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Do you have any kind of applescript that can do this today?
The proxy state, and other options, can be toggled using the networksetup command line tool. For example:
networksetup -setwebproxystate Ethernet off
Seems like something that ought to be done via network location?
Setting this via the Network Locations feature is the best way to handle proxy configuration. A little more work from the ControlPlane side to setup several but already supported.
Terminal command for switching is "scselect" in Mavericks FYI.