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I've modified the file https://github.com/scipy/scipy/blob/master/scipy/io/wavfile.py over the past years to add 24-bit WAV files read/write support, cue markers support, loop makers support, etc.
If you're interested, feel free to reuse this / commit (I won't have time to do a pull request soon).
Note: In WAV audio files, 24-bit is probably the most used bitrate for instrument sample sets, music production, sound engineering; much more than 16-bit (CD) or 32-bit (used in music software as internal processing bitrate).