284e-05 -10022-50-1 107.15 200.65 -10022-70-5 300.15 -10023-30-0 592.15 -10024-47-2 0.00039368605 -10024-70-1 -10024-74-5 571.15 -10024-89-2 450.15 -10024-90-5 299.4 0.00015186829 -10024-93-8 1057.15 -10024-97-2 182.35 184.67 3.5780488e-05 -100245-35-0 470.65 -10025-65-7 854.15 4.5312436e-05 -10025-67-9 196.15 408.75 7.997631e-05 -10025-68-0 188.15 400.15 8.2488014e-05 -10025-69-1 311.15 7.6613387e-05 -10025-73-7 1423.15 5.5175993e-05 -10025-74-8 927.15 -10025-76-0 896.15 -10025-77-1 -10025-78-2 146.65 304.95 9.7939262e-05 -10025-82-8 856.15 928.15 5.529425e-05 -10025-87-3 274.4 378.95 9.3209726e-05 -10025-91-9 346.55 496.65 7.2649363e-05 -10025-93-1 1115.15 -100256-30-2 -100256-90-4 -100256-91-5 366.65 -100256-94-8 -100257-47-4 -10026-03-6 578.15 -10026-04-7 203.15 332.15 0.00011177632 -10026-07-0 498.15 663.15 -10026-08-1 689.15 -10026-10-5 863.15 891.15 -10026-11-6 709.15 8.3138066e-05 -10026-12-7 480.4 527.15 -10026-13-8 433.65 9.8505203e-05 -10026-17-2 1423.15 1673.15 2.1880363e-05 -10026-22-9 328.15 7.4447511e-05 -10026-24-1 369.95 693.15 8.9757415e-05 -10026-98-9 525.65 -10027-06-2 0.00016235593 -10027-07-3 334.65 -100278-51-1 448.15 -10028-15-6 80.45 161.25 -10028-17-8 25.03 -10028-18-9 -10028-22-5 753.15 4.9700833e-05 -100289-17-6 509.65 -100289-21-2 392.15 -10029-04-6 -10029-09-1 -1003-03-8 190.45 381.15 9.7997468e-05 -1003-04-9 -1003-07-2 347.65 -1003-09-4 423.15 -1003-10-7 411.15 8.6729496e-05 -1003-14-1 362.65 -1003-18-5 -1003-19-6 361.82 6.9925936e-05 -1003-20-9 0.00010676157 -1003-22-1 -1003-29-8 319.65 491.15 -1003-30-1 382.15 -1003-31-2 402.65 465.15 9.25e-05 -1003-32-3 502.15 -1003-35-6 561.15 -1003-38-9 364.15 -1003-39-0 441.15 -1003-41-4 383.25 -1003-51-6 457.15 -1003-52-7 -1003-55-0 -1003-56-1 414.65 562.15 -1003-61-8 446.65 -1003-64-1 328.15 409.15 0.0001168363 -1003-67-4 312.15 423.15 -1003-68-5 455.65 -1003-73-2 312.15 421.15 -1003-78-7 270.15 554.15 0.00013045239 -1003-83-4 418.9 -1003-85-6 -1003-90-3 384.15 -1003-92-5 322.65 -1003-99-2 -10030-31-6 537.65 -10030-73-6 304.65 -10030-85-0 368.15 -1003043-76-2 397.15 -100306-34-1 329.65 -100306-41-0 383.15 -10031-18-2 678.15 3.8387026e-05 -10031-22-8 639.15 5.5205776e-05 -10031-24-0 -10031-27-3 661.15 -10031-59-1 905.15 4.4676777e-05 -10031-82-0 286.65 522.15 -10031-87-5 435.65 -10031-90-0 0.00015924067 -10031-93-3 0.00019205794 -10031-96-6 543.15 -100317-21-3 373.65 -10032-00-5 0.00024760519 -10032-02-7 -10032-05-0 455.15 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524.15 -1004-37-1 418.15 -1004-38-2 523.15 -1004-66-6 455.65 -1004-75-7 515.15 -1004-77-9 345.65 0.00015208243 -1004-84-8 336.15 -1004-96-2 381.15 -10040-45-6 546.15 -10040-91-2 478.15 -10040-95-6 333.65 -10040-98-9 412.65 -10041-02-8 470.15 -10041-05-1 513.65 -10041-06-2 386.15 -100418-33-5 355.65 -100418-48-2 365.15 -10042-59-8 -10042-76-9 843.15 918.15 5.0378876e-05 -10042-88-3 854.15 -10043-01-3 1043.15 7.767703e-05 -10043-11-5 -10043-35-3 444.15 4.3087108e-05 -10043-37-5 0.00013606061 -10043-52-4 1045.15 1943.15 5.1572491e-05 -10043-67-1 -10043-92-2 202.15 211.15 -100446-36-4 346.15 -100446-37-5 383.15 -10045-45-1 392.15 -10045-49-5 -10045-66-6 467.65 -10045-71-3 415.15 -10045-86-0 1273.15 -10045-94-0 352.15 5.9909736e-05 -100453-11-0 -10047-28-6 -1004769-34-9 356.15 -1004769-38-3 388.9 -100477-79-0 -10048-13-2 519.15 -10048-32-5 394.15 -10048-95-0 403.15 9.6288458e-05 -10048-98-3 -100487-74-9 474.15 -10049-01-1 -10049-04-4 214.15 284.15 4.2157375e-05 -10049-05-5 1097.15 1573.15 4.4675427e-05 -10049-07-7 963.15 -10049-08-8 873.15 -10049-12-4 -10049-16-8 -10049-21-5 -10049-60-2 425.65 -10049-61-3 553.15 -10049-83-9 457.15 -100491-29-0 493.15 -100491-30-3 504.15 -100492-04-4 516.15 -100492-07-7 442.65 -100499-64-7 332.15 -100499-66-9 462.65 -1005-02-3 368.65 -1005-05-6 329.65 -1005-23-8 439.65 -1005-24-9 481.15 -1005-25-0 339.15 -1005-29-4 442.65 -1005-32-9 297.15 0.00015238434 -1005-38-5 399.65 -1005-39-6 461.65 -1005-40-9 446.9 -1005-51-2 368.65 -1005-56-7 324.15 0.00013455183 -1005-62-5 366.65 451.65 0.00013762051 -1005-64-7 230.05 471.85 -1005-66-9 410.65 -1005-67-0 216.05 486.65 0.00017671808 -1005-68-1 442.15 0.00017898431 -1005-69-2 -1005-91-0 -1005-93-2 475.15 -1005-94-3 321.15 -10050-12-1 442.15 -100501-60-8 367.65 -100501-62-0 474.65 -10051-44-2 498.15 -10051-45-3 623.15 0.00012722145 -100510-33-6 559.65 -100510-66-5 440.65 -100516-72-1 378.15 -100516-78-7 368.65 -100516-88-9 353.15 -10052-47-8 557.15 -100520-15-8 0.00020249114 -1005205-27-5 556.65 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485.65 -100643-71-8 427.4 -100646-51-3 349.65 493.15 -10065-72-2 -10065-79-9 421.65 -10066-11-2 486.15 -10066-20-3 497.15 -1006619-83-5 442.15 -100665-43-8 492.15 -1006694-45-6 462.65 -100678-32-8 438.15 -10068-67-4 391.15 -1007-01-8 368.15 -1007-03-0 -1007-15-4 330.15 503.15 -1007-16-5 429.15 -1007-18-7 527.65 -1007-19-8 324.15 -1007-27-8 -1007-28-9 451.15 -1007-32-5 345.65 503.15 0.00014790419 -1007-33-6 400.65 -1007-36-9 423.15 -1007-48-3 -1007-49-4 -1007-57-4 -10070-48-1 491.65 -100703-98-8 -100704-38-9 469.15 -100704-39-0 471.15 -100710-37-0 -1007105-57-8 318.15 415.65 -1007107-52-9 396.15 -10072-09-0 -10072-48-7 391.15 -10072-97-6 483.65 -10075-38-4 -10075-50-0 364.15 -10075-51-1 367.15 -10075-52-2 315.65 -10075-62-4 356.65 -10075-63-5 456.65 -10075-66-8 323.15 -10075-73-7 368.15 -10075-76-0 358.15 -10075-85-1 530.65 -100751-65-3 336.15 -10076-48-9 0.00013875258 -10076-57-0 0.00025827862 -10078-25-8 417.65 -100784-20-1 449.15 -100784-27-8 398.65 -100791-01-3 467.15 -1008-17-9 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421.15 +99207 476.15 0.00022372549 +99218 458.15 +99241 534.65 +99274 450.15 452.15 +99285 418.15 +99296 450.55 +99309 464.15 +99310 633.15 +99321 535.15 0.00011718651 +99332 347.15 +99343 478.15 +99354 395.65 588.15 0.00012107955 +99365 494.15 +99401 446.15 +99423 348.65 +99434 489.65 +99456 508.65 +99478 370.15 +99489 297.65 501.15 0.00015893715 +99490 373.15 504.15 0.00015647917 +99503 494.15 +99514 303.65 527.15 +99525 406.65 +99536 369.15 +99547 316.15 528.65 0.00013188625 +99558 380.65 +99569 472.65 +99570 419.15 +99581 490.65 +99592 391.15 +99605 413.15 +99616 331.65 437.15 +99627 212.15 476.35 0.00018958991 +99638 316.65 549.15 0.00014626801 +99649 423.15 0.00013007087 +99650 362.65 575.95 0.00010673651 +99661 298.15 494.65 0.00015952434 +99672 321.15 +99683 412.15 +99694 383.65 +99718 334.65 514.15 0.00015199838 +99729 0.00015068632 +99730 384.15 +99752 306.35 495.65 0.00014193762 +99763 404.15 538.15 0.00013575125 +99774 330.15 459.45 +99809 366.65 +99810 369.15 +99821 183.31 444.05 0.00017448688 +99832 445.15 +99843 446.65 +99854 263.15 456.15 0.00016045936 +99865 448.15 +99876 204.25 450.25 0.0001558885 +99887 436.65 498.15 +99898 335.45 503.15 0.00014040206 +99901 323.65 530.15 +99912 293.65 510.15 0.00012966784 +99923 379.15 567.15 0.00011263333 +99934 382.65 420.65 +99945 452.75 0.00010883293 +99967 487.65 9.460274e-05 +99978 387.15 488.15 0.00015023333 +99989 326.15 535.15 0.00013145753 +99990 326.65 511.15 0.00010631008 +990738 423.15 +990910 332.65 +99009855 393.15 +99009866 442.15 +99009935 403.65 +99010647 412.65 +99011026 566.15 +99057848 358.15 +99066703 453.15 +99070152 299.15 +99070174 425.15 +99070185 358.15 +99071951 582.65 +991424 467.15 +991844 366.65 +99105778 412.15 +99108346 424.65 +99112955 +99138928 408.05 +99148557 +99148568 +99158608 348.15 +99169934 +99171241 370.15 +99172766 +99178300 498.15 +99183138 +99183149 293.65 +99184824 400.15 +99186057 0.00015843734 +99187390 +99189603 416.15 +99196584 419.15 +99199607 402.9 +99199629 325.6 +992041 539.15 692.15 +992201 441.65 +992552 328.15 +992949 116.65 215.65 7.3471338e-05 +992983 374.15 5.038404e-05 +99208501 517.65 +99210910 +99210921 +99217637 449.65 +99233199 410.15 +99233235 422.15 +99233417 373.15 +99254225 387.15 +99281900 387.65 +99282798 501.15 +99286450 447.15 +99290978 402.65 +99291255 376.15 +99294936 469.15 +993000 138.15 280.15 +993077 137.25 279.85 0.00011630094 +993102 383.65 +993113 590.15 +993124 295.65 0.00010467351 +993135 381.65 +993157 326.15 484.15 +993168 318.65 444.15 +993226 353.15 +993431 452.15 0.00012030258 +993500 399.15 +993635 434.65 +993862 328.65 0.00020612996 +993953 345.15 0.00016239771 +99300784 489.15 +99304322 432.65 +99305336 531.65 +99338326 414.65 +99357252 412.15 +99358095 464.65 +99358222 498.15 +99359281 +99359349 +99361101 477.65 +99365205 521.15 +99365669 331.15 +99367461 436.9 +99367609 459.65 +99387243 +99395887 398.15 +994058 359.45 +994070 366.65 0.00013407054 +994263 405.15 +994285 449.15 +994296 582.1 +994309 223.15 417.65 0.00016821429 +994310 323.3 0.00016889433 +994321 316.65 +994490 158.15 506.15 0.000292109 +994503 0.00031060182 +994650 200.15 0.00025680294 +994661 487.15 0.00025667819 +994796 504.15 +99419326 +99419746 434.15 +99420685 492.15 +99446329 501.65 +99455080 341.15 +99455160 395.15 +99459480 350.65 +99464649 433.15 +99465108 544.15 +995142 0.00025430003 +995175 337.15 +995255 473.15 +995324 0.00026568214 +995335 +995459 +995835 0.00040461556 +99512104 402.65 +99512739 439.65 +99512740 432.15 +99513221 520.65 +99514882 455.15 +99517461 430.15 +99519843 474.15 +99522799 417.15 +99532533 473.65 +99533809 540.65 +99548579 396.15 +99584335 371.15 +99584960 469.15 +99585190 436.65 +99585509 383.15 +99585918 420.15 +99585929 400.15 +99586319 410.15 +99586648 381.65 +99586660 531.65 +99592322 419.65 +99592399 432.15 +996076 468.65 +996087 294.65 364.15 0.00028228994 +996214 9.7894626e-05 +996305 523.15 +996350 339.15 +996372 294.15 +996509 399.4 +996703 0.00023260567 +996974 0.00022853703 +996985 516.15 8.0994513e-05 +99607702 342.55 +99614014 452.15 +99614025 504.65 +99624289 402.65 +99665006 358.15 +99685968 +997433 +997466 +997502 0.00016433678 +997557 423.15 +997682 531.15 +997693 0.0002051934 +997706 326.15 +997955 +99705507 332.15 +99705654 554.15 +99724182 +99725129 +99725130 +99726768 428.15 +99727976 +99755610 501.65 +99759485 486.15 +99768124 504.65 +99768191 326.65 +99768680 547.65 +99799107 +998072 447.65 +998129 0.00011471443 +998298 445.15 +998301 103.15 405.65 0.00018784448 +998403 0.00024922395 +998914 304.15 0.00016539467 +998936 0.000157257 +998970 349.15 0.00014250186 +99810772 +99817284 415.15 +99817364 318.65 +99822249 447.65 +99832618 417.65 +99839164 317.65 +99839460 407.15 +99842689 +99843615 343.15 +99846658 368.15 +99846932 0.00015777329 +99847424 444.6 +99849033 0.0001806781 +99849180 351.65 +99853222 +99856527 337.15 +99867115 355.65 +99896852 427.15 +99898858 503.65 +999019 343.15 0.00014238086 +999064 0.00017437472 +999075 0.00016979214 +999086 +999213 382.15 +999224 +999406 0.00024965502 +999520 417.15 +999553 395.15 0.0001187692 +999564 +999611 498.15 +999644 +999655 403.65 +999724 384.65 +999815 518.15 +999826 359.65 +999973 398.15 +99902713 368.15 +99902735 412.65 +99902940 367.65 +99903045 464.15 +99931950 380.65 +99948488 +99967790 341.15 +99968840 423.15 +99972675 339.65 +99974228 435.15 +99976995 354.65 +99979778 454.65 +99984711 373.65 +99984744 468.65 +99985689 368.15 diff --git a/chemicals/Misc/joback_predictions.tsv b/chemicals/Misc/joback_predictions.tsv index 2eb63817..70431883 100644 --- a/chemicals/Misc/joback_predictions.tsv +++ b/chemicals/Misc/joback_predictions.tsv @@ -1,23069 +1,23069 @@ CAS Tm Hfus Hvap Tb Tc Pc Vc Hfg Cpg0 Cpg1 Cpg2 Cpg3 mul0 mul1 -50-01-1 349.88 55715 490.01 130390 26.76 0.23518 -5.4e-05 -3.16e-08 -50-02-2 785.74 32376 120697 1134.35 1389.6626 1973554 0.0011035 -1056400 -324.279 3.45706 -0.00348302 1.47396e-06 -50-03-3 757.51 36172 115636 1129.27 1382.5807 1683793.9 0.0011655 -1098660 -274.889 3.24206 -0.00293154 1.13936e-06 -50-04-4 769.15 30523 103513 1109.58 1364.9859 1651112.9 0.0011545 -1063790 -249.689 3.06626 -0.00271254 1.04476e-06 -50-07-7 911.09 49318 99111 1010.57 1262.2242 2811361 0.0008445 -528790 -45.969 1.75404 -0.0013572 4.599e-07 -50-11-3 568.15 17844 56276 685.49 930.53702 3345107 0.0005545 -461130 -0.248 0.88806 -0.0004458 9.89e-08 -50-14-6 502.82 38062 94439 989.11 1216.6925 1034566.8 0.0013545 -259460 -217.52 3.1236 -0.0023272 7.387e-07 -50-21-5 329.99 14234 55727 505.49 694.80792 5765386.8 0.0002405 -613030 8.37 0.37952 -0.0002456 6.18e-08 3119.27 -19.369 -50-22-6 668.74 32921 104928 1025.05 1260.3016 1898605 0.0010295 -755340 -248.489 2.81494 -0.00238474 8.7466e-07 -50-23-7 753.46 30711 120456 1117.47 1368.1836 2147321.7 0.0010465 -892330 -293.189 3.14084 -0.00294774 1.18246e-06 -50-24-8 754.22 31933 120748 1116.63 1367.0901 2220798.9 0.0010325 -834550 -285.409 3.08484 -0.00293502 1.18666e-06 -50-70-4 462.3 21732 127472 888.2 1093.1477 6830134.6 0.0004615 -1101670 22.452 0.8014 -0.0004978 1.17e-07 11344.22 -37.194 -50-71-5 629.4 14100 55740 683.72 977.82427 7255440.9 0.0002955 -526410 107.27 -0.1676 0.000767 -4.436e-07 -50-81-7 471.73 27073 104214 779.24 958.50468 6132226.8 0.0004105 -991010 28.461 0.6368 -0.0004062 9.55e-08 7467.18 -28.333 -50-99-7 443.48 19933 117513 844.68 1034.2622 6631370.1 0.0004595 -1035020 28.561 0.7419 -0.0004604 1.051e-07 9817.26 -33.651 -51-15-0 312.8 25458 51886 474.21 674.45367 4255158 0.0004625 -57750 -35.43 0.86402 -0.00065176 1.882e-07 -51-35-4 479.22 27533 67273 610.85 822.2765 5527839.6 0.0003355 -571080 -29.39 0.6554 -0.0003626 6.45e-08 -51-46-7 379.86 21852 42068 462.36 656.15718 4271861.2 0.0004375 347250 -210.57 1.8012 -0.001735 6.46e-07 -51-73-0 433.36 25928 49332 539.4 759.77969 2960117.7 0.0006055 290310 -134.448 1.5774 -0.00122046 3.8058e-07 -51-75-2 238.42 20121 37537 401.3 580.87674 3177552.8 0.0004315 -110480 13.434 0.61632 -0.0004016 1.037e-07 -51-77-4 341.18 64515 83293 895.78 1099.128 807076.45 0.0014785 -380740 -65.611 2.61364 -0.0017809 4.99e-07 -51-79-6 249.16 13092 40320 398.99 591.44517 4795850.2 0.0002585 -388740 32.061 0.29592 -8.82e-05 -2.16e-08 -51-80-9 211.05 14748 30810 338.88 500.28146 3452080.3 0.0003515 -11470 -23.039 0.72668 -0.0004734 1.231e-07 -51-85-4 370.16 24770 59414 573.74 813.91258 4730109.4 0.0004255 25430 51.434 0.49638 -0.0002002 3.2e-09 -51-98-9 601.98 32009 74624 862.71 1118.5625 1663255.9 0.0010305 -363980 -234.09 2.74774 -0.00235377 8.6549e-07 -52-01-7 707.24 33880 91371 1043.71 1309.1635 1523497.5 0.0012035 -673670 -317.84 3.45045 -0.00320694 1.26146e-06 -52-21-1 758.27 37394 115928 1128.43 1381.6314 1734665.3 0.0011515 -1040880 -267.109 3.18606 -0.00291882 1.14356e-06 -52-31-3 695.9 21680 69533 822.87 1107.4375 3435911.3 0.0006535 -437960 -29.949 1.05922 -0.00044604 5.15e-08 -52-39-1 710.74 35210 111648 1073.71 1316.508 2027229.3 0.0010465 -840920 -237.089 2.78942 -0.00237774 8.7256e-07 -52-43-7 644.94 22343 62049 742.11 1005.7034 3505425.2 0.0005835 -266790 15.352 0.7961 -0.0003264 4.54e-08 -52-51-7 451.04 20934 77360 667.37 875.11263 6696649.8 0.0003745 -402890 -0.048 0.62016 -0.0005218 1.699e-07 -52-52-8 436.04 14273 55861 570.44 809.53867 4938444.8 0.0003635 -407930 -101.95 1.1101 -0.0010786 4.367e-07 -52-66-4 413.85 17151 59582 591.23 831.10741 4684891.8 0.0004055 -438560 -1.83 0.75054 -0.0005616 1.643e-07 -52-67-5 413.85 17151 59582 591.23 831.10741 4684891.8 0.0004055 -438560 -1.83 0.75054 -0.0005616 1.643e-07 -52-76-6 529.71 27038 75197 783.09 1019.051 2051171 0.0009045 -19950 -288.82 2.81482 -0.00261397 1.02159e-06 -52-78-8 550.96 23573 79586 860.79 1094.028 1856306.6 0.0009495 -449550 -266.169 2.74044 -0.00237404 8.902e-07 -52-89-1 402.44 21900 60958 586.83 829.12035 5094760 0.0003625 -460080 57.761 0.3384 -9.4e-05 -3.1e-08 -52-90-4 388.89 19385 56426 548.7 783.04081 6027931 0.0003045 -388530 24.461 0.4347 -0.000281 6.86e-08 -53-02-1 724.3 36598 131316 1128.35 1388.5552 2088840.9 0.0010705 -993850 -334.529 3.40564 -0.0031911 1.26956e-06 -53-03-2 765.86 26284 108625 1096.94 1347.8277 2171403.7 0.0010215 -799680 -260.209 2.90904 -0.00271602 1.09206e-06 -53-05-4 735.94 30949 119193 1108.66 1357.39 2043759.3 0.0010595 -958980 -309.329 3.22984 -0.0029721 1.17496e-06 -53-06-5 765.1 25062 108333 1097.78 1348.2336 2100344.4 0.0010355 -857460 -267.989 2.96504 -0.00272874 1.08786e-06 -53-36-1 765.3 41055 117845 1146.64 1403.919 1562280.3 0.0012065 -1081860 -262.079 3.25458 -0.00291782 1.12726e-06 -53-38-3 631.36 24529 90056 880.88 1105.6229 2003704.4 0.0009955 -243170 -389.5 3.59976 -0.00377933 1.63349e-06 -53-39-4 527.22 23982 77762 811.2 1032.562 1867554.5 0.0009395 -647580 -332.17 3.15906 -0.0031188 1.2845e-06 -53-43-0 539.69 20983 77360 837.91 1074.376 2019947 0.0008935 -428910 -265.26 2.64544 -0.00231964 8.783e-07 -54-06-8 480.56 17860 65231 680.75 904.53734 4233039 0.0004615 -342950 -10.34 0.75822 -0.00036428 4.27e-08 -54-25-1 748.51 44722 111642 956.84 1180.5293 5962940.3 0.0005455 -796350 16.651 0.82486 -0.00019324 -8.82e-08 -54-91-1 505.52 36430 68696 709.02 928.43038 3341240.9 0.0007175 -200190 -57.786 1.3898 -0.00108 3.3032e-07 -55-18-5 35638 366.96 533.87632 3801003.8 -226550 -55-65-2 65483 690.95 930.16869 2761356.1 26310 -55-86-7 251.97 22636 42069 439.43 629.38014 2808382.1 0.0004895 -182030 46.734 0.52002 -0.0002146 4.1e-09 -56-03-1 67444 623.85 287520 -56-12-2 378.7 21456 52303 509.16 714.24514 4717123.5 0.0003125 -442370 10.343 0.4965 -0.0003098 7.54e-08 -56-18-8 376.56 26789 56668 532.11 726.80187 3598560.4 0.0004645 -46120 9.206 0.7738 -0.000438 9.27e-08 -56-23-5 223.13 7720 34064 368.97 586.94881 4802499.6 0.0002765 -135680 29.07 0.2518 -0.000284 1.086e-07 1330.42 -16.151 -56-29-1 626.86 17211 64646 782.49 1053.7876 3235655.4 0.0006425 -402080 -52.44 1.20614 -0.00066564 1.517e-07 -56-40-6 356.16 16276 47851 463.4 674.46585 6259013 0.0002005 -401090 12.161 0.3065 -0.000201 5.16e-08 -56-41-7 352.43 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0.0003275 -285570 -68.408 0.8696 -0.0007152 2.414e-07 297.46 -12.6 -1888-90-0 194.71 4713 32365 382.3 589.69977 3920939.7 0.0003315 28870 -44.95 0.6439 -0.00038828 8.5e-08 1093.34 -15.627 -1888-91-1 342.16 11370 47176 540.99 767.8908 3664206.3 0.0004485 -316540 -42.83 0.84002 -0.0003977 3.716e-08 -1888-94-4 213.91 17272 40152 429.09 617.39102 3159716.4 0.0004285 -384550 33.052 0.50572 -0.0002536 3.13e-08 -1889-08-3 288.71 7671 40602 491.39 717.3947 3501278 0.0004345 -210120 -55.31 0.85842 -0.00037 1.63e-08 -1889-96-9 461.31 9606 72495 677.91 878.52005 3810394.8 0.0005065 -565790 -76.43 1.27258 -0.001273 5.642e-07 -1889-98-1 450.31 6 46015 620.07 877.97522 3302946.2 0.0004965 -571570 -50.53 1.04298 -0.000871 3.642e-07 -1889-99-2 460.29 10803 62251 651.89 878.42375 3704459.7 0.0005495 -387230 -73.53 1.27678 -0.001314 5.885e-07 -1890-04-6 273.13 15504 39834 456.09 698.77407 5273902.8 0.0003655 4050 -32.04 0.6044 -0.00045028 1.32e-07 918.25 -14.978 -1891-45-8 390.51 14843 64383 665.09 879.81227 2191782.7 0.0007485 -354250 -197.57 2.13198 -0.00190564 7.451e-07 -1892-29-1 325.28 22552 71490 613.04 804.90713 5220689 0.0004055 -346610 49.034 0.44058 -0.0001742 8e-10 -1892-57-5 42550 547.55 749.74863 2147321.7 69080 -1898-13-1 319.98 22789 64685 722.05 956.92036 1450142.1 0.0009625 -259660 -49.53 1.5526 -0.0005252 -6.12e-08 3525.87 -22.123 -1899-05-4 364.53 14496 64489 711.5 972.99145 2073649.4 0.0008095 -605730 -81.15 1.45061 -0.0004351 -1.123e-07 -1900-58-9 321.46 13586 49251 576.65 779.46742 1795461.1 0.0007745 -556260 -92.968 1.7208 -0.0012458 3.971e-07 -1903-22-6 259.02 16622 44388 490.33 695.38853 2969804.5 0.0004905 -389520 -35.209 0.88472 -0.0005225 1.074e-07 1595.17 -16.608 -1906-79-2 261.59 16429 41097 456.91 678.21456 4088147 0.0004235 75510 -32.539 0.74602 -0.0004846 1.132e-07 -1906-82-7 302.3 22363 49539 499.14 687.26938 3407887.7 0.0004385 -543560 28.992 0.56724 -0.0002379 4.56e-09 -1907-46-6 241.4 11870 48115 468.27 640.42047 2976288.8 0.0004725 -244000 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25248 47429 520.2 712.87398 2278410.4 0.0006235 -480270 -29.895 1.10472 -0.0005307 6.58e-08 1819.43 -17.196 -1927-68-0 247.37 20068 42977 474.44 672.02671 2761356.1 0.0005115 -438990 -28.077 0.91472 -0.0004219 4.2e-08 1631.11 -16.798 -1927-70-4 221.1 13955 40363 451.12 655.83738 3089852 0.0004495 -423630 -28.85 0.82564 -0.0003707 2.96e-08 1574.77 -16.733 -1928-30-9 345.24 54393 68630 748.28 918.46335 809834.89 0.0013735 -543970 -20.61 2.28976 -0.001285 2.739e-07 2608.1 -19.152 -1929-77-7 319.26 30406 53460 563.49 752.11599 2267573.7 0.0006735 -252910 10.066 1.04415 -0.0005739 1.0856e-07 -1931-60-8 290.09 17708 48396 493.16 705.77935 3911137.4 0.0004075 -287530 36.161 0.4163 -0.0002768 6.742e-08 -1931-62-0 402.42 24964 59045 609.72 815.93156 2960117.7 0.0005205 -899750 12.47 0.84246 -0.000534 1.194e-07 2561.25 -18.466 -1931-63-1 286.79 28314 51981 535.28 709.67925 2269734.8 0.0006385 -652590 30.607 0.87352 -0.0004186 4.86e-08 1834.39 -16.993 -1931-83-5 431.01 47370 82690 880.7 1078.7209 791708.22 0.0014535 -1221950 -21.329 2.53276 -0.001497 3.149e-07 4000.6 -22.087 -1932-04-3 320.22 18606 47524 538.94 748.37453 2635251.7 0.0006275 5690 -162.248 1.708 -0.0012198 3.418e-07 -1932-92-9 246.68 18640 36215 385.22 571.48078 3713495 0.0003595 -192550 36.622 0.42512 -0.00020393 2.149e-08 -1936-40-9 289.43 28490 50518 522.18 717.63086 2250395.2 0.0006445 -244330 56.125 0.72272 -0.000347 3.64e-08 -1937-19-5 57669 554.76 808.88303 5438518.6 38280 -1937-54-8 235.4 21591 49870 550.75 739.65236 1910240.1 0.0007195 -201930 -21.798 1.22258 -0.0007801 2.0006e-07 -1937-62-8 341.14 49537 65253 696.7 867.1931 1122306.1 0.0011055 -635550 -3.156 1.77404 -0.000999 2.052e-07 2465.44 -18.876 -1937-63-9 341.14 49537 65253 696.7 867.1931 1122306.1 0.0011055 -635550 -3.156 1.77404 -0.000999 2.052e-07 2465.44 -18.876 -1940-18-7 272.02 6101 49359 494.61 693.08364 3699954.4 0.0004335 -291120 -114.689 1.21182 -0.0010554 4.014e-07 -1941-52-2 500.36 32741 132943 1024.66 1264.0564 3699954.4 0.0007685 -953540 51.043 1.14212 -0.0006078 9.91e-08 -1941-79-3 397.49 35980 83800 706.32 876.74894 2805407.9 0.0006295 -1168110 56.107 0.8172 -0.0003374 1.3e-09 5376.5 -24.641 -1942-45-6 286.02 19598 35554 391.64 579.00123 2999151.8 0.0004455 63850 13.174 0.61404 -0.00031926 6.298e-08 -1942-46-7 308.56 24778 40006 437.4 621.92111 2455600.3 0.0005575 22570 11.356 0.80404 -0.00042806 8.678e-08 -1942-52-5 239.86 20874 42262 450.31 647.4036 2937698.8 0.0005015 -132710 34.934 0.62874 -0.0002506 3.6e-09 -1943-08-4 436.6 51583 73054 742.77 919.02758 1311798.7 0.0010635 -399850 -7.626 1.74324 -0.0009795 2.0306e-07 -1943-09-5 492.09 59963 81770 818.92 1004.0851 1029923.8 0.0012645 -488030 -13.042 2.15664 -0.0012559 2.7806e-07 -1943-16-4 564.2 29212 70682 712.2 1010.0457 5953741.8 0.0003755 -120740 6.87 0.52948 -0.000458 1.41e-07 -1943-83-5 36189 372.34 561.34563 4634004 -126400 -1943-84-6 62968 655.23 822.63653 1297660.5 -399620 -1945-53-5 583.86 26762 77757 857.58 1097.8808 1723163.2 0.0009725 -512450 -230.23 2.65858 -0.00240724 9.324e-07 -1945-91-1 248.23 22826 45948 480.36 668.47884 2992592.7 0.0004595 -705150 33.161 0.57924 -0.0002516 5.3e-09 1725.24 -17.255 -1946-00-5 331.18 14921 69282 619.77 808.6706 3217328.3 0.0005445 -409670 -102.02 1.36274 -0.001109 3.978e-07 -1946-82-3 511.37 34991 74001 704.28 909.24583 3243030.1 0.0005715 -589320 11.174 0.93062 -0.0005605 1.2396e-07 -1947-58-6 346.08 17816 69950 606.92 797.95965 6259013 0.0004095 -388250 22.852 0.54 -0.0004038 1.232e-07 4771.46 -23.416 -1948-31-8 473.83 26288 69161 658.08 872.77833 4130292.6 0.0004535 -553320 11.31 0.74654 -0.0004549 9.966e-08 -1949-88-8 443.48 19933 117513 844.68 1034.2622 6631370.1 0.0004595 -1035020 28.561 0.7419 -0.0004604 1.051e-07 9817.26 -33.651 -1949-89-9 397.66 19368 101222 752.94 926.05619 5670271.4 0.0004465 -877510 24.952 0.702 -0.0004268 9.58e-08 8059.85 -29.98 -1951-11-7 229.61 12586 39626 419.41 619.64487 3881949.9 0.0003575 -275230 30.711 0.37532 -0.0002191 4.486e-08 1313.73 -15.911 -1951-12-8 310.36 16933 45659 473.62 677.7483 4205631.8 0.0003265 -497180 15.061 0.44732 -0.00029 7.29e-08 1665.16 -16.325 -1952-38-1 396.39 21294 65099 644.87 856.45912 3891642.7 0.0004895 -199300 -9.668 0.7598 -0.00038026 5.03e-08 -1952-67-6 643.38 25105 63347 752.91 1016.0507 3376278.5 0.0006015 -400430 7.152 0.85614 -0.0003644 5.8e-08 -1953-02-2 430.76 26066 63419 625.97 849.93607 4684891.8 0.0004285 -522710 22.301 0.61102 -0.0003763 8.286e-08 -1953-33-9 602.02 26021 60088 702.75 957.83044 3782325.6 0.0005115 -491610 73.143 0.35422 0.0003608 -3.112e-07 -1954-28-5 402.94 43816 60792 631.22 812.62543 2073649.4 0.0007355 -938290 28.138 1.1868 -0.0005976 9.36e-08 1350.78 -15.338 -1955-45-9 233.8 7012 32721 374.93 565.38397 4200182.4 0.0003045 -369610 -71.36 0.87644 -0.0009528 4.184e-07 -1961-77-9 679.26 26494 92746 979.35 1226.3624 1849924.8 0.0010445 -536960 -274.74 2.99066 -0.00288298 1.17936e-06 -1968-40-7 209.22 16975 37913 414.66 591.00882 2944078.1 0.0004345 -379660 18.943 0.59402 -0.0002853 3.24e-08 1294.12 -16.265 -1969-43-3 213.42 20254 38038 427.94 591.3557 2269734.8 0.0005575 -361310 20.207 0.79564 -0.0003548 4.11e-08 1279.97 -16.419 -1972-28-7 50434 602.52 809.52996 2388849.2 -754510 -1974-04-5 213.45 15648 37223 425.48 612.19681 3042316.5 0.0004835 -166760 3.034 0.71294 -0.0004316 1.057e-07 1292.16 -16.287 -1974-05-6 213.45 15648 37223 425.48 612.19681 3042316.5 0.0004835 -166760 3.034 0.71294 -0.0004316 1.057e-07 1292.16 -16.287 -1975-78-6 267.45 23162 48332 530.48 711.86594 2060492.3 0.0006215 -84850 10.798 0.88862 -0.0004892 1.015e-07 -1977-33-9 574.71 35736 99874 858.64 1055.9954 3079572.5 0.0006815 -977600 -11.026 1.25254 -0.0008585 2.2826e-07 -1984-77-6 345.65 45089 60814 634.71 809.30853 1559813.2 0.0008795 -729410 -18.259 1.52192 -0.0009039 2.008e-07 1823.59 -16.576 -1985-48-4 345.76 12721 42782 499.95 739.20883 3906250 0.0003965 -239540 -20.85 0.59962 -8.7e-05 -9.41e-08 -1985-84-8 523.26 70056 87160 890.12 1100.068 1189060.6 0.0011695 -1198450 -119.104 2.45664 -0.0015224 3.436e-07 987.76 -12.856 -1989-50-0 488.23 13968 57095 639.69 896.78428 4305564.2 0.0005195 -389270 -203.21 1.8142 -0.0020226 8.928e-07 -1989-52-2 666.68 72759 111728 1233.94 1546.9659 499137.09 0.0021125 -941240 -298.995 4.80032 -0.00358644 1.157e-06 -1996-88-9 303.54 26843 29318 536.45 667.99871 1025312 0.0010455 -3937800 -79.348 2.46592 -0.0023216 7.879e-07 -1999-33-3 622.02 36607 86936 784.92 1007.933 4795850.2 0.0004945 -626830 26.842 0.7745 -0.0004764 1.0212e-07 -1999-34-4 534.5 36531 78592 750.18 972.1765 3704459.7 0.0005695 -526810 31.683 0.83001 -0.0004659 8.446e-08 -1999-46-8 481.37 27945 73225 703.4 915.45363 3302946.2 0.0005595 -599880 7.81 0.94246 -0.0005669 1.2296e-07 -2000-40-0 447.42 21163 74245 645.61 862.92779 5367038.3 0.0004225 -344050 30.61 0.585 -0.0004793 1.4516e-07 -2001-95-8 1754.2 150539 242904 2523.74 6288.9566 313480.57 0.0032035 -3988730 318.77 3.42612 0.0008162 -1.4299e-06 -2002-24-6 269.93 12736 51898 448.2 636.60739 5296958.1 0.0002535 -274600 46.152 0.1934 2.82e-05 -6.62e-08 -2003-31-8 324.58 12351 39287 416.75 649.39852 5044227.8 0.0002405 316190 47.61 0.0806 -3.666e-05 6.18e-09 -2003-32-9 352.72 12560 44275 472.46 739.79331 5153446.4 0.0002795 408800 46.41 0.1128 -9.766e-05 3.708e-08 -2003-82-9 289.47 11933 30859 343.4 559.908 6132226.8 0.0002275 193380 25.91 0.17722 -0.00011866 3.758e-08 -2004-67-3 187.48 9271 44651 425.18 596.16933 3686487.8 0.0003665 -209040 -1.639 0.59364 -0.0003614 8.87e-08 -2004-70-8 139.27 7628 26012 314.84 490.59779 3886791.7 0.0002765 96120 -18.83 0.47882 -0.0003549 1.131e-07 692.32 -15.186 -2008-41-5 300.53 25950 54910 585.49 779.17419 2104200 0.0007175 -284110 5.793 1.15099 -0.0006347 1.1946e-07 -2008-75-5 259.73 16483 42702 467.71 678.33211 2989321.2 0.0004945 -126750 -34.398 0.8614 -0.0004858 8.66e-08 -2009-74-7 209.77 14754 39718 440.23 628.48965 2881205.9 0.0004635 -209090 -12.889 0.76176 -0.0004797 1.2186e-07 1323.97 -16.205 -2009-83-8 248.12 19581 50014 466.49 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3356745.5 0.0004715 -333230 -83.25 1.0338 -0.000591 1.216e-07 -87310-12-1 334.95 46745 63069 669.66 835.2469 1156138.7 0.0010695 -732130 11.935 1.65904 -0.0008608 1.459e-07 2395.04 -18.591 -87324-44-5 583.78 42640 75618 775.66 1004.4247 2841412.8 0.0006155 -840330 -136.85 1.609 -0.0012222 3.71e-07 901.02 -12.044 -87340-27-0 478.13 51010 90226 862.47 1066.2687 1699097.9 0.0009865 -733500 -79.328 1.97866 -0.00139564 3.824e-07 -87362-54-7 284.17 23317 49437 549.33 760.51677 2276236.8 0.0006215 -521850 -86.58 1.30904 -0.0007248 1.27e-07 943.13 -14.592 -87365-91-1 223.91 38081 32468 535.02 666.3155 1159290 0.0009465 -4146050 64.17 1.53062 -0.0011578 2.925e-07 -87373-47-5 405.71 14471 47272 541.08 801.89386 4114411.9 0.0004765 115590 -188.35 1.59572 -0.001572 6.398e-07 -87384-00-7 242.85 25386 50560 525.88 716.3675 2475186.3 0.0005735 -766010 31.961 0.76908 -0.000365 3.27e-08 -87392-05-0 344.18 20763 48655 501.74 723.6729 4835954.7 0.0003015 -568320 -40.22 0.6583 -0.0004343 1.071e-07 1687.95 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727.78 919.3546 1804625.5 0.0008605 -786100 19.082 1.38292 -0.0007345 1.1446e-07 -87694-52-8 397.04 27652 65276 667.17 856.68472 1935535.4 0.0007875 -751400 10.51 1.33564 -0.0007441 1.2946e-07 -87777-46-6 257.71 16493 49163 464.06 641.10655 3341240.9 0.0004525 -79340 11.322 0.71574 -0.00044413 1.1119e-07 -87827-60-9 309.1 26309 70824 612.32 771.65086 2535371 0.0006275 -559470 2.698 1.02772 -0.0005842 1.269e-07 4729.04 -23.44 -87842-52-2 355.07 20619 48901 540.94 772.2672 3195540.6 0.0005715 -402300 -122.108 1.57046 -0.0016002 6.9e-07 -87853-82-5 303.79 21431 65858 616.16 811.68715 3243030.1 0.0004805 -394800 30.661 0.60264 -0.0003502 6.95e-08 -87954-39-0 207.61 12805 36702 424.54 626.67045 2802438.5 0.0004575 -148800 -42.88 0.83896 -0.00041164 5.66e-08 887.44 -15.243 -88057-40-3 1015.45 42845 75270 814.4 1120.9818 1543918.7 0.0011725 857490 -218.73 3.1152 -0.0034443 1.5979e-06 -88090-34-0 307.84 5182 36940 454.68 699.57873 4468243.3 0.0003995 244450 -236.85 1.7832 -0.00220412 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-0.0025236 7.485e-07 +302911940 371.74 17737 47405 552.32 777.26364 3156167.2 0.0005255 -244720 -112.64 1.44046 -0.00129198 4.939e-07 +316186171 328.09 17326 58112 556.18 749.56469 3456140.4 0.0004775 -649240 -29.21 1.01546 -0.00080098 2.885e-07 +321744143 427.98 33424 78578 735.66 930.93561 2220798.9 0.0007415 -1013280 -26.2 1.34898 -0.0007072 9.27e-08 +321744165 427.98 33424 78578 735.66 930.93561 2220798.9 0.0007415 -1013280 -26.2 1.34898 -0.0007072 9.27e-08 +321744176 427.98 33424 78578 735.66 930.93561 2220798.9 0.0007415 -1013280 -26.2 1.34898 -0.0007072 9.27e-08 +321744187 427.98 33424 78578 735.66 930.93561 2220798.9 0.0007415 -1013280 -26.2 1.34898 -0.0007072 9.27e-08 +321744198 427.98 33424 78578 735.66 930.93561 2220798.9 0.0007415 -1013280 -26.2 1.34898 -0.0007072 9.27e-08 +321744212 427.98 33424 78578 735.66 930.93561 2220798.9 0.0007415 -1013280 -26.2 1.34898 -0.0007072 9.27e-08 +321744234 427.98 33424 78578 735.66 930.93561 2220798.9 0.0007415 -1013280 -26.2 1.34898 -0.0007072 9.27e-08 +321744267 412.03 30275 74494 702.6 894.81138 2258959.9 0.0007255 -978880 -41.62 1.42318 -0.0008266 1.478e-07 +329910396 371.4 28265 62208 648.15 853.34347 2102270.9 0.0007235 -840710 -37.43 1.34148 -0.0007322 1.111e-07 +336111207 275.26 10577 43907 439.5 638.74426 4498261.6 0.0003065 -342180 36.92 0.36044 -0.0001107 -1.694e-08 +339152942 503.28 19692 56925 639.11 908.1159 4522494.7 0.0004355 -320960 95.07 0.1383 0.0002 -1.62e-07 +339152953 488.36 19018 52928 602.12 862.22524 4704191.1 0.0003925 -299940 83.861 0.1256 0.0002236 -1.705e-07 +339152964 518.24 20106 54978 630.85 900.88959 5470746.8 0.0004055 -257870 79.161 0.157 0.0001726 -1.454e-07 +352356388 486.15 31939 72137 739.71 958.5554 2329273.6 0.0007135 -879860 -63.36 1.43746 -0.000853 1.663e-07 +357188740 175.7 4967 23551 306.83 483.07528 5015689.1 0.0002345 -459250 -3.03 0.38142 -0.000361 1.298e-07 +369403087 570.87 29729 87665 832.13 1046.1747 2670779.7 0.0007305 -1016850 -108.06 1.76336 -0.001416 4.741e-07 +489446857 478.4 31449 69739 712.56 928.60509 2497501.9 0.0006655 -853060 -57.33 1.35206 -0.000845 1.843e-07 +500003010 197.39 15974 35057 394.64 560.69319 2550760.1 0.0004955 -146200 -16.757 0.89368 -0.0005272 1.209e-07 +500005276 190.57 11082 31544 358.84 524.38203 3333528.9 0.0003515 -410970 49.343 0.35244 -2.62e-05 -6.13e-08 1025.42 -16.009 +500015532 353.65 27756 51977 538.89 741.87853 3195540.6 0.0004885 -124460 1.715 0.74938 -0.0004296 9.05e-08 +500023950 162.76 10042 30700 348.17 517.03868 3745380.1 0.0002975 -644560 29.07 0.34674 -0.0001188 -1.56e-08 +500023961 189.03 16155 33314 371.49 536.40892 3310552.3 0.0003595 -659920 29.843 0.43582 -0.00017 -3.2e-09 +500033421 214.13 11700 36442 406.11 602.67422 3745380.1 0.0003465 -417810 -32.52 0.66032 -0.0003818 7.25e-08 962.65 -15.03 +500116881 258.08 17300 38953 485.9 652.93694 2407640.5 0.0005035 -1519010 25.761 0.7821 -0.0006222 1.737e-07 +727411247 389 20007 59616 572.73 812.94311 4414962.3 0.0004095 -141050 -35.02 0.8042 -0.00043798 7.066e-08 +850411211 379.12 30055 59811 608.81 799.45191 2550760.1 0.0005835 -901920 23.034 0.86074 -0.000447 6.63e-08 2354.36 -17.793 +1235106667 633.28 21029 78306 907.67 1248.9504 4260714.8 0.0009565 -110630 -193.3 2.2602 -0.002347 1.004e-06 +1243297100 289.07 13706 50620 579.84 761.50436 1527071.7 0.0008395 -757010 14.352 1.40776 -0.0007548 1.338e-07 2551.67 -19.522 diff --git a/chemicals/Misc/webbook_constants.tsv b/chemicals/Misc/webbook_constants.tsv index cfeb9653..4b5cfc54 100644 --- a/chemicals/Misc/webbook_constants.tsv +++ b/chemicals/Misc/webbook_constants.tsv @@ -1,13780 +1,13780 @@ CAS Tt Tm Tb Tc Pt Pc Vc Hfs Hfl Hfg S0s S0l S0g Hsub Hfus Hvap AntoineTmin AntoineTmax AntoineA AntoineB AntoineC -100-00-5 356 515.18322 -48740 74700 -100-01-6 420 -44646.056 55200 101000 415.6 609 27.518563 10573.213 52.016 -100-02-7 385 552.2 -208934.35 -115729.27 93067.607 -100-06-1 311.8607 531.2 -100-07-2 294 417 -335900 -261800 74100 -100-09-4 456.76437 -561700 -451900 413 111314.12 92000 -100-10-7 347 -137000 -100-11-8 372.7 -100-12-9 518.7 -55310 -100-17-4 327.1 547.2 -100-18-5 256.09085 481.10563 794.15 9777860 -132300 56500 393.41 484.73 20.303274 3779.5553 -81.204 -100-19-6 353.65 449.21051 -100-20-9 539.2 -357562.45 226.1 -100-21-0 -816277.57 146519.44 -100-22-1 533.2 39600 -100-23-2 436.9 -37388.004 64414.188 101802.19 -100-25-4 444.77266 -38000 94721.401 525 564.7 14.309392 385.25242 -429.356 -100-29-8 556.2 -100-36-7 419.2 -100-37-8 414.04939 -310000 53521.578 -100-39-0 271.75 471.43703 22035.601 84000 53123.705 305.4 471.7 22.273873 4704.4922 -34.57 -100-40-3 400.76311 29700 69500 39338.363 -100-41-4 178.1177 179 409.3 617 3640000 0.000374 6590.2281 48791.449 255.25678 360.6 41000 420 600 21.656642 3902.9416 -23.698 -100-42-5 242.47 241 419 87743.469 136548.78 240.17988 345.1 43681.521 305.6 355.34 20.859809 3361.5647 -59.551 -100-44-7 233.17439 452 -33000 19000 49956.05 295 452.6 22.295079 4448.9214 -39.396 -100-46-9 440 34175.029 87775.029 55413.352 302 457.7 22.627734 4613.2937 -41.973 -100-47-0 260.33 263 464 701 4215001.4 0.00032927231 163200 219000 209.1 55640 301.4 463.8 22.689697 4859.7716 -28.331 -100-48-1 352.4 210300 283500 73200 -100-49-2 455.17157 -378000 -100-50-5 177.1 437.37404 -100-51-6 257 478 -155040.69 -94740.687 216.7 63000 395.67 478.56 21.821898 4003.9652 -89.559 -100-52-7 216.02 246.88764 452 689.04929 4361356.5 -85303.046 -35935.987 221.2 48000 273.14 322.06 23.520815 5382.3825 -5.103 -100-53-8 467.66516 38480.518 91654.757 52715.19 -100-54-9 323.31212 491.84456 205644.16 277744.16 72100 -100-56-1 0 -100-60-7 422.2 -100-61-8 216 468 5197970 33384.351 83916.767 50560.799 323 472.76 23.012243 5126.8807 -22.456 -100-63-0 291.13623 514.40065 141075.87 203007.97 61892.818 345 516.7 23.453003 5711.0166 -37.496 -100-64-1 362.5 362 481.2 -153200 -74880 185.09946 78740.847 63100 -100-65-2 352.15 -100-66-3 250 427 643 4200000 0.00034129693 -117118.5 -71720.483 44000 383.03 437.26 21.131422 3430.29 -69.607 -100-68-5 256.44 461.13243 44557.897 97472.699 252.5 52000 390.3 474.77 21.037315 3693.0863 -79.166 -100-69-6 157000 -100-70-9 302.15 492.04363 210000 280700 70700 -100-71-0 210.05 421.88747 1500 44700 -100-72-1 460.16332 -100-74-3 210.15 411.70929 42100 -100-75-4 -31000 17000 -100-76-5 430 -55100 -4300 206.98 50800 -100-79-8 461.7 -100-80-1 250.78 191.57132 444.18528 340.8 442.3 21.224631 3648.4369 -66.922 -100-81-2 476.7 -100-83-4 513.2 100100 -100-84-5 217.5444 448.71344 665.3 -155400 -100-86-7 488.2 -100-97-0 124078.89 198978.89 163.38 78865.839 -1000-50-6 411 -1000-63-1 397.11934 -403300 -361000 42383.205 -1000-86-8 157.45537 366.6 -1000-87-9 356 -100046-00-2 107000 -10006-28-7 -1548080 -1499300 145.91 184.23 -1002-26-2 376.5 -1002-35-3 393 -1002-43-3 217.64141 -1002-57-9 -694000 -524000 170000 -1002-67-1 201.5 -1002-69-3 496.59416 64000 359.3 498.8 20.991793 3860.9586 -91.133 -1002-84-2 325.68 326 775.43 1551340 156000 -100207-68-9 58900 131300 72200 -10022-50-1 107.2 200.8 -108780 260.25 -10024-43-8 -49400 252.89 -10024-97-2 309.59149 87899.097 7252895.9 9.55e-05 82050 219.96 129.8 187.7 21.59362 1430.0826 -44.659 -10025-67-9 248.80693 -58160 -16740 223.84 327.19 265.8 411 20.872473 3263.7532 -61.685 -10025-74-8 283000 -10025-78-2 305 -496220 313.71 275.3 304.8 21.220831 2694.0246 -27 -10025-82-8 160893.41 -10025-87-3 274.275 601 4960000 0.000276 -559820 325.45 275 378.3 21.371812 3329.4436 -40.119 -10025-91-9 798 0.000254 322.4 492 19.040352 2765.1376 -125.836 -10026-03-6 347 464.7 29.779448 8031.8382 -24.494 -10026-04-7 204.4 330.13022 0 -662750 330.86 298 313 22.631925 3722.2347 5.305 -10026-07-0 105000 506 665 22.087847 5738.0397 -121.43 -10026-11-6 778.2 5805863 0.000319 -980520 -869980 181.41 367.69 463 604 31.638624 11408.174 -36.557 -10026-12-7 -797470 -773350 -703330 214.05 260.97 404.07 95000 -10026-13-8 364.21 71100 328.7 435 22.29402 2994.4751 -157.173 -10026-17-2 -671530 -637690 -356480 82.01 86.24 278.02 -10026-18-3 -790360 94.52 -10028-15-6 80.7 161.3 261.1 142670 238.92 92.8 162 21.267528 1640.5619 6.982 -10028-18-9 1350 1556 24.0129 16746.593 -433.953 -10028-22-5 -2583000 307.46 -1003-03-8 190.45 187.45 381.20999 -95140 -54860 241.04 40250 -1003-04-9 448.2 -135300 50100 -1003-09-4 204.3 203.9 423.2 219.7 333.4 373.5 19.33985 3373.8122 0.878 -1003-10-7 -196200 38200 -1003-14-1 364.85 -1003-17-4 158.69 363.77412 -1003-19-6 167.125 361.8063 -1003-29-8 491.2 -106400 -1003-30-1 378.34666 -1003-31-2 465.2 49500 -1003-38-9 144.25 366 -1003-49-2 393.52847 -1003-64-1 180.3 410 -103600 42000 -1003-67-4 5687.5601 82420.275 -1003-73-2 8800 82200 -10030-74-7 -665380 -10031-18-2 104180 271.54 -10031-22-8 -277400 -267410 -104390 161.19 173.88 339.39 -10031-82-0 525.28529 -10031-87-5 432 -10031-92-2 -405723.27 -10034-85-2 222.15 26404.213 206.59 149.8 238.1 21.341602 2164.4162 -18.012 -10034-94-3 -2176940 -2113880 94.96 123.01 -10035-10-6 186.12253 -36392.629 198.7 206.7 343.8 21.082124 1738.3804 -25.086 -10036-09-6 -254000 -10036-47-2 105 200 309.4 3710000 -8370 301.18 -10038-98-9 228 357 19.991619 2487.0245 -63.588 -1004-36-0 522.2 -1004-66-6 455.7 -10043-11-5 -250910 476980 14.77 212.36 -10043-35-3 -1094245.8 -992280 89.094755 295.23 -10043-52-4 -795800 -774090 -471540 104.62 123.87 290.26 -10043-92-2 176.23 129 211.8 18.860014 1285.5171 -36.803 -10049-04-4 104600 257.22 214 284.3 19.18728 1484.2026 -90.46 -10049-06-6 -515470 -237230 87.29 278.34 -10049-60-2 422.59 -1005-51-2 366.5 262300 334100 174.66 336.85 71815 -1005-64-7 230.05 471.93608 -1005-68-1 444.03449 -100508-56-3 -697100 -100508-57-4 -907700 -10051-06-6 95700 -10051-96-4 534.2 -10052-18-3 -130900 -100569-88-8 395000 -1006-59-3 310.8 491.70673 -1006-65-1 75300 139000 64000 -1006-67-3 80300 160000 79900 -10060-32-9 357 -10060-33-0 375.7 -10061-01-5 377.4792 -10061-02-6 385.15008 -100652-57-1 347.1529 -1007-26-7 458.70111 -1007-42-7 276.1 -10075-69-1 98600 -1008-17-9 495 -1008-74-8 14000 98700 84900 -1008-75-9 18000 103000 84100 -1008-76-0 579.2 -1008-88-4 66886.152 -1008-89-5 542.2 68516.45 -1009-93-4 254.4 461 -10097-28-6 -100420 211.58 -10097-32-2 111863.16 175.01937 -10099-70-4 243 -10099-76-0 -1144990 109.9 -101-02-0 295.15 -101-05-3 432.48 -101-18-8 613.2 -101-20-2 182200 -101-21-3 315.13374 -101-25-7 222498.12 -101-27-9 345.59 -101-33-7 173.15 -101-37-1 300.585 -101-41-7 491.2 57400 -101-42-8 406.3074 -203000 -101-53-1 359 595.2 -54000 63510 117700 -101-54-2 339 627 -101-55-3 291.9 578.2 -101-60-0 -1106900 -101-61-1 663 -101-68-8 313.57 -54397.68 189000 332.5 442 530 17.084974 2233.3371 -253.28 -101-77-9 364.10924 471 545 13.684493 964.2927 -356.851 -101-80-4 464.4996 -17000 241 -101-81-5 299 535 780 2790675.8 0.000563 75105.512 97048.2 163880.29 239.3 436 87355.531 65000 -101-82-6 549.2 69900 -101-83-7 529.15183 -226800 -101-84-8 300.01044 300.1 531.58895 769.43741 3141070 -32110 233.91 66567.323 477.36 544.09 21.038213 4145.6087 -95.324 -101-97-3 501.22863 62313.374 -101-99-5 326 381 510 28.374019 7710.1463 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+98102 429.65 -561900 115300 +98135 233.4 474 314.7 374.8 470.6 20.972636 3778.5421 -74 +98157 410.7026 +98168 460.2 -686010 +98179 451.09716 +98180 413.35 -581600 +98191 254.9 477.02308 56600 +98271 72100 +98293 327 558.2 775 3700000 0.00055865922 -474000 -374700 99229.678 96500 +98464 475.7 +98511 222 464 -57000 52200 +98533 321.2 +98544 372 507 -294649.69 -193130.61 88699.025 67900 471.27 524.8 20.995547 3734.8782 -118.559 +98555 308.17208 490.70105 357 490.1 21.710891 4248.182 -74.617 +98566 410.92868 -323700 +98737 436.72591 -502900 -398500 104400 +98828 177.13 177 425 630.77319 3196082 0.00043103448 -41200 3900 277.57 386.53 44000 343.17 426.52 20.848043 3352.1287 -65.948 +98839 248.11634 438 645 3550000 0.00040983607 118300 243.8 48756.867 280.6 438.6 23.53166 5357.8093 7.23 +98840 54900 +98851 293.88051 476.76402 75200 +98862 293 475 710.9269 4229792.6 0.00038353652 -142500 -86700 372.88 54905.469 310.3 475.6 22.217551 4619.8998 -43.472 +98873 256.2 450.3 308.6 487 21.458919 4429.4254 -41.157 +98884 272.04915 471 -158527.81 -109000 54800 305.3 470.4 22.134658 4555.4965 -41.011 +98895 301.9603 505.7 +98920 401.96407 -134900 121200 +98942 431.7 -134800 +98953 278.9 484 12464.542 68530 224.3 54842.233 407.3 483.78 21.219542 3977.9276 -73.438 +98964 463 +98986 -343800 95290.008 +980712 406 +98057262 553.7 +98057273 589 +98068292 559.15 +98184179 -183000 +98184180 -193600 +98184191 -194000 +98260130 411.15 +98841691 262.01 +98930893 547.15 +99025 501.2 +99036 562.7 -173000 +99047 384.00458 536.2 -425015.48 -328015.48 97000 +99058 452.9 -414834.4 -289300 128000 +99069 408.67917 -592985.7 -467985.7 177 121815.76 +99070 539.7 +99081 288.70941 504.71912 -46000 +99092 386 -35036.466 62500 96750 392.5 578.9 24.974183 7617.6515 -12.776 +99309 467.31772 109200 +99343 -432600 +99354 395.71282 -37000 107300 +99490 502.76959 330.6 500.7 23.094284 5407.0708 -33.473 +99514 301.7 +99547 528.7 -109700 84651.367 65200 +99592 -232000 +99616 331.00929 -120000 +99627 210.02 476.39833 -132300 56200 +99638 549.2 -339793.47 +99650 363 570.2 -26953.255 -36000 87000 +99661 493.2 +99718 331 512 -256400 -190300 66100 344.6 515.3 23.366933 5630.3801 -39.784 +99752 -393300 -312600 81715.052 +99763 398.4 98800 83100 +99821 155.15 443 +99832 293 448 22.292915 4383.1987 -41.163 +99854 456.19972 51400 +99865 447.19704 +99876 204.2 204 450 652.00164 2800000 -78007.83 306.7 49190.014 380.19 451.57 21.096607 3682.5013 -65.491 +99887 498.2 +99898 334 500 -270000 -177268.73 87085 381.3 501.4 24.814568 6450.7635 -15.386 +99901 324 528.2 +99912 291.55 505.2 395.16 485.09 21.296011 3965.2242 -79.206 +99923 379.00203 567.2 -182000 +99934 316.24956 +99945 454.98526 547.7 -428643.92 -329843.92 98656.18 +99967 488.36942 -602854.71 -488854.71 175.7 115163.71 +99978 483.97496 11700 68900 57200 323.3 482.7 20.070967 3141.3132 -116.036 +99989 536.19972 +99990 324.78 325 511 -48200 30900 75504.935 420.86 506.4 20.936025 3914.0677 -90.468 +992916 -844000 -803800 47895.123 +992983 374 +993077 282.00574 +993168 -446700 +993500 -55600 -17900 37700 +993624 -376500 -313700 62800 +993635 -211100 -148300 62800 +99363129 392.09513 +99363130 409.1 +99363141 409.30756 +994058 359.34586 -341790 -306500 35000 +994309 268.3 419.5 21.595577 3828.9227 -39.14 +994310 50700 +994490 622.7 +994650 -290100 -228600 61500 389.59 497.69 20.671389 3622.0792 -106.148 +99493557 -905490 +995244 42600 +996350 337.9999 +996509 37900 +996703 680 2400000 0.00064516129 53900 +99685968 2320000 2560000 190000 +997499 54000 +997502 -41300 2200 43500 +997762 439000 520400 81300 +997955 -206000 -139500 66500 +998298 446 39100 +998301 404.6 +998414 42900 +998947 388.97729 +999780 190.78 356.00094 +999906 405 42900 +999973 398.6561 42200 +99977249 378.15 +9998907 -451000 diff --git a/chemicals/Misc/wikidata_properties.tsv b/chemicals/Misc/wikidata_properties.tsv index 5b1a3df4..8a2f17b1 100644 --- a/chemicals/Misc/wikidata_properties.tsv +++ b/chemicals/Misc/wikidata_properties.tsv @@ -1,10068 +1,10068 @@ CAS Tm Tb Hfus Hvap Hf S0 LFL UFL T_flash T_autoignition RI RIT logP -100-00-5 356.48333 515.37222 400.37222 -100-01-6 419.26111 605.37222 472.03889 -100-02-7 386.15 -100-06-1 311.15 -100-07-2 295.15 -100-09-4 457.15 -100-10-7 347.15 -100-11-8 372.15 -100-13-0 300.15 -100-14-1 345.15 -100-15-2 426.15 -100-17-4 325.15 -100-18-5 256.15 -100-19-6 352.15 -100-20-9 354.15 -100-22-1 323.15 -100-23-2 438.15 -100-25-4 445.92778 572.03889 -100-28-7 331.15 -100-37-8 203.15 435.92778 0.067 0.117 325.37222 -100-39-0 269.15 -100-41-4 178.15 409.26111 0.008 0.067 285.92778 1.495 -100-42-5 242.59444 418.15 0.009 0.068 304.26111 -100-44-7 234.26111 452.03889 0.011 340.37222 -100-46-9 230.15 -100-47-0 260.15 -100-48-1 351.15 -100-50-5 275.15 -100-51-6 258.15 478.15 -100-52-7 247.15 335.15 -100-53-8 243.15 -100-54-9 323.15 -100-55-0 266.15 -100-60-7 265.15 -100-61-8 215.92778 468.70556 352.59444 -100-63-0 292.59444 360.92778 -100-64-1 362.15 -100-66-3 235.85 426.75 0.012 0.063 325.15 748.15 1.5174 2.11 -100-69-6 223.15 -100-70-9 300.15 -100-71-0 210.15 -100-74-3 210.37222 411.48333 305.37222 -100-79-8 246.15 -100-80-1 191.15 -100-83-4 377.15 -100-86-7 297.15 -1000-70-0 250.15 -1000520-92-2 379.15 -100063-22-7 420.15 -1001-53-2 320.15 -100124-06-9 562.15 -1002-57-9 468.15 -1002-84-2 326.15 -10022-31-8 863.15 -10024-97-2 182.03889 184.81667 219.9 -10025-65-7 -107000 -10025-66-8 1173.15 -870300 -10025-67-9 195.92778 410.92778 391.48333 -10025-74-8 -983000 -10025-78-2 146.15 -10025-82-8 -537000 -10025-83-9 1036.15 -240000 -10025-87-3 274.26111 378.70556 -10026-12-7 2320.15 -10026-13-8 433.15 -10028-15-6 80.372222 161.48333 238.9 -1003-03-8 188.15 -1003-29-8 316.15 -1003-56-1 413.15 -1003-67-4 457.15 -1003-68-5 458.15 -1003-73-2 311.15 -1003-90-3 378.15 -1003-99-2 317.15 -1003043-40-0 455.15 -10031-22-8 646.15 1166.15 -281900 -10031-26-2 -268000 -10031-82-0 287.15 -10034-85-2 222.35 237.79 26600 206.6 -10035-10-6 186.48333 206.48333 198.7 -100365-72-8 398.15 -100377-63-7 484.15 -10038-98-9 -531000 -1004-36-0 407.15 -1004-38-2 523.15 -10040-95-6 339.15 -10041-02-8 479.15 -10041-06-2 389.15 -10042-76-9 843.15 918.15 -10043-01-3 973.15 1873.15 -10043-52-4 1045.15 2208.15 -10049-04-4 214.26111 284.26111 -10049-05-5 1097.15 1393.15 -10049-14-6 1309.15 1690.15 -1005-39-6 462.15 -100523-96-4 334.15 -100564-78-1 351.15 -1006-41-3 441.15 -1006-94-6 327.15 -10061-02-6 189.26111 380.92778 0.053 0.145 298.15 -1007-15-4 329.15 -1007-16-5 413.15 -100704-10-7 338.15 -10075-50-0 364.15 -10075-62-4 358.15 -10075-85-1 528.15 -1007605-44-8 364.15 -100796-79-0 373.15 -1008-89-5 268.15 -1008-91-9 412.15 -1008304-87-7 435.15 -100846-24-0 342.15 -100859-84-5 475.15 -1009-14-9 264.15 -1009-22-9 391.15 -1009-35-4 365.15 -100905-33-7 374.15 -1009813-26-6 908.45 -10099-74-8 743.15 1.782 -101-01-9 417.15 -101-02-0 296.15 -101-10-0 388.15 -101-14-4 383.15 -101-18-8 353.15 -101-37-1 300.15 -101-53-1 356.15 -101-54-2 347.15 -101-55-3 291.15 -101-61-1 360.15 -101-68-8 310.37222 587.03889 472.03889 -101-70-2 375.15 -101-72-4 350.15 -101-75-7 356.15 -101-77-9 365.37222 670.92778 463.15 -101-79-1 375.15 -101-80-4 464.15 -101-81-5 297.15 -101-82-6 283.15 -101-83-7 271.15 -101-84-8 300.92778 532.03889 0.007 0.06 388.15 -101-90-6 307.15 -101-97-3 244.15 -10101-63-0 685.15 -10102-03-1 305.45 320.15 -10102-43-9 109.26111 121.48333 81000 -10102-44-0 263.70556 294.26111 33100 240.1 -10103-60-3 -1157000 -10105-60-9 310.15 -101066-61-9 321.15 -101080-58-4 438.15 -101084-96-2 452.15 -101096-72-4 309.15 -1011-15-0 319.15 -1011-17-2 398.15 -1011-65-0 398.15 -1011-95-6 256.15 1.595 -1012-72-2 350.15 -101209-08-9 413.15 -10129-78-9 424.15 -1013-25-8 318.15 -10130-89-9 503.15 -10137-74-3 598.15 -101385-93-7 309.15 -10139-84-1 427.15 -1014-05-7 336.15 -1014-60-4 283.15 -1014-81-9 362.15 -101420-81-9 475.15 -10147-37-2 226.15 -10147-40-7 314.15 -10147-41-8 331.15 -10147-70-3 361.15 -10147-71-4 387.15 -1015-89-0 564.15 -10154-75-3 368.15 -1016-19-9 313.15 -1016-58-6 419.15 -1016-77-9 349.15 -1016-78-0 356.15 -101664-56-6 450.15 -10177-10-3 418.15 -1018256-11-5 412.15 -1019-52-9 524.15 -10190-55-3 -1053000 -101969-75-9 390.15 -10199-50-5 400.15 -10199-89-0 371.15 -102-01-2 358.15 -102-04-5 307.15 -102-06-7 422.15 -102-07-8 515.15 -102-08-9 425.15 -102-09-0 352.15 -102-25-0 488.15 349.15 -102-32-9 402.15 -102-36-3 315.15 -102-39-6 467.15 -102-47-6 270.15 -102-50-1 287.15 -102-54-5 445.92778 522.03889 -102-56-7 353.15 -102-69-2 180.15 -102-70-5 203.15 -102-71-6 293.15 -102-76-1 195.15 -102-79-4 203.15 -102-81-8 503.15 363.70556 -102-83-0 203.15 -102-85-2 193.15 -102-87-4 288.15 -102-92-1 309.15 -1020-84-4 369.15 -1020253-82-0 442.15 -10203-08-4 336.15 -10203-32-4 284.15 -10210-32-9 463.15 -10210-68-1 324.26111 -102127-34-4 352.15 -102151-33-7 382.15 -102195-80-2 311.15 -1022-13-5 369.15 -102225-55-8 323.15 -102268-15-5 426.15 -10236-60-9 407.15 -102368-13-8 438.15 -10238-21-8 446.15 -1024652-24-1 403.15 -102593-74-8 434.15 -10272-07-8 328.15 -1027730-68-2 384.15 -1028-33-7 354.15 -10287-53-3 337.15 -10294-29-8 443.15 -10294-33-4 227.03889 363.15 1.312 -10294-40-3 1653.15 -1366800 -10294-54-9 1292.15 -1442900 1.56 -10298-80-3 317.15 -103-01-5 391.15 -103-03-7 445.15 -103-04-8 337.15 -103-09-3 228.15 -103-11-7 183.15 -103-14-0 357.15 -103-16-2 393.15 -103-23-1 206.15 -103-29-7 325.15 -103-30-0 397.15 -103-36-6 280.15 -103-41-3 308.15 -103-43-5 318.15 -103-45-7 242.15 1.498 -103-46-8 335.15 -103-49-1 247.15 -103-50-4 277.15 -103-63-9 217.15 -103-65-1 174.15 432.15 -103-67-3 218.15 -103-69-5 209.15 -103-70-8 320.15 -103-71-9 240.15 -103-72-0 252.15 -103-73-1 243.15 -103-74-2 265.15 -103-76-4 234.15 -103-82-2 350.95 -103-83-3 198.15 -103-84-4 387.15 64700 -210600 446.15 813.15 -103-88-8 442.15 -103-89-9 422.15 -103-90-2 441.15 813.15 0.46 -103008-51-1 304.15 -103068-64-0 348.15 -1031-93-2 339.15 -103140-12-1 332.15 -103213-32-7 444.15 -10323-20-3 429.15 -10333-68-3 377.15 -10334-26-6 473.15 -103360-04-9 333.15 -1034-01-1 372.15 -10341-26-1 354.15 -10342-59-3 259.15 -10342-83-3 319.15 -103438-88-6 322.15 -10349-57-2 568.15 -10350-10-4 485.15 -10354-00-4 399.15 -10361-37-2 1235.9278 1833.15 -860100 -103616-89-3 507.15 -10365-98-7 433.15 -10366-35-5 438.15 -10366-71-9 451.15 -10373-78-1 473.15 -10377-48-7 1118.15 -1038-95-5 418.15 -10386-27-3 345.15 -10386-28-4 394.15 -10389-51-2 423.15 -103956-09-8 422.15 -10397-58-7 448.15 -104-01-8 360.15 -104-03-0 427.15 -104-04-1 489.15 -104-10-9 382.15 -104-12-1 303.15 -104-13-2 259.15 -104-20-1 281.15 -104-21-2 357.15 543.15 485.15 -104-29-0 353.15 -104-40-5 318.15 -104-47-2 281.15 -104-51-8 185.15 -104-53-0 231.15 -104-63-2 243.15 -104-66-5 368.15 -104-75-6 197.15 -104-76-7 197.15 -104-78-9 213.15 -104-81-4 308.15 -104-82-5 278.15 -104-83-6 300.15 493.75 -104-84-7 285.15 -104-85-8 301.15 -104-87-0 267.15 -104-88-1 319.15 -104-90-5 202.15 -104-92-7 284.15 -104-93-8 223.15 -104-94-9 330.37222 519.26111 788.15 -104-95-0 312.15 -10403-47-1 412.15 -1040681-74-0 365.15 -10413-34-0 365.15 -104197-13-9 323.15 -104197-15-1 359.15 -10421-85-9 356.15 -104222-34-6 416.15 -104222-42-6 396.15 -104227-87-4 376.15 -10431-98-8 211.15 -104326-94-5 399.15 -104376-24-1 353.15 -1044-49-1 584.15 -10443-65-9 341.15 -10444-89-0 498.15 -104451-99-2 300.15 -104460-70-0 309.15 -10463-20-4 420.15 -10463-37-3 440.15 -10465-81-3 408.15 -10469-09-7 445.15 -1048-08-4 510.15 -104830-06-0 363.15 -10485-09-3 309.15 -10490-07-0 373.15 -104968-58-3 324.15 -105-05-5 230.15 -105-07-7 374.15 -105-13-5 297.15 -105-34-0 250.15 -105-36-2 235.15 -105-37-3 200.15 -105-38-4 193.15 -105-39-5 247.15 -105-43-1 231.15 -105-45-3 193.15 -105-46-4 199.81667 385.37222 0.017 0.098 289.81667 -105-53-3 223.15 472.05 -105-54-4 180.15 -105-55-5 350.15 -105-56-6 250.15 -105-57-7 173.15 -105-58-8 230.15 -105-59-9 252.15 -105-60-2 342.03889 541.48333 0.014 0.08 412.03889 -105-67-9 295.15 -105-68-0 1.4069 -105-76-0 188.15 553.15 414.15 538.15 -10502-44-0 380.15 -10516-71-9 318.15 -105184-38-1 342.15 -10520-81-7 315.15 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361.15 +956047 388.15 +957755 465.15 +95711083 398.65 +959228 416.15 +959239 375.15 +95962144 231.35 561.15 435.65 567.15 4.8 +96059 208.15 +96117 290.15 +96128 279.26111 468.70556 349.81667 +96140 155.15 336.43 +96184 258.70556 429.81667 0.032 0.126 344.26111 +96208 271.15 +96220 230.92778 374.81667 0.016 0.064 285.92778 +96231 269.15 1.4802 +96242 233.15 +96297 243.15 +96300 319.15 +96311 375.15 +96322 223.15 +96333 196.48333 353.15 0.028 0.25 270.37222 +96344 241.15 +96377 130.15 +96413 254.15 +96435 201.15 +96457 473.15 585.92778 525.37222 +96479 137.15 +96480 228.15 +96504 363.15 +96537 378.15 +96548 216.15 +96640 193.15 463.15 +96695 423.15 488.70556 +96764 328.15 +96811 421.15 +96866 336.15 +96968 400.15 +96979 505.15 +96980 462.15 +96991 455.15 +960714 420.15 +96096525 626.85 +961295 459.15 +961386 419.15 +96107958 691.15 +96232712 400.15 +96424689 333.15 +96606370 330.15 +96784542 354.15 +96799029 399.15 +96799030 374.15 +96898929 457.15 +97007 323.15 +97029 451.15 +97085 333.15 +97234 447.15 +97303 442.15 +97392 450.15 +97518 398.15 +97529 413.15 +97530 263.15 +97610 188.15 +97621 185.15 +97632 213.15 +97643 248.15 427.15 319.15 1.413 +97654 438.85 +97698 410.15 +97723 217.15 +97778 343.15 +97858 192.15 +97881 198.15 +97950 221.15 +97004041 303.15 +97023488 377.15 +97033277 392.15 +97108504 348.15 +973671 439.15 +97483777 399.15 +97509756 302.15 +978869 554.15 +97888807 432.15 +97892676 385.15 +97914595 372.15 +97936431 367.15 +98000 258.70556 443.15 0.018 0.163 338.15 764.15 1.4869 0.28 +98011 236.48333 434.81667 0.021 0.193 333.15 +98066 215.15 +98077 269.15 +98088 244.15 +98099 288.15 +98102 426.15 +98113 321.15 +98135 146.15 +98157 217.15 +98168 279.15 +98179 271.15 +98180 414.15 +98191 251.15 +98237 305.15 +98293 328.15 +98317 294.15 +98464 268.15 +98511 220.92778 465.92778 341.48333 +98533 322.15 +98544 372.15 +98555 305.15 +98566 237.15 +98577 370.15 +98588 348.15 +98599 342.15 +98602 325.15 +98613 355.15 +98646 419.15 +98680 313.15 +98737 439.15 +98748 351.15 +98793 433.15 +98806 490.15 +98828 177.03889 425.37222 0.009 0.065 308.70556 693.15 +98839 249.81667 438.70556 0.019 0.061 327.03889 +98862 292.55 475.25 1.1207893e-05 350.15 843.15 1.5372 1.63 +98873 257.15 +98884 272.15 +98895 304.15 +98919 290.15 +98920 403.15 +98942 213.15 +98953 278.70556 483.70556 0.018 360.92778 +98964 463.15 +98986 410.15 +98027840 436.15 +98041442 311.15 +98198482 423.15 +98327878 556.15 +98400692 422.15 +98437231 528.15 +98495115 315.15 +98546511 483.15 +98555716 430.15 +98619079 395.15 +98946180 294.15 +98977367 311.15 +98995405 306.15 +99036 369.15 +99047 382.15 +99058 448.15 +99069 475.15 +99070 355.15 +99081 288.15 505.37222 0.016 379.26111 +99092 386.15 +99127 344.15 +99149 433.15 +99241 474.15 +99274 453.15 +99296 448.15 +99309 462.15 +99332 340.15 +99343 479.15 +99401 447.15 +99423 348.15 +99490 298.35 503.15 1.5003 +99503 494.15 +99514 302.15 +99525 405.15 +99547 314.15 +99558 380.15 +99569 474.15 +99570 416.15 +99581 493.15 +99592 390.15 +99605 415.15 +99616 331.15 +99627 210.15 +99638 317.15 +99649 424.15 +99650 362.03889 573.15 423.15 +99730 383.15 +99752 307.15 +99763 400.15 +99774 330.15 +99810 370.15 +99876 205.25 450.25 320.15 +99887 210.15 +99898 333.15 +99901 324.15 +99912 292.15 +99923 379.15 +99934 380.15 +99945 453.15 +99967 488.15 +99978 248.15 +99989 326.15 535.15 +99990 325.37222 510.92778 0.016 379.26111 +990910 334.15 +992789 318.75 +99277711 440.15 +993135 378.15 +994309 198.15 +994490 158.15 +99479660 305.15 +99570577 330.15 +99584857 432.15 +996509 263.15 +99627051 327.15 +997502 1.472 +99726995 328.15 +99768124 496.15 +99769194 409.15 +998301 103.15 +998403 208.15 +998914 303.15 +99817364 323.15 +999611 464.26111 0.018 338.15 +999973 195.15 diff --git a/chemicals/data_reader.py b/chemicals/data_reader.py index 79a07abd..0f412d75 100644 --- a/chemicals/data_reader.py +++ b/chemicals/data_reader.py @@ -76,8 +76,10 @@ def make_df_sparse(df, non_sparse_columns=[]): return df -def register_df_source(folder, name, sep='\t', index_col=0, csv_kwargs={}, +def register_df_source(folder, name, sep='\t', index_col=0, csv_kwargs=None, postload=None, sparsify=False, int_CAS=False): + if csv_kwargs is None: + csv_kwargs = {} load_cmds[name] = (folder, name, sep, index_col, csv_kwargs, postload, sparsify, int_CAS) '''The following flags will strip out the excess memory usage of redundant @@ -98,10 +100,10 @@ def load_df(key): import pandas as pd folder, name, sep, index_col, csv_kwargs, postload, sparsify, int_CAS = load_cmds[key] path = path_join(folder, name) - # if int_CAS: - # dtype = csv_kwargs.get('dtype', {}) - # dtype['CASRN'] = int64_dtype - # csv_kwargs['dtype'] = dtype + if int_CAS: + dtype = csv_kwargs.get('dtype', {}) + dtype['CAS'] = int64_dtype + csv_kwargs['dtype'] = dtype df = pd.read_csv(path, sep=sep, index_col=index_col, **csv_kwargs) if postload: postload(df) if sparsify: From 3db1e09fcb45cb41f1f208a2d3aba3ea3cd916cd Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 15:25:49 -0600 Subject: [PATCH 24/40] Update prediction scripts --- dev/data/update_common_chemistry.py | 4 ++-- dev/data/update_wikidata.py | 3 ++- dev/predictions/generate_fedors_predictions.py | 2 +- dev/predictions/generate_omega_from_Tc_VaporPressure.py | 2 +- dev/predictions/generate_wilson_jasperson_predictions.py | 2 +- 5 files changed, 7 insertions(+), 6 deletions(-) diff --git a/dev/data/update_common_chemistry.py b/dev/data/update_common_chemistry.py index 8815e739..e44be02f 100644 --- a/dev/data/update_common_chemistry.py +++ b/dev/data/update_common_chemistry.py @@ -7,7 +7,7 @@ from fluids.numerics import mean from chemicals import serialize_formula, rho_to_Vm, molecular_weight, nested_formula_parser - +from chemicals.identifiers import CAS_to_int from rdkit import Chem from rdkit.Chem import Descriptors from rdkit.Chem.rdMolDescriptors import CalcMolFormula @@ -207,7 +207,7 @@ def common_chemistry_data(CASRN): Tm, _ = process_temperataure(prop_val) if prop['name'] == 'Density': rho, rhoT, rhoP = process_density(prop_val) - return {'CAS': json_data['rn'], 'name': remove_html(json_data['name']), 'synonyms': synonyms, + return {'CAS': CAS_to_int(json_data['rn']), 'name': remove_html(json_data['name']), 'synonyms': synonyms, 'formula': formula, 'inchi': inchi, 'inchiKey': inchiKey, 'smiles': smiles, 'Tm': Tm, 'Tb': Tb, 'TbP': TbP, 'rho': rho, 'rhoT': rhoT, 'rhoP': rhoP, 'MW': MW, } diff --git a/dev/data/update_wikidata.py b/dev/data/update_wikidata.py index bf2cdf99..d79665c6 100644 --- a/dev/data/update_wikidata.py +++ b/dev/data/update_wikidata.py @@ -8,6 +8,7 @@ from fluids import C2K, R2K, F2K from time import time, sleep from chemicals.safety import mgm3_to_ppmv +from chemicals.identifiers import CAS_to_int from chemicals import molecular_weight, nested_formula_parser import os @@ -157,7 +158,7 @@ def retrieve_chemical_data(ID): MW = None else: MW = None - dat = {'CAS': CAS, 'name': name, 'MW': MW, + dat = {'CAS': CAS_to_int(CAS), 'name': name, 'MW': MW, 'formula': formula, 'smiles': smiles, 'inchi': inchi, 'inchikey': inchikey} diff --git a/dev/predictions/generate_fedors_predictions.py b/dev/predictions/generate_fedors_predictions.py index b564fcb6..181c9fad 100644 --- a/dev/predictions/generate_fedors_predictions.py +++ b/dev/predictions/generate_fedors_predictions.py @@ -16,7 +16,7 @@ lines = ['\t'.join(keys) + '\n'] def generate_line(CASi): chem_info = pubchem_db.CAS_index[CASi] - CAS = chem_info.CASs + CAS = CASi mol = Chem.MolFromSmiles(chem_info.smiles) if mol is None: # rdkit coult not parse diff --git a/dev/predictions/generate_omega_from_Tc_VaporPressure.py b/dev/predictions/generate_omega_from_Tc_VaporPressure.py index 1273a468..80fb020d 100644 --- a/dev/predictions/generate_omega_from_Tc_VaporPressure.py +++ b/dev/predictions/generate_omega_from_Tc_VaporPressure.py @@ -28,7 +28,7 @@ def generate_line(CASi): values = [omega] line = values - line.insert(0, CAS) + line.insert(0, CASi) for i, v in enumerate(line): if v is None: line[i] = '' diff --git a/dev/predictions/generate_wilson_jasperson_predictions.py b/dev/predictions/generate_wilson_jasperson_predictions.py index f679f8a4..c8075829 100644 --- a/dev/predictions/generate_wilson_jasperson_predictions.py +++ b/dev/predictions/generate_wilson_jasperson_predictions.py @@ -33,7 +33,7 @@ def generate_line(CASi): if not missing_Tc_increments or not missing_Pc_increments: values = [Tc, Pc] line = values - line.insert(0, CAS) + line.insert(0, CASi) for i, v in enumerate(line): if v is None: line[i] = '' From ef1b447ea15dfaa4099e37c902d2f0c10bb336b9 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 15:38:37 -0600 Subject: [PATCH 25/40] Add memory usage debug function --- chemicals/__init__.py | 16 +++++++++++++++- 1 file changed, 15 insertions(+), 1 deletion(-) diff --git a/chemicals/__init__.py b/chemicals/__init__.py index 377cab9a..2dc99c78 100644 --- a/chemicals/__init__.py +++ b/chemicals/__init__.py @@ -186,7 +186,21 @@ def constant_statistics(): else: counts[p] = set(prop_CASs) return {k: len(v) for k, v in counts.items()} - + + def memory_usage(finish_loading=True): + if finish_loading: + complete_lazy_loading() + usages = [] + names = [] + for name, df in data_reader.df_sources.items(): + names.append(name) + usages.append(df.memory_usage().values.sum()) + + names = [x for _, x in sorted(zip(usages, names))] + usages.sort() + for name, use in zip(names, usages): + print(f'{name} : {use/1024**2:3f} MB') + print(f'Total usage: {sum(usages)/1024**2:3f} MB') global vectorized, numba, units, numba_vectorized if PY37: From 0088332c33588a4a6abab51f88bfd8f250e1650e Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 16:15:55 -0600 Subject: [PATCH 26/40] Fix type erro for sqlite MW --- dev/generate_sqlite_database.py | 2 +- 1 file changed, 1 insertion(+), 1 deletion(-) diff --git a/dev/generate_sqlite_database.py b/dev/generate_sqlite_database.py index 3c10c658..d91f6809 100644 --- a/dev/generate_sqlite_database.py +++ b/dev/generate_sqlite_database.py @@ -61,7 +61,7 @@ def RIT(CASRN): CASs.append(CAS) for i, p in enumerate(props): if p == 'MW': - lookedup_constant = v.MW + lookedup_constant = float(v.MW) else: lookedup_constant = funcs[i](CASRN=CAS) prop_array[i].append(lookedup_constant) From 7b404ec2138780845d05da2f4b2342d4c756d703 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 18:20:34 -0600 Subject: [PATCH 27/40] Code cleanup --- chemicals/identifiers.py | 6 ++++++ dev/generate_sqlite_database.py | 5 +---- 2 files changed, 7 insertions(+), 4 deletions(-) diff --git a/chemicals/identifiers.py b/chemicals/identifiers.py index b82e825e..6bd3019d 100644 --- a/chemicals/identifiers.py +++ b/chemicals/identifiers.py @@ -402,6 +402,12 @@ def finished_loading(self): ''' return not (not self.loaded_main_db and self.main_db is not None) + def finish_loading(self): + '''Complete loading the main database, if it has not been fully loaded. + ''' + if not self.finished_loading: + self.autoload_main_db() + def autoload_main_db(self): '''Load the main database when needed. ''' diff --git a/dev/generate_sqlite_database.py b/dev/generate_sqlite_database.py index d91f6809..6414ff9e 100644 --- a/dev/generate_sqlite_database.py +++ b/dev/generate_sqlite_database.py @@ -29,10 +29,7 @@ import os import numpy as np -try: - Chemical('asdfsdaf') -except: - pass +pubchem_db.finish_loading() # Can't use the database data_reader.USE_CONSTANTS_DATABASE = False From 373542ac4e08210679e9625ef4866368eb26ca36 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 22:56:07 -0600 Subject: [PATCH 28/40] Two fixes --- chemicals/Electrolytes/Lange Pure Species Conductivity.tsv | 2 +- conftest.py | 4 ++-- 2 files changed, 3 insertions(+), 3 deletions(-) diff --git a/chemicals/Electrolytes/Lange Pure Species Conductivity.tsv b/chemicals/Electrolytes/Lange Pure Species Conductivity.tsv index c963f2b3..20db77bf 100644 --- a/chemicals/Electrolytes/Lange Pure Species Conductivity.tsv +++ b/chemicals/Electrolytes/Lange Pure Species Conductivity.tsv @@ -1,4 +1,4 @@ -CASRN Chemical T Conductivity +CAS Chemical T Conductivity 56-23-5 Carbon tetrachloride 291.15 4E-016 56-81-5 Glycerol 298.15 0.0000064 57-11-4 Stearic acid 353.15 4E-011 diff --git a/conftest.py b/conftest.py index aedc4d23..2101eea5 100644 --- a/conftest.py +++ b/conftest.py @@ -18,7 +18,7 @@ def pytest_ignore_collect(path): # return True if 'setup' in path: return True - if ver_tup <= (3, 6) or ver_tup >= (3, 10) or is_pypy: + if ver_tup <= (3, 6) or ver_tup >= (3, 11) or is_pypy: # numba does not yet run under pypy, numba support 3.6 to 3.9 for now if 'numba' in path: return True @@ -30,4 +30,4 @@ def pytest_addoption(parser): def pytest_configure(config): os.environ["CHEDL_LOW_MEMORY"] = config.getoption("--enable-low-memory") - \ No newline at end of file + From 18235bbdffc5f1874de1aeefa06579b5159a4437 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 23:06:14 -0600 Subject: [PATCH 29/40] Save 0.1 second on test_CAS_numbers_valid_and_unique --- chemicals/identifiers.py | 4 ++-- tests/test_data_reader.py | 25 ++++++++++++++++--------- 2 files changed, 18 insertions(+), 11 deletions(-) diff --git a/chemicals/identifiers.py b/chemicals/identifiers.py index 6bd3019d..f61d022d 100644 --- a/chemicals/identifiers.py +++ b/chemicals/identifiers.py @@ -115,9 +115,9 @@ def check_CAS(CASRN): >>> check_CAS('77332-18-5') False """ - if CASRN.count('-') != 2: - return False try: + if CASRN.count('-') != 2: + return False check = CASRN[-1] # Don't store the int - it is not necessary and is slower productsum = 0 diff --git a/tests/test_data_reader.py b/tests/test_data_reader.py index 9d8b2d1d..ff7c29a5 100644 --- a/tests/test_data_reader.py +++ b/tests/test_data_reader.py @@ -28,22 +28,29 @@ import numpy as np import chemicals -int64_dtype = np.dtype(np.int64) @pytest.mark.slow def test_CAS_numbers_valid_and_unique(): + int64_dtype = np.dtype(np.int64) chemicals.complete_lazy_loading() for k, df in chemicals.data_reader.df_sources.items(): if df.index.dtype is int64_dtype: - CASs = [int_to_CAS(v) for v in df.index] + already_int = True else: - CASs = df.index.values.tolist() + already_int = False assert df.index.is_unique - for CAS in CASs: - assert check_CAS(CAS) - CAS_int = CAS_to_int(CAS) - # Check that the CAS number fits in a 64 bit int - assert CAS_int < 9223372036854775807 - + + if already_int: + for CAS in df.index.values.tolist(): + assert CAS < 9223372036854775807 + CAS = int_to_CAS(CAS) + assert check_CAS(CAS) + else: + for CAS in df.index.values.tolist(): + assert check_CAS(CAS) + CAS_int = CAS_to_int(CAS) + # Check that the CAS number fits in a 64 bit int + assert CAS_int < 9223372036854775807 + # Check that the name is CAS for k, df in chemicals.data_reader.df_sources.items(): assert df.index.name == 'CAS' From 43fcd1fad9443e17d52fe3940e12219ec594d997 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 23:18:48 -0600 Subject: [PATCH 30/40] Save another few dozen ms --- chemicals/identifiers.py | 7 ++++--- tests/test_data_reader.py | 1 + 2 files changed, 5 insertions(+), 3 deletions(-) diff --git a/chemicals/identifiers.py b/chemicals/identifiers.py index f61d022d..0bc93c5b 100644 --- a/chemicals/identifiers.py +++ b/chemicals/identifiers.py @@ -121,10 +121,11 @@ def check_CAS(CASRN): check = CASRN[-1] # Don't store the int - it is not necessary and is slower productsum = 0 - i = 1 - for num in CASRN.replace('-', '')[:-1][::-1]: + chars = CASRN.replace('-', '')[:-1] + i = len(chars) + for num in chars: productsum += i*int(num) - i += 1 + i -= 1 return productsum % 10 == int(check) except: return False diff --git a/tests/test_data_reader.py b/tests/test_data_reader.py index ff7c29a5..45b03558 100644 --- a/tests/test_data_reader.py +++ b/tests/test_data_reader.py @@ -54,3 +54,4 @@ def test_CAS_numbers_valid_and_unique(): # Check that the name is CAS for k, df in chemicals.data_reader.df_sources.items(): assert df.index.name == 'CAS' +test_CAS_numbers_valid_and_unique() \ No newline at end of file From 81acf4a5139a90ac3ef71a88c84c12414607bdde Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 23:29:02 -0600 Subject: [PATCH 31/40] Find three more values that were not being checked correctly - Incorrect CASs fixed --- .../Critical Properties/IUPACOrganicCriticalProps.tsv | 2 +- chemicals/Misc/cccbdb.nist.gov Dipoles.csv | 2 -- chemicals/identifiers.py | 2 ++ tests/test_critical.py | 8 ++++---- tests/test_data_reader.py | 1 - tests/test_dipole.py | 2 +- 6 files changed, 8 insertions(+), 9 deletions(-) diff --git a/chemicals/Critical Properties/IUPACOrganicCriticalProps.tsv b/chemicals/Critical Properties/IUPACOrganicCriticalProps.tsv index 9e5d25fc..3d33f304 100644 --- a/chemicals/Critical Properties/IUPACOrganicCriticalProps.tsv +++ b/chemicals/Critical Properties/IUPACOrganicCriticalProps.tsv @@ -478,7 +478,7 @@ CAS Chemical MW Tc Pc Vc Zc Reference 462-95-3 diethoxymethane 104.149 531.7 7 463-49-0 propadiene 40.065 394 5250000 6 463-82-1 2,2-dimethylpropane 72.15 433.8 3196000 0.0003070 0.272 5 -464-06-02 2,2,3-trimethylbutane 100.204 531.1 2950000 0.0003980 0.265 5 +464-06-2 2,2,3-trimethylbutane 100.204 531.1 2950000 0.0003980 0.265 5 493-01-6 cis-bicyclo[4.4.0]decane 138.253 703.6 3200000 5 493-02-7 trans-bicyclo[4.4.0]decane 138.253 687 5 496-11-7 indan 118.178 684.9 3950000 3 diff --git a/chemicals/Misc/cccbdb.nist.gov Dipoles.csv b/chemicals/Misc/cccbdb.nist.gov Dipoles.csv index f45269c1..2e306102 100644 --- a/chemicals/Misc/cccbdb.nist.gov Dipoles.csv +++ b/chemicals/Misc/cccbdb.nist.gov Dipoles.csv @@ -1,6 +1,4 @@ CAS Chemical dipole_moment --20-4 Methane selenol 1.29 --2-2 Ammonia Dimer 1.99 50-00-0 Formaldehyde 2.33 56-23-5 Carbon tetrachloride 0 56-40-6 Glycine 1.09 diff --git a/chemicals/identifiers.py b/chemicals/identifiers.py index 0bc93c5b..b4982cbb 100644 --- a/chemicals/identifiers.py +++ b/chemicals/identifiers.py @@ -118,6 +118,8 @@ def check_CAS(CASRN): try: if CASRN.count('-') != 2: return False + if CASRN[-2] != '-' or CASRN[-5] != '-': + return False check = CASRN[-1] # Don't store the int - it is not necessary and is slower productsum = 0 diff --git a/tests/test_critical.py b/tests/test_critical.py index e824849f..b4f0e51a 100644 --- a/tests/test_critical.py +++ b/tests/test_critical.py @@ -199,7 +199,7 @@ def test_Tc_all_values(): # Use the default method for each chemical in this file Tcs = [Tc(i) for i in CASs] Tcs_default_sum = pd.Series(Tcs).sum() - assert_close(Tcs_default_sum, 6246571.366122) + assert_close(Tcs_default_sum, 6246040.066122223) def test_Tc(): Tc_val = Tc(CASRN='64-17-5') @@ -256,7 +256,7 @@ def test_Pc_all_values(): # Use the default method for each chemical in this file Pcs = [Pc(i) for i in CASs] Pcs_default_sum = pd.Series(Pcs).sum() - assert_close(Pcs_default_sum, 64604961266.18326) + assert_close(Pcs_default_sum, 64602001266.18326) def test_Vc(): assert_close(0.000168, Vc(CASRN='64-17-5')) @@ -287,7 +287,7 @@ def test_Vc_all_values(): # Use the default method for each chemical in this file Vcs = [Vc(i) for i in CASs] Vcs_default_sum = pd.Series(Vcs).sum() - assert_close(Vcs_default_sum, 4.956260233439) + assert_close(Vcs_default_sum, 4.955859233439) def test_Zc(): assert_close(0.241, Zc(CASRN='64-17-5')) @@ -318,7 +318,7 @@ def test_Zc_all_values(): # Use the default method for each chemical in this file Zcs = [Zc(i) for i in CASs] Zcs_default_sum = pd.Series(Zcs).sum() - assert_close(Zcs_default_sum, 1999.5705747225877, 1e-6) + assert_close(Zcs_default_sum, 1999.3018781772432, 1e-6) diff --git a/tests/test_data_reader.py b/tests/test_data_reader.py index 45b03558..ff7c29a5 100644 --- a/tests/test_data_reader.py +++ b/tests/test_data_reader.py @@ -54,4 +54,3 @@ def test_CAS_numbers_valid_and_unique(): # Check that the name is CAS for k, df in chemicals.data_reader.df_sources.items(): assert df.index.name == 'CAS' -test_CAS_numbers_valid_and_unique() \ No newline at end of file diff --git a/tests/test_dipole.py b/tests/test_dipole.py index bea1ce9d..5e9412a7 100644 --- a/tests/test_dipole.py +++ b/tests/test_dipole.py @@ -33,7 +33,7 @@ def test_dipole_moment_methods(): assert_close(tot, 248.59999999999999) tot = dipole.dipole_data_CCDB['dipole_moment'].sum() - assert_close(tot, 632.97000000000003) + assert_close(tot, 629.69) tot = dipole.dipole_data_Muller['dipole_moment'].sum() assert_close(tot, 420.05190108045235) From 82e7c6da5bbc985bdbd5f4fc9f15ca001762c07b Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 23:32:45 -0600 Subject: [PATCH 32/40] 3.10 workflow --- .github/workflows/build.yml | 4 ++-- 1 file changed, 2 insertions(+), 2 deletions(-) diff --git a/.github/workflows/build.yml b/.github/workflows/build.yml index 9889a742..2b5203ab 100644 --- a/.github/workflows/build.yml +++ b/.github/workflows/build.yml @@ -13,7 +13,7 @@ jobs: strategy: fail-fast: false matrix: - python-version: ['3.6', '3.7', '3.8', '3.9', 'pypy-3.6'] # pandas won't build c extensions on 'pypy-3.7' right now + python-version: ['3.6', '3.7', '3.8', '3.9', '3.10', 'pypy-3.6'] # pandas won't build c extensions on 'pypy-3.7' right now os: [windows-latest, ubuntu-latest, macos-latest] architecture: ['x86', 'x64'] exclude: @@ -80,7 +80,7 @@ jobs: python -m pip install wheel pip install -r requirements_test.txt - name: Add numba - if: ${{ matrix.python-version == '3.7' || matrix.python-version == '3.8' || matrix.python-version == '3.9' }} + if: ${{ matrix.python-version == '3.7' || matrix.python-version == '3.8' || matrix.python-version == '3.9' || matrix.python-version == '3.10' }} run: | pip install numba #- name: Test with low memory From f559f600e44714f370dbd12e2b630122f8cb7564 Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Mon, 23 May 2022 23:51:15 -0600 Subject: [PATCH 33/40] Fix --- .github/workflows/build.yml | 4 ++++ 1 file changed, 4 insertions(+) diff --git a/.github/workflows/build.yml b/.github/workflows/build.yml index 2b5203ab..701f7a98 100644 --- a/.github/workflows/build.yml +++ b/.github/workflows/build.yml @@ -40,6 +40,10 @@ jobs: # no python builds available on linux 32 bit - os: ubuntu-latest architecture: x86 + # Scipy dropped 32 bit windows + - os: windows-latest + architecture: x86 + python-version: 3.10 steps: - uses: actions/checkout@v2 - name: Set up Python ${{ matrix.python-version }} ${{ matrix.architecture }} From 76ec826f56da49adfa44224da2fc935f218dfd6a Mon Sep 17 00:00:00 2001 From: Yoel Date: Tue, 24 May 2022 14:34:57 -0500 Subject: [PATCH 34/40] tweaks to avoid function call and minor simplifications --- chemicals/acentric.py | 6 +++-- chemicals/combustion.py | 17 ++++++++------ chemicals/critical.py | 22 ++++++++++-------- chemicals/data_reader.py | 41 ++++++++++++++------------------- chemicals/dipole.py | 8 ++++--- chemicals/environment.py | 16 ++++++++----- chemicals/lennard_jones.py | 12 ++++++---- chemicals/molecular_geometry.py | 12 ++++++---- chemicals/phase_change.py | 17 ++++++++------ chemicals/reaction.py | 31 +++++++++++++++---------- chemicals/refractivity.py | 9 ++++---- chemicals/safety.py | 22 ++++++++++-------- chemicals/triple.py | 12 ++++++---- 13 files changed, 127 insertions(+), 98 deletions(-) diff --git a/chemicals/acentric.py b/chemicals/acentric.py index e1a05cbd..d12dfca4 100644 --- a/chemicals/acentric.py +++ b/chemicals/acentric.py @@ -52,6 +52,7 @@ 'omega_methods', 'omega_all_methods', 'omega_definition'] from chemicals import critical +from chemicals import data_reader as dr from chemicals.data_reader import (list_available_methods_from_df_dict, database_constant_lookup, retrieve_any_from_df_dict, @@ -150,8 +151,9 @@ def omega(CASRN, method=None): Hydrocarbons, Second Edition. Amsterdam Boston: Gulf Professional Publishing, 2014. ''' - val, found = database_constant_lookup(CASRN, 'omega') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'omega') + if found: return val if method: return retrieve_from_df_dict(critical.omega_sources, CASRN, 'omega', method) else: diff --git a/chemicals/combustion.py b/chemicals/combustion.py index 481a3bd4..6bbeb4cb 100644 --- a/chemicals/combustion.py +++ b/chemicals/combustion.py @@ -75,7 +75,7 @@ """ from fluids.numerics import normalize - +from chemicals import data_reader as dr from chemicals.data_reader import (data_source, database_constant_lookup, list_available_methods_from_df_dict, register_df_source, @@ -260,8 +260,9 @@ def RON(CASRN, method=None): Learning Projects for Fuel Property Prediction." Journal of Open Source Software 2, no. 17 (2017): 401. ''' - val, found = database_constant_lookup(CASRN, 'RON') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'RON') + if found: return val if not _combustion_data_loaded: _load_combustion_data() if method: value = retrieve_from_df_dict(RON_sources, CASRN, 'RON', method) @@ -354,8 +355,9 @@ def MON(CASRN, method=None): Learning Projects for Fuel Property Prediction." Journal of Open Source Software 2, no. 17 (2017): 401. ''' - val, found = database_constant_lookup(CASRN, 'MON') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'MON') + if found: return val if not _combustion_data_loaded: _load_combustion_data() if method: value = retrieve_from_df_dict(MON_sources, CASRN, 'MON', method) @@ -387,8 +389,9 @@ def ignition_delay_methods(CASRN): -------- ignition_delay """ - val, found = database_constant_lookup(CASRN, 'IGNITION_DELAY') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE: + val, found = database_constant_lookup(CASRN, 'IGNITION_DELAY') + if found: return val if not _combustion_data_loaded: _load_combustion_data() return list_available_methods_from_df_dict(ignition_delay_sources, CASRN, 'IGNITION_DELAY') diff --git a/chemicals/critical.py b/chemicals/critical.py index d21fde31..743ffc72 100644 --- a/chemicals/critical.py +++ b/chemicals/critical.py @@ -100,7 +100,7 @@ import os from fluids.constants import N_A, R, R_inv - +from chemicals import data_reader as dr from chemicals import miscdata from chemicals.data_reader import (data_source, list_available_methods_from_df_dict, @@ -405,8 +405,9 @@ def Tc(CASRN, method=None): Estimation Based on Zero, First and Second Order Methods." In Proceedings of the AIChE Spring Meeting, 21, 1996. ''' - val, found = database_constant_lookup(CASRN, 'Tc') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'Tc') + if found: return val if not _critical_data_loaded: _load_critical_data() if method: return retrieve_from_df_dict(Tc_sources, CASRN, 'Tc', method) @@ -583,8 +584,9 @@ def Pc(CASRN, method=None): Estimation Based on Zero, First and Second Order Methods." In Proceedings of the AIChE Spring Meeting, 21, 1996. ''' - val, found = database_constant_lookup(CASRN, 'Pc') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'Pc') + if found: return val if not _critical_data_loaded: _load_critical_data() if method: return retrieve_from_df_dict(Pc_sources, CASRN, 'Pc', method) @@ -755,8 +757,9 @@ def Vc(CASRN, method=None): .. [20] Fedors, R. F. "A Method to Estimate Critical Volumes." AIChE Journal 25, no. 1 (1979): 202-202. https://doi.org/10.1002/aic.690250129. ''' - val, found = database_constant_lookup(CASRN, 'Vc') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'Vc') + if found: return val if not _critical_data_loaded: _load_critical_data() if method: return retrieve_from_df_dict(Vc_sources, CASRN, 'Vc', method) @@ -924,8 +927,9 @@ def Zc(CASRN, method=None): Tc-PR." AIChE Journal n/a, no. n/a (n.d.): e17518. https://doi.org/10.1002/aic.17518. ''' - val, found = database_constant_lookup(CASRN, 'Zc') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'Zc') + if found: return val if not _critical_data_loaded: _load_critical_data() if method: return retrieve_from_df_dict(Zc_sources, CASRN, 'Zc', method) diff --git a/chemicals/data_reader.py b/chemicals/data_reader.py index 0f412d75..1f3fc29d 100644 --- a/chemicals/data_reader.py +++ b/chemicals/data_reader.py @@ -166,7 +166,7 @@ def retrieve_from_df(df, index, key): df_index = df.index if df_index.dtype is int64_dtype and isinstance(index, str): try: index = CAS_to_int(index) - except: pass + except: return None if index in df_index: if isinstance(key, (int, str)): return get_value_from_df(df, index, key) @@ -177,7 +177,7 @@ def retrieve_any_from_df(df, index, keys): df_index = df.index if df_index.dtype is int64_dtype and isinstance(index, str): try: index = CAS_to_int(index) - except: pass + except: return None if index not in df.index: return None for key in keys: value = df.at[index, key] @@ -191,8 +191,7 @@ def get_value_from_df(df, index, key): value = df.at[index, key] try: return None if isnan(value) else float(value) - except TypeError: - # Not a number + except TypeError: # Not a number return value def list_available_methods_from_df_dict(df_dict, index, key): @@ -200,15 +199,13 @@ def list_available_methods_from_df_dict(df_dict, index, key): int_index = None for method, df in df_dict.items(): df_index = df.index - if df_index.dtype is int64_dtype and isinstance(index, str): + if df_index.dtype is int64_dtype: if int_index is None: try: int_index = CAS_to_int(index) except: int_index = 'skip' - elif int_index == 'skip': - continue - if (int_index in df_index) and not isnan(df.at[int_index, key]): + elif int_index != 'skip' and (int_index in df_index) and not isnan(df.at[int_index, key]): methods.append(method) elif (index in df_index) and not isnan(df.at[index, key]): methods.append(method) @@ -238,18 +235,17 @@ def list_available_methods_from_df(df, index, keys_by_method): CONSTANTS_CURSOR = None DATABASE_CONSTANTS_CACHE = {} -def cached_constant_lookup(CASi, prop): +def cached_constant_lookup(CASi, prop, cache=DATABASE_CONSTANTS_CACHE): if CONSTANTS_CURSOR is None: init_constants_db() prop_idx = CONSTANT_DATABASE_NAME_TO_IDX[prop] - try: - return DATABASE_CONSTANTS_CACHE[CASi][prop_idx], True - except KeyError: - pass + if CASi in cache: + return cache[CASi][prop_idx], True + # Fetch and store the whole row CONSTANTS_CURSOR.execute("SELECT * FROM constants WHERE `index`=?", (str(CASi),)) result = CONSTANTS_CURSOR.fetchone() - DATABASE_CONSTANTS_CACHE[CASi] = result + cache[CASi] = result if result is not None: return result[prop_idx], True @@ -262,17 +258,14 @@ def init_constants_db(): conn = sqlite3.connect(path_join(source_path, 'Misc', 'default.sqlite')) CONSTANTS_CURSOR = conn.cursor() -def database_constant_lookup(CAS, prop): - if not USE_CONSTANTS_DATABASE: - return None, False - try: - CASi = CAS_to_int(CAS) - except: - if type(CAS) is not int: +def database_constant_lookup(CASi, prop): + print("ASDSAAAAAAAAAAAAAAA") + if isinstance(CASi, str): + print(CASi) + try: + CASi = CAS_to_int(CASi) + except: return None, False - else: - # Was already an int - CASi = CAS try: return cached_constant_lookup(CASi, prop) except: diff --git a/chemicals/dipole.py b/chemicals/dipole.py index db58058c..de7bbe5e 100644 --- a/chemicals/dipole.py +++ b/chemicals/dipole.py @@ -39,10 +39,11 @@ 'dipole_moment_methods', 'dipole_moment_all_methods'] +from chemicals import data_reader as dr from chemicals.data_reader import (data_source, database_constant_lookup, + retrieve_any_from_df_dict, list_available_methods_from_df_dict, register_df_source, - retrieve_any_from_df_dict, retrieve_from_df_dict) from chemicals.miscdata import PSI4_2022A from chemicals.utils import (PY37, can_load_data, mark_numba_incompatible, @@ -186,8 +187,9 @@ def dipole_moment(CASRN, method=None): Program." WIREs Computational Molecular Science 2, no. 4 (2012): 556-65. https://doi.org/10.1002/wcms.93. ''' - val, found = database_constant_lookup(CASRN, 'dipole_moment') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'dipole_moment') + if found: return val if not _dipole_data_loaded: _load_dipole_data() if method: return retrieve_from_df_dict(dipole_sources, CASRN, 'dipole_moment', method) diff --git a/chemicals/environment.py b/chemicals/environment.py index 6d9cdbfc..115fa3ba 100644 --- a/chemicals/environment.py +++ b/chemicals/environment.py @@ -54,6 +54,7 @@ __all__ = ['GWP', 'ODP', 'logP', 'GWP_all_methods', 'ODP_all_methods', 'logP_all_methods', 'GWP_methods', 'ODP_methods', 'logP_methods'] +from chemicals import data_reader as dr from chemicals import miscdata from chemicals.data_reader import ( data_source, list_available_methods_from_df, database_constant_lookup, @@ -248,8 +249,9 @@ def GWP(CASRN, method=None): Other Weak Atmospheric Absorbers." Reviews of Geophysics 58, no. 3 (2020): e2019RG000691. https://doi.org/10.1029/2019RG000691. ''' - val, found = database_constant_lookup(CASRN, 'GWP') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'GWP') + if found: return val if not _GWP_ODP_data_loaded: _load_GWP_ODP_data() if method: if method in _IPCC_2014_GWP_keys_by_method: @@ -364,8 +366,9 @@ def ODP(CASRN, method=None): Project-Report No. 52, Geneva, Switzerland, 516 p. https://www.wmo.int/pages/prog/arep/gaw/ozone_2010/documents/Ozone-Assessment-2010-complete.pdf ''' - val, found = database_constant_lookup(CASRN, 'ODP') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'ODP') + if found: return val if not _GWP_ODP_data_loaded: _load_GWP_ODP_data() if method: key = _ODP_keys_by_method[method] @@ -448,8 +451,9 @@ def logP(CASRN, method=None): .. [2] Haynes, W.M., Thomas J. Bruno, and David R. Lide. CRC Handbook of Chemistry and Physics, 95E. Boca Raton, FL: CRC press, 2014. ''' - val, found = database_constant_lookup(CASRN, 'logP') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'logP') + if found: return val if not _logP_data_loaded: _load_logP_data() if method: return retrieve_from_df_dict(logP_sources, CASRN, 'logP', method) diff --git a/chemicals/lennard_jones.py b/chemicals/lennard_jones.py index 3d78a2ae..57862f47 100644 --- a/chemicals/lennard_jones.py +++ b/chemicals/lennard_jones.py @@ -95,7 +95,7 @@ import os from fluids.constants import k - +from chemicals import data_reader as dr from chemicals.data_reader import (data_source, database_constant_lookup, list_available_methods_from_df_dict, register_df_source, @@ -252,8 +252,9 @@ def Stockmayer(CASRN='', Tm=None, Tb=None, Tc=None, Zc=None, omega=None, Ranges of Temperature and Density." The Journal of Supercritical Fluids 76 (April 2013): 94-114. doi:10.1016/j.supflu.2013.02.002. ''' - val, found = database_constant_lookup(CASRN, 'Stockmayer') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'Stockmayer') + if found: return val if not _LJ_data_loaded: _load_LJ_data() if method is not None: if method == FLYNN: @@ -411,8 +412,9 @@ def molecular_diameter(CASRN=None, Tc=None, Pc=None, Vc=None, Zc=None, omega=Non Ranges of Temperature and Density." The Journal of Supercritical Fluids 76 (April 2013): 94-114. doi:10.1016/j.supflu.2013.02.002. ''' - val, found = database_constant_lookup(CASRN, 'molecular_diameter') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'molecular_diameter') + if found: return val if not _LJ_data_loaded: _load_LJ_data() if method is not None: if method == FLYNN: diff --git a/chemicals/molecular_geometry.py b/chemicals/molecular_geometry.py index 16335b90..2ccfa04a 100644 --- a/chemicals/molecular_geometry.py +++ b/chemicals/molecular_geometry.py @@ -43,7 +43,7 @@ 'linear', 'linear_methods', 'linear_all_methods'] from fluids.numerics import horner, interp - +from chemicals import data_reader as dr from chemicals.data_reader import (data_source, database_constant_lookup, list_available_methods_from_df_dict, register_df_source, @@ -171,8 +171,9 @@ def RG(CASRN, method=None): .. [2] Kooijman, Harry A., and Ross Taylor. The ChemSep Book. Books on Demand Norderstedt, Germany, 2000. ''' - val, found = database_constant_lookup(CASRN, 'RG') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'RG') + if found: return val if not _RG_data_loaded: _load_RG_data() if method: value = retrieve_from_df_dict(RG_sources, CASRN, 'RG', method) @@ -256,8 +257,9 @@ def linear(CASRN, method=None): Program." WIREs Computational Molecular Science 2, no. 4 (2012): 556-65. https://doi.org/10.1002/wcms.93. ''' - val, found = database_constant_lookup(CASRN, 'linear') if method is None else (None, False) - if found: return bool(val) + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'linear') + if found: return bool(found) if not _RG_data_loaded: _load_RG_data() if method: value = retrieve_from_df_dict(linear_sources, CASRN, 'linear', method) diff --git a/chemicals/phase_change.py b/chemicals/phase_change.py index 7511784c..ea316758 100644 --- a/chemicals/phase_change.py +++ b/chemicals/phase_change.py @@ -136,7 +136,7 @@ from fluids.constants import N_A, R, pi from fluids.numerics import numpy as np - +from chemicals import data_reader as dr from chemicals import miscdata from chemicals.data_reader import (data_source, database_constant_lookup, list_available_methods_from_df_dict, @@ -339,8 +339,9 @@ def Tb(CASRN, method=None): .. [6] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' - val, found = database_constant_lookup(CASRN, 'Tb') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'Tb') + if found: return val if not _phase_change_const_loaded: _load_phase_change_constants() if method: return retrieve_from_df_dict(Tb_sources, CASRN, 'Tb', method) @@ -443,8 +444,9 @@ def Tm(CASRN, method=None): .. [6] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' - val, found = database_constant_lookup(CASRN, 'Tm') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'Tm') + if found: return val if not _phase_change_const_loaded: _load_phase_change_constants() if method: return retrieve_from_df_dict(Tm_sources, CASRN, 'Tm', method) @@ -1317,8 +1319,9 @@ def Hfus(CASRN, method=None): .. [4] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' - val, found = database_constant_lookup(CASRN, 'Hfus') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'Hfus') + if found: return val if not _phase_change_const_loaded: _load_phase_change_constants() if method: return retrieve_from_df_dict(Hfus_sources, CASRN, 'Hfus', method) diff --git a/chemicals/reaction.py b/chemicals/reaction.py index 4e49e1a4..779b7677 100644 --- a/chemicals/reaction.py +++ b/chemicals/reaction.py @@ -86,6 +86,7 @@ 'Gibbs_formation', 'entropy_formation', 'Hf_basis_converter', 'balance_stoichiometry', 'stoichiometric_matrix'] +from chemicals import data_reader as dr from chemicals import heat_capacity, miscdata from chemicals.data_reader import (data_source, database_constant_lookup, list_available_methods_from_df_dict, @@ -243,8 +244,9 @@ def Hfs(CASRN, method=None): .. [2] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' - val, found = database_constant_lookup(CASRN, 'Hfs') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'Hfs') + if found: return val if not _reaction_data_loaded: _load_reaction_data() if method: return retrieve_from_df_dict(Hfs_sources, CASRN, 'Hfs', method) @@ -329,8 +331,9 @@ def Hfl(CASRN, method=None): .. [3] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' - val, found = database_constant_lookup(CASRN, 'Hfl') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'Hfl') + if found: return val if not _reaction_data_loaded: _load_reaction_data() if method: return retrieve_from_df_dict(Hfl_sources, CASRN, 'Hfl', method) @@ -439,8 +442,9 @@ def Hfg(CASRN, method=None): .. [6] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' - val, found = database_constant_lookup(CASRN, 'Hfg') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'Hfg') + if found: return val if not _reaction_data_loaded: _load_reaction_data() if method: return retrieve_from_df_dict(Hfg_sources, CASRN, 'Hfg', method) @@ -521,8 +525,9 @@ def S0s(CASRN, method=None): .. [2] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' - val, found = database_constant_lookup(CASRN, 'S0s') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'S02') + if found: return val if not _reaction_data_loaded: _load_reaction_data() if method: return retrieve_from_df_dict(S0s_sources, CASRN, 'S0s', method) @@ -600,8 +605,9 @@ def S0l(CASRN, method=None): .. [1] Haynes, W.M., Thomas J. Bruno, and David R. Lide. CRC Handbook of Chemistry and Physics. [Boca Raton, FL]: CRC press, 2014. ''' - val, found = database_constant_lookup(CASRN, 'S0l') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'S0l') + if found: return val if not _reaction_data_loaded: _load_reaction_data() if method: return retrieve_from_df_dict(S0l_sources, CASRN, 'S0l', method) @@ -688,8 +694,9 @@ def S0g(CASRN, method=None): .. [3] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' - val, found = database_constant_lookup(CASRN, 'S0g') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'S0g') + if found: return val if not _reaction_data_loaded: _load_reaction_data() if method: return retrieve_from_df_dict(S0g_sources, CASRN, 'S0g', method) diff --git a/chemicals/refractivity.py b/chemicals/refractivity.py index 0c9f43a6..867782c8 100644 --- a/chemicals/refractivity.py +++ b/chemicals/refractivity.py @@ -63,7 +63,7 @@ from fluids.constants import N_A, pi from fluids.numerics import horner, interp - +from chemicals import data_reader as dr from chemicals import miscdata from chemicals.data_reader import (data_source, database_constant_lookup, list_available_methods_from_df_dict, @@ -179,9 +179,10 @@ def RI(CASRN, method=None): Chemistry and Physics, 95E. Boca Raton, FL: CRC press, 2014. .. [2] Wikidata. Wikidata. Accessed via API. https://www.wikidata.org/ ''' - RI, found = database_constant_lookup(CASRN, 'RI') if method is None else (None, False) - RIT, _ = database_constant_lookup(CASRN, 'RIT') if method is None else (None, False) - if found: return (RI, RIT) + if dr.USE_CONSTANTS_DATABASE and method is None: + RI, found = database_constant_lookup(CASRN, 'dipole_moment') + RIT, _ = database_constant_lookup(CASRN, 'dipole_moment') + if found: return (RI, RIT) if not _RI_data_loaded: _load_RI_data() key = ('RI', 'RIT') if method: diff --git a/chemicals/safety.py b/chemicals/safety.py index 3e9ce1b5..644d833d 100644 --- a/chemicals/safety.py +++ b/chemicals/safety.py @@ -133,7 +133,7 @@ import os from fluids.core import F2K - +from chemicals import data_reader as dr from chemicals import miscdata from chemicals.data_reader import (data_source, database_constant_lookup, list_available_methods_from_df_dict, @@ -855,8 +855,9 @@ def T_flash(CASRN, method=None): (October 15, 2017): 52-59. doi:10.1016/j.fluid.2017.06.008. .. [4] Wikidata. Wikidata. Accessed via API. https://www.wikidata.org/ ''' - val, found = database_constant_lookup(CASRN, 'T_flash') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'T_flash') + if found: return val if not _safety_data_loaded: _load_safety_data() if method: return retrieve_from_df_dict(Tflash_sources, CASRN, 'T_flash', method) @@ -940,8 +941,9 @@ def T_autoignition(CASRN, method=None): and of Hazardous. NFPA, 2008. .. [3] Wikidata. Wikidata. Accessed via API. https://www.wikidata.org/ ''' - val, found = database_constant_lookup(CASRN, 'T_autoignition') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'T_autoignition') + if found: return val if not _safety_data_loaded: _load_safety_data() if method: return retrieve_from_df_dict(Tautoignition_sources, CASRN, 'T_autoignition', method) @@ -1044,8 +1046,9 @@ def LFL(Hc=None, atoms=None, CASRN='', method=None): and of Hazardous. NFPA, 2008. .. [3] Wikidata. Wikidata. Accessed via API. https://www.wikidata.org/ ''' - val, found = database_constant_lookup(CASRN, 'LFL') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'LFL') + if found: return val if not _safety_data_loaded: _load_safety_data() if not method: LFL = retrieve_any_from_df_dict(LFL_sources, CASRN, 'LFL') @@ -1159,8 +1162,9 @@ def UFL(Hc=None, atoms=None, CASRN='', method=None): and of Hazardous. NFPA, 2008. .. [3] Wikidata. Wikidata. Accessed via API. https://www.wikidata.org/ ''' - val, found = database_constant_lookup(CASRN, 'UFL') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'UFL') + if found: return val if not _safety_data_loaded: _load_safety_data() if not method: UFL = retrieve_any_from_df_dict(UFL_sources, CASRN, 'UFL') diff --git a/chemicals/triple.py b/chemicals/triple.py index b5ba284f..7f59189a 100644 --- a/chemicals/triple.py +++ b/chemicals/triple.py @@ -47,7 +47,7 @@ 'Pt_all_methods', 'Pt_methods', 'Pt'] import os - +from chemicals import data_reader as dr from chemicals import miscdata from chemicals.data_reader import (data_source, database_constant_lookup, list_available_methods_from_df_dict, @@ -169,8 +169,9 @@ def Tt(CASRN, method=None): .. [2] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' - val, found = database_constant_lookup(CASRN, 'Tt') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'Tt') + if found: return val if not _triple_data_loaded: _load_triple_data() if method: if method == MELTING: @@ -258,8 +259,9 @@ def Pt(CASRN, method=None): .. [2] Shen, V.K., Siderius, D.W., Krekelberg, W.P., and Hatch, H.W., Eds., NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' - val, found = database_constant_lookup(CASRN, 'Pt') if method is None else (None, False) - if found: return val + if dr.USE_CONSTANTS_DATABASE and method is None: + val, found = database_constant_lookup(CASRN, 'Pt') + if found: return val if not _triple_data_loaded: _load_triple_data() if method: return retrieve_from_df_dict(Pt_sources, CASRN, 'Pt', method) From a92e1647fc537af2a8ff6293af50e7b261ac956f Mon Sep 17 00:00:00 2001 From: Yoel Date: Tue, 24 May 2022 15:33:26 -0500 Subject: [PATCH 35/40] minor edits --- chemicals/data_reader.py | 24 ++++++++++++++---------- 1 file changed, 14 insertions(+), 10 deletions(-) diff --git a/chemicals/data_reader.py b/chemicals/data_reader.py index 1f3fc29d..075b38c3 100644 --- a/chemicals/data_reader.py +++ b/chemicals/data_reader.py @@ -78,8 +78,7 @@ def make_df_sparse(df, non_sparse_columns=[]): def register_df_source(folder, name, sep='\t', index_col=0, csv_kwargs=None, postload=None, sparsify=False, int_CAS=False): - if csv_kwargs is None: - csv_kwargs = {} + if csv_kwargs is None: csv_kwargs = {} load_cmds[name] = (folder, name, sep, index_col, csv_kwargs, postload, sparsify, int_CAS) '''The following flags will strip out the excess memory usage of redundant @@ -196,7 +195,7 @@ def get_value_from_df(df, index, key): def list_available_methods_from_df_dict(df_dict, index, key): methods = [] - int_index = None + int_index = None if isinstance(index, str) else index # Assume must be string or int for method, df in df_dict.items(): df_index = df.index if df_index.dtype is int64_dtype: @@ -205,6 +204,8 @@ def list_available_methods_from_df_dict(df_dict, index, key): int_index = CAS_to_int(index) except: int_index = 'skip' + else: + (int_index in df_index) and not isnan(df.at[int_index, key]) and methods.append(method) elif int_index != 'skip' and (int_index in df_index) and not isnan(df.at[int_index, key]): methods.append(method) elif (index in df_index) and not isnan(df.at[index, key]): @@ -235,17 +236,17 @@ def list_available_methods_from_df(df, index, keys_by_method): CONSTANTS_CURSOR = None DATABASE_CONSTANTS_CACHE = {} -def cached_constant_lookup(CASi, prop, cache=DATABASE_CONSTANTS_CACHE): +def cached_constant_lookup(CASi, prop): if CONSTANTS_CURSOR is None: init_constants_db() prop_idx = CONSTANT_DATABASE_NAME_TO_IDX[prop] - if CASi in cache: - return cache[CASi][prop_idx], True + if CASi in DATABASE_CONSTANTS_CACHE: + return DATABASE_CONSTANTS_CACHE[CASi][prop_idx], True # Fetch and store the whole row CONSTANTS_CURSOR.execute("SELECT * FROM constants WHERE `index`=?", (str(CASi),)) result = CONSTANTS_CURSOR.fetchone() - cache[CASi] = result + DATABASE_CONSTANTS_CACHE[CASi] = result if result is not None: return result[prop_idx], True @@ -259,14 +260,17 @@ def init_constants_db(): CONSTANTS_CURSOR = conn.cursor() def database_constant_lookup(CASi, prop): - print("ASDSAAAAAAAAAAAAAAA") if isinstance(CASi, str): - print(CASi) try: CASi = CAS_to_int(CASi) except: return None, False try: return cached_constant_lookup(CASi, prop) - except: + except Exception: + # Prevent database lookup after first failure considering it should work everytime. + # This fails on Yoel's machine due to "OperationalError: no such table: constants". + # It might possibly fail for other users every time (and maybe for other reasons). + global USE_CONSTANTS_DATABASE + USE_CONSTANTS_DATABASE = False return None, False From efbfc448deef3168073c588d38732301c78fdb60 Mon Sep 17 00:00:00 2001 From: Yoel Date: Tue, 24 May 2022 15:37:07 -0500 Subject: [PATCH 36/40] add explanatory comment --- chemicals/data_reader.py | 2 +- 1 file changed, 1 insertion(+), 1 deletion(-) diff --git a/chemicals/data_reader.py b/chemicals/data_reader.py index 075b38c3..78953a4a 100644 --- a/chemicals/data_reader.py +++ b/chemicals/data_reader.py @@ -260,7 +260,7 @@ def init_constants_db(): CONSTANTS_CURSOR = conn.cursor() def database_constant_lookup(CASi, prop): - if isinstance(CASi, str): + if isinstance(CASi, str): # Assume it must be either an int or string try: CASi = CAS_to_int(CASi) except: From 654ce2216b13a4298ccb7e8594f8df077edb9c31 Mon Sep 17 00:00:00 2001 From: Yoel Date: Tue, 24 May 2022 15:46:33 -0500 Subject: [PATCH 37/40] do not switch off database lookup due to dict errors --- chemicals/data_reader.py | 2 ++ 1 file changed, 2 insertions(+) diff --git a/chemicals/data_reader.py b/chemicals/data_reader.py index 78953a4a..13e54f23 100644 --- a/chemicals/data_reader.py +++ b/chemicals/data_reader.py @@ -267,6 +267,8 @@ def database_constant_lookup(CASi, prop): return None, False try: return cached_constant_lookup(CASi, prop) + except TypeError as e: + raise e from None except Exception: # Prevent database lookup after first failure considering it should work everytime. # This fails on Yoel's machine due to "OperationalError: no such table: constants". From 0363d9427f25243180e8da1cecc50c7fe0cc9f58 Mon Sep 17 00:00:00 2001 From: Yoel Date: Tue, 24 May 2022 15:50:50 -0500 Subject: [PATCH 38/40] do not switch off sql lookup if user error --- chemicals/data_reader.py | 2 +- 1 file changed, 1 insertion(+), 1 deletion(-) diff --git a/chemicals/data_reader.py b/chemicals/data_reader.py index 13e54f23..44eba1e4 100644 --- a/chemicals/data_reader.py +++ b/chemicals/data_reader.py @@ -267,7 +267,7 @@ def database_constant_lookup(CASi, prop): return None, False try: return cached_constant_lookup(CASi, prop) - except TypeError as e: + except (TypeError, KeyError) as e: raise e from None except Exception: # Prevent database lookup after first failure considering it should work everytime. From bdb4e456d4b398248a086b4aefd5080229f257c3 Mon Sep 17 00:00:00 2001 From: Yoel Date: Sun, 29 May 2022 19:56:04 -0500 Subject: [PATCH 39/40] fix bugs introduced in PR enhancement --- chemicals/data_reader.py | 28 +++++++++++++--------------- chemicals/molecular_geometry.py | 2 +- chemicals/reaction.py | 2 +- chemicals/refractivity.py | 4 ++-- 4 files changed, 17 insertions(+), 19 deletions(-) diff --git a/chemicals/data_reader.py b/chemicals/data_reader.py index 44eba1e4..186485b2 100644 --- a/chemicals/data_reader.py +++ b/chemicals/data_reader.py @@ -237,21 +237,20 @@ def list_available_methods_from_df(df, index, keys_by_method): DATABASE_CONSTANTS_CACHE = {} def cached_constant_lookup(CASi, prop): - if CONSTANTS_CURSOR is None: - init_constants_db() - prop_idx = CONSTANT_DATABASE_NAME_TO_IDX[prop] + if CONSTANTS_CURSOR is None: init_constants_db() if CASi in DATABASE_CONSTANTS_CACHE: - return DATABASE_CONSTANTS_CACHE[CASi][prop_idx], True - - # Fetch and store the whole row - CONSTANTS_CURSOR.execute("SELECT * FROM constants WHERE `index`=?", (str(CASi),)) - result = CONSTANTS_CURSOR.fetchone() - DATABASE_CONSTANTS_CACHE[CASi] = result - if result is not None: + result = DATABASE_CONSTANTS_CACHE[CASi] + else: + # Fetch and store the whole row + CONSTANTS_CURSOR.execute("SELECT * FROM constants WHERE `index`=?", (str(CASi),)) + result = CONSTANTS_CURSOR.fetchone() + DATABASE_CONSTANTS_CACHE[CASi] = result + if result is None: + # Result the value, and whether the compound was in the index + return result, False + else: + prop_idx = CONSTANT_DATABASE_NAME_TO_IDX[prop] return result[prop_idx], True - - # Result the value, and whether the compound was in the index - return result, False def init_constants_db(): global CONSTANTS_CURSOR @@ -271,8 +270,7 @@ def database_constant_lookup(CASi, prop): raise e from None except Exception: # Prevent database lookup after first failure considering it should work everytime. - # This fails on Yoel's machine due to "OperationalError: no such table: constants". - # It might possibly fail for other users every time (and maybe for other reasons). + # It will possibly fail for users every time if database has not been created. global USE_CONSTANTS_DATABASE USE_CONSTANTS_DATABASE = False return None, False diff --git a/chemicals/molecular_geometry.py b/chemicals/molecular_geometry.py index 2ccfa04a..602c1cc9 100644 --- a/chemicals/molecular_geometry.py +++ b/chemicals/molecular_geometry.py @@ -259,7 +259,7 @@ def linear(CASRN, method=None): ''' if dr.USE_CONSTANTS_DATABASE and method is None: val, found = database_constant_lookup(CASRN, 'linear') - if found: return bool(found) + if found: return bool(val) if not _RG_data_loaded: _load_RG_data() if method: value = retrieve_from_df_dict(linear_sources, CASRN, 'linear', method) diff --git a/chemicals/reaction.py b/chemicals/reaction.py index 779b7677..7d425ad1 100644 --- a/chemicals/reaction.py +++ b/chemicals/reaction.py @@ -526,7 +526,7 @@ def S0s(CASRN, method=None): NIST WebBook, NIST, http://doi.org/10.18434/T4M88Q ''' if dr.USE_CONSTANTS_DATABASE and method is None: - val, found = database_constant_lookup(CASRN, 'S02') + val, found = database_constant_lookup(CASRN, 'S0s') if found: return val if not _reaction_data_loaded: _load_reaction_data() if method: diff --git a/chemicals/refractivity.py b/chemicals/refractivity.py index 867782c8..ed8984ea 100644 --- a/chemicals/refractivity.py +++ b/chemicals/refractivity.py @@ -180,8 +180,8 @@ def RI(CASRN, method=None): .. [2] Wikidata. Wikidata. Accessed via API. https://www.wikidata.org/ ''' if dr.USE_CONSTANTS_DATABASE and method is None: - RI, found = database_constant_lookup(CASRN, 'dipole_moment') - RIT, _ = database_constant_lookup(CASRN, 'dipole_moment') + RI, found = database_constant_lookup(CASRN, 'RI') + RIT, _ = database_constant_lookup(CASRN, 'RIT') if found: return (RI, RIT) if not _RI_data_loaded: _load_RI_data() key = ('RI', 'RIT') From 7c7b834393e23ffa66b624e581e0e63171537f0a Mon Sep 17 00:00:00 2001 From: Caleb Bell Date: Wed, 1 Jun 2022 21:43:41 -0600 Subject: [PATCH 40/40] Update chemsep data --- .../Misc/{ChemSep8.26.xml => ChemSep8.30.xml} | 387 ++++++++++-------- chemicals/utils.py | 79 +++- dev/data/chemsep_radius_of_gyration.py | 2 +- tests/test_identifiers.py | 2 +- 4 files changed, 302 insertions(+), 168 deletions(-) rename chemicals/Misc/{ChemSep8.26.xml => ChemSep8.30.xml} (99%) diff --git a/chemicals/Misc/ChemSep8.26.xml b/chemicals/Misc/ChemSep8.30.xml similarity index 99% rename from chemicals/Misc/ChemSep8.26.xml rename to chemicals/Misc/ChemSep8.30.xml index f2631ed5..3fcff6da 100644 --- a/chemicals/Misc/ChemSep8.26.xml +++ b/chemicals/Misc/ChemSep8.30.xml @@ -1,4 +1,4 @@ - + @@ -3644,7 +3644,7 @@ - + @@ -6546,7 +6546,7 @@ - + @@ -8647,7 +8647,7 @@ - + @@ -10861,7 +10861,7 @@ - + @@ -11324,7 +11324,7 @@ - + @@ -12208,7 +12208,7 @@ - + @@ -14446,7 +14446,7 @@ - + @@ -14683,7 +14683,7 @@ - + @@ -15122,7 +15122,7 @@ - + @@ -19309,7 +19309,7 @@ - + @@ -19524,7 +19524,7 @@ - + @@ -20199,7 +20199,7 @@ - + @@ -20436,7 +20436,7 @@ - + @@ -20672,7 +20672,7 @@ - + @@ -21328,14 +21328,14 @@ - - - - - - - - + + + + + + + + @@ -21375,7 +21375,7 @@ - + @@ -23182,7 +23182,7 @@ - + @@ -23414,7 +23414,7 @@ - + @@ -25700,7 +25700,7 @@ - + @@ -25923,7 +25923,7 @@ - + @@ -26149,7 +26149,7 @@ - + @@ -27499,7 +27499,7 @@ - + @@ -27954,7 +27954,7 @@ - + @@ -28845,7 +28845,7 @@ - + @@ -30212,10 +30212,10 @@ - + - + @@ -30893,7 +30893,7 @@ - + @@ -32510,7 +32510,7 @@ - + @@ -39215,7 +39215,7 @@ - + @@ -39441,6 +39441,7 @@ + @@ -39895,7 +39896,7 @@ - + @@ -40341,7 +40342,7 @@ - + @@ -41008,10 +41009,10 @@ - + - + @@ -41229,10 +41230,10 @@ - + - + @@ -41890,9 +41891,9 @@ - + - + @@ -43006,7 +43007,7 @@ - + @@ -43163,7 +43164,7 @@ - + @@ -43346,7 +43347,7 @@ - + @@ -43543,7 +43544,7 @@ - + @@ -44330,7 +44331,7 @@ - + @@ -44948,7 +44949,7 @@ - + @@ -45163,7 +45164,7 @@ - + @@ -45387,7 +45388,7 @@ - + @@ -45608,10 +45609,10 @@ - + - + @@ -45831,7 +45832,7 @@ - + @@ -46062,7 +46063,7 @@ - + @@ -46284,7 +46285,7 @@ - + @@ -46507,7 +46508,7 @@ - + @@ -46730,7 +46731,7 @@ - + @@ -46953,7 +46954,7 @@ - + @@ -47176,7 +47177,7 @@ - + @@ -47399,7 +47400,7 @@ - + @@ -47621,7 +47622,7 @@ - + @@ -51817,7 +51818,7 @@ - + @@ -61876,7 +61877,7 @@ - + @@ -62106,7 +62107,7 @@ - + @@ -62336,7 +62337,7 @@ - + @@ -62558,7 +62559,7 @@ - + @@ -62787,7 +62788,7 @@ - + @@ -63027,7 +63028,7 @@ - + @@ -67212,7 +67213,7 @@ - + @@ -69521,7 +69522,7 @@ - + @@ -70881,7 +70882,7 @@ - + @@ -71529,7 +71530,7 @@ - + @@ -71753,7 +71754,7 @@ - + @@ -71985,7 +71986,7 @@ - + @@ -74893,7 +74894,7 @@ - + @@ -81989,7 +81990,7 @@ - + @@ -82440,7 +82441,7 @@ - + @@ -82667,7 +82668,7 @@ - + @@ -82869,7 +82870,7 @@ - + @@ -83740,7 +83741,7 @@ - + @@ -83954,10 +83955,10 @@ - + - + @@ -84616,7 +84617,7 @@ - + @@ -85956,7 +85957,7 @@ - + @@ -86189,7 +86190,7 @@ - + @@ -87301,7 +87302,7 @@ - + @@ -87728,7 +87729,7 @@ - + @@ -87931,7 +87932,7 @@ - + @@ -88354,7 +88355,7 @@ - + @@ -88566,7 +88567,7 @@ - + @@ -88781,7 +88782,7 @@ - + @@ -88997,7 +88998,7 @@ - + @@ -89211,9 +89212,9 @@ - + - + @@ -89404,9 +89405,9 @@ - + - + @@ -89612,7 +89613,7 @@ - + @@ -89763,7 +89764,7 @@ - + @@ -89972,7 +89973,7 @@ - + @@ -90187,7 +90188,7 @@ - + @@ -90801,10 +90802,10 @@ - + - + @@ -91024,7 +91025,7 @@ - + @@ -91431,7 +91432,7 @@ - + @@ -91606,14 +91607,14 @@ - - - - - - - - + + + + + + + + @@ -91704,6 +91705,15 @@ + + + + + + + + + @@ -91738,6 +91748,16 @@ + + + + + + + + + + @@ -91745,6 +91765,16 @@ + + + + + + + + + + @@ -91776,7 +91806,7 @@ - + @@ -91872,6 +91902,16 @@ + + + + + + + + + + @@ -91883,10 +91923,10 @@ - - - - + + + + @@ -91895,7 +91935,7 @@ - + @@ -91988,6 +92028,16 @@ + + + + + + + + + + @@ -92010,7 +92060,7 @@ - + @@ -92103,6 +92153,16 @@ + + + + + + + + + + @@ -92125,7 +92185,7 @@ - + @@ -92252,14 +92312,14 @@ - - - + + + - - - - + + + + @@ -92284,7 +92344,7 @@ - + @@ -92459,14 +92519,14 @@ - - - - - - - - + + + + + + + + @@ -92503,7 +92563,7 @@ - + @@ -92679,13 +92739,13 @@ - - - - - - - + + + + + + + @@ -92723,7 +92783,7 @@ - + @@ -93437,7 +93497,7 @@ - + @@ -93872,7 +93932,7 @@ - + @@ -94101,7 +94161,7 @@ - + @@ -94561,7 +94621,7 @@ - + @@ -94606,7 +94666,7 @@ - + @@ -94614,13 +94674,13 @@ - - - - - + + + + + - + @@ -94730,11 +94790,11 @@ - - - + + + - + @@ -94746,6 +94806,7 @@ + diff --git a/chemicals/utils.py b/chemicals/utils.py index 12a62bd6..dd063671 100644 --- a/chemicals/utils.py +++ b/chemicals/utils.py @@ -40,7 +40,7 @@ 'Vfs_to_zs', 'none_and_length_check', 'normalize', 'remove_zeros', 'mixing_simple', 'mixing_logarithmic', 'mixing_power', 'to_num', 'Parachor', 'property_molar_to_mass', 'property_mass_to_molar', -'SG_to_API', 'API_to_SG', 'SG', 'Watson_K', +'SG_to_API', 'API_to_SG', 'API_to_rho', 'rho_to_API', 'SG', 'Watson_K', 'dxs_to_dns', 'dns_to_dn_partials', 'dxs_to_dn_partials', 'd2ns_to_dn2_partials', 'd2xs_to_dxdn_partials', 'dxs_to_dxsn1', 'd2xs_to_d2xsn1', 'vapor_mass_quality', 'mix_component_flows', @@ -430,9 +430,82 @@ def vapor_mass_quality(VF, MWl, MWg): nl = (1. - VF) return ng*MWg/(nl*MWl + ng*MWg) +def rho_to_API(rho, rho_ref=999.0170824078306): + r'''Calculates API of a liquid given its mass density, as shown in + [1]_. + + .. math:: + \text{API gravity} = \frac{141.5\rho_{ref}}{\rho} - 131.5 + + Parameters + ---------- + rho : float + Mass density the fluid at 60 degrees Farenheight [kg/m^3] + rho_ref : float, optional + Density of the reference substance, [kg/m^3] + + Returns + ------- + API : float + API of the fluid [-] + + Notes + ----- + Defined only at 60 degrees Fahrenheit. + + Examples + -------- + >>> rho_to_API(820) + 40.8913623 + >>> SG_to_API(SG(820)) + 40.8913623 + + References + ---------- + .. [1] API Technical Data Book: General Properties & Characterization. + American Petroleum Institute, 7E, 2005. + ''' + return 141.5*rho_ref/rho - 131.5 + +def API_to_rho(API, rho_ref=999.0170824078306): + r'''Calculates mass density of a liquid given its API, as shown in + [1]_. + + .. math:: + \rho~60^\circ\text{F} = \frac{141.5\rho_{ref}}{\text{API} + 131.5} + + Parameters + ---------- + API : float + API of the fluid [-] + rho_ref : float, optional + Density of the reference substance, [kg/m^3] + + Returns + ------- + rho : float + Mass density the fluid at 60 degrees Farenheight [kg/m^3] + + Notes + ----- + Defined only at 60 degrees Fahrenheit. + + Examples + -------- + >>> API_to_rho(rho_to_API(820)) + 820.0 + + References + ---------- + .. [1] API Technical Data Book: General Properties & Characterization. + American Petroleum Institute, 7E, 2005. + ''' + return (141.5*rho_ref)/(API + 131.5) + + def SG_to_API(SG): - r'''Calculates specific gravity of a liquid given its API, as shown in + r'''Calculates API of a liquid given its specific gravity, as shown in [1]_. .. math:: @@ -466,7 +539,7 @@ def SG_to_API(SG): def API_to_SG(API): - r'''Calculates API of a liquid given its specific gravity, as shown in + r'''Calculates specific gravity of a liquid given its API, as shown in [1]_. .. math:: diff --git a/dev/data/chemsep_radius_of_gyration.py b/dev/data/chemsep_radius_of_gyration.py index d265d27c..76eabca0 100644 --- a/dev/data/chemsep_radius_of_gyration.py +++ b/dev/data/chemsep_radius_of_gyration.py @@ -25,7 +25,7 @@ import xml.etree.cElementTree as ET folder = os.path.join(os.path.dirname(__file__), '..','..', 'chemicals', 'Misc') -tree = ET.parse(os.path.join(folder, 'ChemSep8.26.xml')) +tree = ET.parse(os.path.join(folder, 'ChemSep8.30.xml')) root = tree.getroot() radius_of_gyrations = {} diff --git a/tests/test_identifiers.py b/tests/test_identifiers.py index 32112e58..2ad735f8 100644 --- a/tests/test_identifiers.py +++ b/tests/test_identifiers.py @@ -410,7 +410,7 @@ def test_db_vs_ChemSep(): import xml.etree.cElementTree as ET folder = os.path.join(os.path.dirname(__file__), '..', 'chemicals', 'Misc') - tree = ET.parse(os.path.join(folder, 'ChemSep8.26.xml')) + tree = ET.parse(os.path.join(folder, 'ChemSep8.30.xml')) root = tree.getroot() data = {}