Stereodepiction Brecher would not approve of

[egonw]

@johnmay, is there anything that you think that can be done on the choice of bonds to use the wedge for on the bridgehead carbons for these two SMILES:

Cl[C@@]12C(=C([C@@]([C@@H]3COS(OC[C@@H]31)=O)(C2(Cl)Cl)Cl)Cl)Cl
Cl[C@]12C(=C([C@]([C@@H]3COS(OC[C@@H]31)=O)(C2(Cl)Cl)Cl)Cl)Cl

According to Brecher (below, right), this wedges on the two bonds to the two chlorines should be on the bonds towards the middle bridging CCl2 group, I think (whereas those on the bonds to the hydrogens in the above seem fine, per below left):

[johnmay]

But I agree it looks nicer, would be a bit of extra working when choosing which bond to wedge but is possible.

[egonw]

Yeah, if too complicated, then ignore it. Certainly not anything urgent.