diff --git a/Lib/pathlib.py b/Lib/pathlib.py
index 3d68c161603d08..52a6288f342a9c 100644
--- a/Lib/pathlib.py
+++ b/Lib/pathlib.py
@@ -300,6 +300,9 @@ def __init__(self, *args):
         for arg in args:
             if isinstance(arg, PurePath):
                 path = arg._raw_path
+                if arg._flavour is ntpath and self._flavour is posixpath:
+                    # GH-103631: Convert separators for backwards compatibility.
+                    path = path.replace('\\', '/')
             else:
                 try:
                     path = os.fspath(arg)
diff --git a/Lib/test/test_pathlib.py b/Lib/test/test_pathlib.py
index ab2c2b232a0411..e5fd581b8cfd2f 100644
--- a/Lib/test/test_pathlib.py
+++ b/Lib/test/test_pathlib.py
@@ -789,6 +789,12 @@ def test_div(self):
         pp = P('//a') / '/c'
         self.assertEqual(pp, P('/c'))
 
+    def test_parse_windows_path(self):
+        P = self.cls
+        p = P('c:', 'a', 'b')
+        pp = P(pathlib.PureWindowsPath('c:\\a\\b'))
+        self.assertEqual(p, pp)
+
 
 class PureWindowsPathTest(_BasePurePathTest, unittest.TestCase):
     cls = pathlib.PureWindowsPath
diff --git a/Misc/NEWS.d/next/Library/2023-05-25-23-34-54.gh-issue-103631.x5Urye.rst b/Misc/NEWS.d/next/Library/2023-05-25-23-34-54.gh-issue-103631.x5Urye.rst
new file mode 100644
index 00000000000000..d1eb2d3ed6191f
--- /dev/null
+++ b/Misc/NEWS.d/next/Library/2023-05-25-23-34-54.gh-issue-103631.x5Urye.rst
@@ -0,0 +1,2 @@
+Fix ``pathlib.PurePosixPath(pathlib.PureWindowsPath(...))`` not converting
+path separators to restore 3.11 compatible behavior.