Explain how the porosity of crosslinked polystyrene can be controlled during its synthesis. What factors influence the pore size and distribution of crosslinked polystyrene?
The porosity of crosslinked polystyrene can be controlled during its synthesis by varying the molar mass of the sacrificial PLA block. This will influence the pore size and distribution of crosslinked polystyrene, as well as its surface area. The Friedel-Craft reaction can also be used to synthesize polystyrene-based hyper-cross-linked polymers (HCPs) in various situations. Additionally, conjugated PAE networks with high BET surface areas can be synthesized through careful control of the pore dimension. Finally, the porous structure of hypercrosslinked polystyrene can be adjusted to increase its surface area for adsorption purposes.
And what about the temperature and duration of the polymerization as a way to impact in the porosity of the crosslinked polystyrene?
The temperature and duration of the polymerization process can impact the porosity of crosslinked polystyrene. Here are some ways that temperature and duration can affect the porosity of crosslinked polystyrene:

- Pre-polymerization stage: During this stage, the target morphology and particle size are essentially predefined. The reaction is generally carried out at 100-150°C with yields of up to 15-30%. This means that the temperature used during this stage can impact the resulting morphology and particle size, which can in turn affect the porosity of the final product.
- Post-polymerization: During this stage, the polymerization reaction is continued to give higher yields with correspondingly higher viscosities. This means that the duration of the polymerization process can impact the viscosity of the final product, which can affect the porosity of the foam.
- Nanoparticles: One way to improve the porosity of polymer foams is to add nanoparticles to the polymer. Nanoparticles behave like nucleating agents that cells nucleate at the boundary between polymer and the nanoparticle. During the foaming process, nanoparticles contribute to the homogeneous dispersion of the nanoparticles in the polymer matrix, which improves the properties of the polymer foams and generates multifunctional material as polymer nanocomposite foams. For example, graphene-reinforced polymer foams have been shown to have a great effect on cell nucleation and mechanical strength.
- Glass transition temperature: The glass transition temperature (Tg) of a polymer is the temperature at which an amorphous polymer changes from a hard/glassy state to a soft/leathery state, or vice versa. Tg is directly related to a material’s strength and capabilities in any given end-use application. Glass transition temperature is tied to a polymer’s mechanical properties, including its tensile strength, impact resistance, modulus of elasticity, and its operational temperature range. The Tg of a polymer can affect its porosity by impacting its mechanical properties, which can in turn affect the foam structure.

It is important to note that the porosity of crosslinked polystyrene can also be affected by factors such as the type of polymerization (anionic vs. cationic), the monomers used, and the presence of other additives or foaming agents.