Fix synchronous HEAD request (#3188)

When making a HEAD requests the response does not contain a ContentType. The Async version of `Request` already has this check, however the synchronous call fails with a NullReferenceException.

Author: VanHuychemG

src/Elasticsearch.Net/Connection/HttpConnection-CoreFx.cs

@@ -72,7 +72,7 @@ public virtual TResponse Request<TResponse>(RequestData requestData)
 				statusCode = (int) responseMessage.StatusCode;
 
 				responseMessage.Headers.TryGetValues("Warning", out warnings);
-				mimeType = responseMessage.Content.Headers.ContentType.ToString();
+				mimeType = responseMessage.Content.Headers.ContentType?.MediaType;
 
 				if (responseMessage.Content != null)
 					responseStream = responseMessage.Content.ReadAsStreamAsync().GetAwaiter().GetResult();