diff --git a/clang/docs/ReleaseNotes.rst b/clang/docs/ReleaseNotes.rst
index 829ec2e334a06..79c495d072b2d 100644
--- a/clang/docs/ReleaseNotes.rst
+++ b/clang/docs/ReleaseNotes.rst
@@ -375,6 +375,10 @@ Bug Fixes to C++ Support
 - Fixed a bug causing destructors of constant-evaluated structured bindings
   initialized by array elements to be called in the wrong evaluation context.
 
+- Fix crash where ill-formed code was being treated as a deduction guide and
+  we now produce a diagnostic. Fixes:
+  (`#65522 <https://github.com/llvm/llvm-project/issues/65522>`_)
+
 Bug Fixes to AST Handling
 ^^^^^^^^^^^^^^^^^^^^^^^^^
 - Fixed an import failure of recursive friend class template.
diff --git a/clang/include/clang/Basic/DiagnosticSemaKinds.td b/clang/include/clang/Basic/DiagnosticSemaKinds.td
index 29362df683653..f12713a9094d8 100644
--- a/clang/include/clang/Basic/DiagnosticSemaKinds.td
+++ b/clang/include/clang/Basic/DiagnosticSemaKinds.td
@@ -5414,6 +5414,8 @@ def note_constraint_normalization_here : Note<
 def note_parameter_mapping_substitution_here : Note<
   "while substituting into concept arguments here; substitution failures not "
   "allowed in concept arguments">;
+def note_building_deduction_guide_here : Note<
+  "while building implicit deduction guide first needed here">;
 def note_lambda_substitution_here : Note<
   "while substituting into a lambda expression here">;
 def note_instantiation_contexts_suppressed : Note<
diff --git a/clang/lib/Sema/SemaTemplateInstantiate.cpp b/clang/lib/Sema/SemaTemplateInstantiate.cpp
index 00a36696cf904..1ed3df5a011bc 100644
--- a/clang/lib/Sema/SemaTemplateInstantiate.cpp
+++ b/clang/lib/Sema/SemaTemplateInstantiate.cpp
@@ -1075,7 +1075,9 @@ void Sema::PrintInstantiationStack() {
           << Active->InstantiationRange;
       break;
     case CodeSynthesisContext::BuildingDeductionGuides:
-      llvm_unreachable("unexpected deduction guide in instantiation stack");
+      Diags.Report(Active->PointOfInstantiation,
+                   diag::note_building_deduction_guide_here);
+      break;
     }
   }
 }
diff --git a/clang/test/SemaCXX/gh65522.cpp b/clang/test/SemaCXX/gh65522.cpp
new file mode 100644
index 0000000000000..2d6331b0372a3
--- /dev/null
+++ b/clang/test/SemaCXX/gh65522.cpp
@@ -0,0 +1,11 @@
+// RUN: %clang_cc1 -std=c++20 -Wc++17-compat -verify -Wno-unused %s
+
+class X {};
+
+template<typename T>
+class B3 { // expected-note {{candidate template ignored: could not match 'B3<T>' against 'int'}}
+  template<X x> B3(T); // expected-warning 2{{non-type template parameter of type 'X' is incompatible with C++ standards before C++20}} \
+                       // expected-note {{candidate template ignored: couldn't infer template argument 'x'}}
+};
+B3 b3 = 0; // expected-error {{no viable constructor or deduction guide for deduction of template arguments of 'B3'}} \
+           // expected-note {{while building implicit deduction guide first needed here}}