MCM & GECKO–A photolysis parameterisations

MCM photolysis parameterisations

The table below lists improved MCM/GECKO-A photolysis parameterisations, which include a dependence on the overlying ozone column. At 350DU they are identical the original MCM photolysis parameterisation:

j(χ) = l·cosᵐ(χ)·exp(-n·sec(χ))

where j is in s^-1. For other ozone columns l is redefined to:

l([O3]) = l_a0 + l_b0·exp(l_b1/[O3]) + l_c0·exp(l_c1/[O3])

where l, l_a0, l_b0, l_c0 are in s^-1 and l_b1, l_c1 are in DU.

Download the parameters as formatted text file or csv file.

MCM/GECKO-A	TUV	la0	lb0	lb1	lc0	lc1	l(350DU)	m	n	TUV label
J(1)	2	(2.038±0.111)·10-5	(4.109±0.224)·10-4	157.66±9.04	(1.563±0.085)·10-3	35.13±2.04	6.508·10-5	1.844±0.073	0.429±0.055	O3 -> O2 + O(1D)
J(2)	3	(4.893±0.036)·10-4	(1.562±0.012)·10-4	548.91±5.17	(1.325±0.010)·10-4	41.63±0.41	5.719·10-4	0.240±0.018	0.151±0.008	O3 -> O2 + O(3P)
J(3)	5	(9.043±0.338)·10-6	(1.595±0.060)·10-5	46.42±1.75	(1.221±0.046)·10-5	311.23±11.72	1.302·10-5	0.812±0.062	0.306±0.039	H2O2 -> 2 OH
J(4)	6	(1.476±0.048)·10-2	(3.048±0.093)·10-4	92.35±6.29	(1.126±0.034)·10-3	1102.90±48.32	1.559·10-2	0.321±0.058	0.284±0.032	NO2 -> NO + O(3P)
J(5)	7	(-1.113±0.010)·10-3	(1.641±0.014)·10-2	7950.01±67.93	(1.641±0.014)·10-2	8286.26±70.80	3.032·10-2	0.090±0.021	0.179±0.009	NO3 -> NO + O2
J(6)	8	(1.199±0.013)·10-1	(6.907±0.074)·10-2	5587.14±59.73	(6.911±0.074)·10-2	5648.23±60.38	2.497·10-1	0.095±0.025	0.196±0.012	NO3 -> NO2 + O(3P)
J(7)	12	(2.620±0.088)·10-3	(9.349±0.312)·10-6	38.45±1.33	(1.926±0.064)·10-4	1182.53±46.46	2.763·10-3	0.353±0.063	0.299±0.035	HNO2 -> OH + NO
J(8)	13	(5.250±0.205)·10-7	(7.022±0.274)·10-6	40.55±1.58	(2.885±0.113)·10-6	214.41±8.37	1.090·10-6	1.298±0.058	0.323±0.040	HNO3 -> OH + NO2
J(9)	18	(3.392±0.133)·10-6	(1.214±0.048)·10-5	246.80±9.76	(2.878±0.113)·10-5	40.29±1.60	6.337·10-6	1.063±0.060	0.375±0.040	HNO4 -> HO2 + NO2
J(10)	19	(2.358±0.093)·10-6	(2.003±0.079)·10-5	40.25±1.59	(8.440±0.332)·10-6	246.69±9.74	4.404·10-6	1.063±0.060	0.375±0.040	HNO4 -> OH + NO3
J(11011)	22	(4.016±0.165)·10-5	(6.623±0.272)·10-5	394.87±16.35	(4.194±0.172)·10-5	56.55±2.34	6.754·10-5	0.786±0.066	0.379±0.042	CH2O -> H + HCO
J(11012)	23	(7.026±0.272)·10-5	(3.418±0.132)·10-5	502.07±19.54	(1.605±0.062)·10-5	60.56±2.36	8.733·10-5	0.580±0.067	0.324±0.040	CH2O -> H2 + CO
J(11021)	24	(2.751±0.123)·10-6	(4.072±0.183)·10-5	44.47±2.01	(2.284±0.102)·10-5	219.45±9.91	7.401·10-6	1.342±0.064	0.455±0.046	CH3CHO -> CH3 + HCO
J(11022)	26	(3.245±0.157)·10-7	(6.236±0.303)·10-6	44.43±2.16	(3.807±0.185)·10-6	211.90±10.28	1.057·10-6	1.364±0.067	0.576±0.049	CH3CHO -> CH3CO + H
J(82011)	27	(4.382±0.177)·10-5	(8.068±0.326)·10-5	51.50±2.22	(8.904±0.359)·10-5	332.44±14.32	7.498·10-5	0.880±0.064	0.356±0.042	genCH3CHO(poly)
J(11031)	28	(3.727±0.204)·10-6	(2.174±0.119)·10-4	44.70±2.46	(1.650±0.090)·10-4	185.10±10.21	2.872·10-5	1.175±0.070	1.251±0.055	C2H5CHO -> C2H5 + HCO
J(15021)	29	(1.145±0.048)·10-5	(6.025±0.253)·10-5	46.85±1.98	(4.546±0.191)·10-5	269.87±11.41	2.391·10-5	1.080±0.063	0.395±0.043	ALD3OH -> R(OH) + HCO
J(82021)	30	(4.843±0.197)·10-5	(1.085±0.044)·10-4	324.69±14.09	(1.004±0.041)·10-4	51.17±2.22	8.546·10-5	0.907±0.064	0.360±0.042	genC2H5CHO(poly)
J(83011)	31	(1.528±0.064)·10-5	(6.065±0.254)·10-5	269.57±11.37	(8.026±0.336)·10-5	46.83±1.97	3.188·10-5	1.080±0.063	0.395±0.043	genC2H5CHO(OHpoly)
J(61011)	32	(6.604±0.238)·10-6	(9.400±0.339)·10-6	46.68±1.70	(7.447±0.269)·10-6	313.51±11.38	9.048·10-6	0.769±0.061	0.292±0.038	CH3OOH -> CH3O + OH
J(65011)	33	(6.410±0.231)·10-6	(8.678±0.312)·10-6	47.38±1.72	(7.015±0.253)·10-6	317.07±11.49	8.741·10-6	0.760±0.061	0.292±0.037	HOCH2OOH -> HOCH2O. + OH
J(41011)	34	(8.077±0.328)·10-7	(4.355±0.177)·10-6	222.86±9.05	(1.009±0.041)·10-5	40.81±1.66	1.715·10-6	1.257±0.060	0.354±0.042	CH3ONO2 -> CH3O + NO2
J(47011)	35	(4.517±0.184)·10-6	(2.192±0.089)·10-5	241.01±9.88	(5.270±0.215)·10-5	40.00±1.64	9.656·10-6	1.103±0.060	0.448±0.042	CH3(OONO2) -> CH3(OO) + NO2
J(41021)	37	(1.273±0.050)·10-6	(6.469±0.256)·10-6	223.65±8.84	(1.451±0.057)·10-5	41.34±1.63	2.629·10-6	1.245±0.059	0.342±0.040	C2H5ONO2 -> C2H5O + NO2
J(41031)	38	(1.815±0.066)·10-6	(1.572±0.057)·10-5	41.42±1.50	(6.794±0.246)·10-6	225.55±8.17	3.258·10-6	1.179±0.056	0.280±0.037	n-C3H7ONO2 -> C3H7O + NO2
J(41041)	39	(1.754±0.064)·10-6	(6.819±0.250)·10-6	224.77±8.25	(1.598±0.059)·10-5	40.80±1.50	3.194·10-6	1.190±0.056	0.285±0.038	1-C4H9ONO2 -> 1-C4H9O + NO2
J(41121)	40	(1.403±0.062)·10-6	(2.902±0.128)·10-5	41.02±1.82	(1.293±0.057)·10-5	219.57±9.76	4.035·10-6	1.232±0.062	0.586±0.045	2-C4H9ONO2 -> 2-C4H9O + NO2
J(41111)	41	(2.177±0.085)·10-6	(9.482±0.370)·10-6	233.06±9.16	(1.958±0.076)·10-5	42.28±1.66	4.294·10-6	1.195±0.059	0.328±0.040	CH3CHONO2CH3 -> CH3CHOCH3 + NO2
J(45011)	42	(6.372±0.271)·10-8	(4.913±0.209)·10-6	34.65±1.47	(1.076±0.046)·10-6	156.26±6.65	1.785·10-7	1.748±0.058	0.416±0.043	CH2(OH)CH2(ONO2) -> CH2(OH)CH2(O.) + NO2
J(81011)	43	(3.019±0.121)·10-5	(8.336±0.334)·10-5	48.97±1.97	(7.456±0.298)·10-5	301.26±12.14	5.359·10-5	0.952±0.063	0.353±0.041	CH3COCH2(ONO2) -> CH3COCH2(O.) + NO2
J(42021)	44	(7.502±0.291)·10-6	(3.478±0.135)·10-5	44.93±1.76	(2.213±0.086)·10-5	264.86±10.35	1.342·10-5	1.043±0.060	0.327±0.040	C(CH3)3(ONO2) -> C(CH3)3(O.) + NO2
J(48011)	46	(4.292±0.152)·10-7	(1.257±0.044)·10-6	228.51±8.09	(3.479±0.123)·10-6	39.10±1.38	7.014·10-7	1.077±0.056	0.279±0.036	CH3CO(OONO2) -> CH3CO(OO) + NO2
J(48012)	47	(2.963±0.107)·10-7	(8.350±0.300)·10-7	237.08±8.53	(2.015±0.072)·10-6	40.28±1.45	4.874·10-7	1.061±0.057	0.285±0.037	CH3CO(OONO2) -> CH3CO(O) + NO3
J(48021)	48	(2.179±0.078)·10-6	(1.106±0.039)·10-5	23.10±0.82	(1.423±0.051)·10-6	233.08±8.31	2.496·10-6	0.637±0.062	0.284±0.037	CH3CH2CO(OONO2) -> CH3CH2CO(OO) + NO2
J(48022)	49	(2.309±0.079)·10-6	(2.175±0.075)·10-6	220.83±7.60	(1.154±0.040)·10-5	26.67±0.92	2.755·10-6	0.715±0.059	0.269±0.036	CH3CH2CO(OONO2) -> CH3CH2CO(O) + NO3
J(13011)	50	(7.487±0.264)·10-7	(4.051±0.143)·10-8	66.15±2.33	(1.601±0.056)·10-7	596.68±21.02	8.380·10-7	0.457±0.064	0.302±0.037	CH2=CHCHO -> CH2=CH + CHO
J(13012)	51	(3.436±0.121)·10-6	(1.883±0.066)·10-7	67.20±2.37	(7.468±0.263)·10-7	616.51±21.74	3.860·10-6	0.457±0.064	0.302±0.037	CH2=CHCHO -> CH2=CH2 + CO
J(13013)	53	(8.314±0.293)·10-7	(1.822±0.064)·10-7	638.28±22.48	(4.713±0.166)·10-8	70.62±2.49	9.370·10-7	0.457±0.064	0.302±0.037	CH2=CHCHO -> CH2=CHCO + H
J(13051)	54	(1.213±0.047)·10-6	(7.252±0.279)·10-7	512.70±19.75	(2.723±0.105)·10-7	65.00±2.50	1.581·10-6	0.602±0.066	0.321±0.040	CH2=C(CH3)CHO -> CH2=CCH3 + CHO
J(13052)	55	(5.613±0.215)·10-6	(3.324±0.128)·10-6	502.02±19.28	(1.253±0.048)·10-6	63.21±2.43	7.273·10-6	0.603±0.066	0.321±0.040	CH2=C(CH3)CHO -> CH3CH=CH2 + CO
J(13053)	57	(1.371±0.053)·10-6	(2.992±0.115)·10-7	62.09±2.38	(8.043±0.308)·10-7	490.04±18.81	1.766·10-6	0.603±0.066	0.321±0.040	CH2=C(CH3)CHO -> CH2=C(CH3)CO + H
J(23011)	59	(5.597±0.210)·10-6	(5.450±0.205)·10-6	376.78±14.17	(4.052±0.152)·10-6	53.69±2.02	7.756·10-6	0.717±0.063	0.310±0.039	CH3COCH=CH2 -> CH3 + C2H3CO
J(15011)	62	(8.445±0.355)·10-6	(6.630±0.278)·10-5	45.26±1.91	(4.131±0.173)·10-5	247.44±10.45	1.851·10-5	1.176±0.062	0.390±0.043	HOCH2CHO -> CH2OH + HCO
J(21011)	65	(5.308±0.278)·10-7	(1.699±0.089)·10-5	44.79±2.35	(9.500±0.497)·10-6	187.09±9.80	2.001·10-6	1.596±0.070	0.578±0.053	CH3COCH3 -> CH3CO + CH3
J(21012)	66	(2.882±0.132)·10-7	(3.078±0.141)·10-6	45.97±2.11	(2.033±0.093)·10-6	242.23±11.10	7.690·10-7	1.224±0.065	0.482±0.047	CH3COCH3 -> CO + 2 CH3
J(21021)	67	(3.677±0.156)·10-6	(2.598±0.110)·10-5	45.98±1.97	(1.755±0.075)·10-5	255.26±10.91	8.144·10-6	1.147±0.063	0.404±0.043	CH3COCH2CH3 -> CH3CO + CH2CH3
J(25011)	68	(2.715±0.094)·10-6	(1.052±0.036)·10-5	212.87±7.43	(2.955±0.102)·10-5	39.77±1.39	4.752·10-6	1.189±0.054	0.277±0.036	CH2(OH)COCH3 -> CH3CO + CH2(OH)
J(31011)	70	(1.753±0.048)·10-4	(3.265±0.090)·10-5	57.76±1.75	(4.933±0.135)·10-5	418.07±12.59	1.967·10-4	0.440±0.052	0.258±0.029	CHOCHO -> 2 HO2 + 2 CO
J(31012)	72	(2.507±0.097)·10-5	(3.452±0.133)·10-5	53.85±2.09	(4.182±0.161)·10-5	346.40±13.46	4.035·10-5	0.849±0.063	0.320±0.040	CHOCHO -> CH2O + CO
J(31013)	73	(1.973±0.054)·10-4	(8.781±0.239)·10-5	380.07±11.34	(6.509±0.177)·10-5	54.68±1.63	2.324·10-4	0.524±0.051	0.248±0.029	Ald (mult)
J(88011)	74	(4.787±0.098)·10-3	(6.271±0.125)·10-5	60.40±1.57	(1.120±0.022)·10-4	481.63±12.15	4.841·10-3	0.172±0.042	0.243±0.022	Ald (poly)
J(31021)	75	(1.906±0.043)·10-4	(5.849±0.132)·10-5	311.47±7.77	(6.390±0.144)·10-5	49.97±1.25	2.097·10-4	0.405±0.044	0.233±0.024	CH3COCHO -> CH3CO + HCO
J(31031)	76	(2.881±0.067)·10-3	(4.932±0.108)·10-5	41.79±1.12	(2.978±0.065)·10-5	304.69±7.91	2.890·10-3	0.182±0.046	0.254±0.024	CH3COCOCH3 -> Products
J(66011)	78	(8.445±0.322)·10-7	(1.912±0.073)·10-6	272.04±10.38	(3.259±0.124)·10-6	43.27±1.65	1.374·10-6	0.958±0.060	0.319±0.039	CH3CO(OOH) -> Products
J(25071)	79	(5.287±0.186)·10-4	(9.879±0.349)·10-6	90.88±3.31	(7.599±0.268)·10-5	891.90±32.53	5.802·10-4	0.415±0.065	0.305±0.037	CH3COCOOH -> CH3CHO + CO2
J(11041)	134	(1.343±0.054)·10-5	(2.685±0.109)·10-5	342.80±13.98	(2.267±0.092)·10-5	53.07±2.16	2.313·10-5	0.872±0.064	0.356±0.042	n-C3H7CHO -> n-C3H7 + CHO
J(11042)	135	(6.382±0.258)·10-6	(1.268±0.051)·10-5	338.82±13.81	(1.078±0.044)·10-5	52.30±2.13	1.091·10-5	0.872±0.064	0.356±0.042	n-C3H7CHO -> C2H4 + CH2CHOH
J(15031)	136	(1.088±0.045)·10-5	(4.597±0.190)·10-5	48.00±2.00	(3.813±0.158)·10-5	282.20±11.77	2.194·10-5	1.040±0.063	0.387±0.043	ALD4OH -> NI products
J(15032)	137	(5.120±0.213)·10-6	(2.181±0.091)·10-5	48.03±2.01	(1.797±0.075)·10-5	282.45±11.81	1.034·10-5	1.039±0.063	0.387±0.043	ALD4OH -> NII products
J(82031)	138	(6.382±0.258)·10-5	(1.268±0.051)·10-4	338.82±14.69	(1.078±0.044)·10-4	52.30±2.26	1.091·10-4	0.872±0.064	0.356±0.042	C4nALDpoly
J(83021)	139	(2.133±0.089)·10-5	(7.485±0.312)·10-5	282.56±11.85	(9.045±0.377)·10-5	48.07±2.02	4.308·10-5	1.038±0.063	0.388±0.043	C4nALDOHpoly
J(12011)	140	(5.269±0.222)·10-5	(1.346±0.057)·10-4	350.47±15.74	(1.006±0.042)·10-4	55.59±2.49	1.025·10-4	0.885±0.065	0.411±0.043	i-C3H7CHO -> i-C3H7 + CHO
J(11051)	141	(2.074±0.084)·10-5	(4.252±0.173)·10-5	340.33±13.94	(3.626±0.147)·10-5	52.60±2.15	3.599·10-5	0.876±0.064	0.360±0.042	n-C4H9CHO -> C4H9 + CHO
J(15041)	144	(5.079±0.213)·10-6	(2.294±0.096)·10-5	47.85±2.02	(1.894±0.080)·10-5	279.74±11.83	1.051·10-5	1.049±0.063	0.399±0.043	C5nALDOH -> NI products
J(82041)	147	(6.265±0.254)·10-5	(1.089±0.044)·10-4	51.77±2.23	(1.281±0.052)·10-4	336.17±14.53	1.080·10-4	0.877±0.064	0.360±0.042	C5nALDpoly
J(83031)	148	(2.027±0.085)·10-5	(9.173±0.384)·10-5	47.91±2.02	(7.563±0.317)·10-5	280.17±11.81	4.202·10-5	1.051±0.063	0.398±0.043	C5nALDOHpoly
J(12021)	149	(9.302±0.395)·10-6	(3.092±0.131)·10-5	308.96±13.23	(2.295±0.098)·10-5	56.17±2.40	1.931·10-5	1.024±0.065	0.378±0.044	i-C4H9CHO -> C4H9 + CHO
J(12022)	150	(9.790±0.396)·10-6	(1.792±0.072)·10-5	354.06±14.41	(1.399±0.057)·10-5	54.02±2.20	1.648·10-5	0.850±0.064	0.353±0.042	i-C4H9CHO -> CH3CH=CH2 + CH2=CHOH
J(12031)	152	(2.845±0.112)·10-5	(4.818±0.190)·10-5	344.36±13.65	(3.917±0.154)·10-5	52.83±2.09	4.594·10-5	0.845±0.063	0.333±0.041	sec-C4H9CHO -> C4H9 + CHO
J(12032)	153	(1.102±0.043)·10-5	(1.520±0.060)·10-5	53.21±2.11	(1.864±0.073)·10-5	345.63±13.71	1.781·10-5	0.846±0.064	0.333±0.041	sec-C4H9CHO -> CH3CH=CHOH + CH2=CH2
J(12041)	154	(1.467±0.059)·10-5	(4.107±0.164)·10-5	292.64±11.76	(4.108±0.164)·10-5	51.47±2.07	2.714·10-5	1.001±0.062	0.351±0.041	t-C4H9CHO -> C4H9 + CHO
J(12061)	155	(4.771±0.193)·10-5	(7.669±0.309)·10-5	52.54±2.26	(9.419±0.380)·10-5	339.94±14.69	8.145·10-5	0.874±0.064	0.350±0.042	tALD -> products
J(12071)	156	(8.217±0.333)·10-6	(1.499±0.061)·10-5	347.78±14.17	(1.158±0.047)·10-5	52.93±2.16	1.371·10-5	0.848±0.065	0.353±0.042	neoC5H11CHO -> neoC5H11 + CHO
J(11061)	159	(2.571±0.104)·10-5	(5.017±0.203)·10-5	341.12±13.90	(4.208±0.170)·10-5	52.85±2.15	4.375·10-5	0.868±0.064	0.355±0.042	n-C5H11CHO -> C5H11 + CHO
J(15051)	162	(5.640±0.235)·10-6	(1.961±0.082)·10-5	285.20±11.94	(2.347±0.098)·10-5	48.11±2.01	1.140·10-5	1.028±0.063	0.395±0.043	C6nALDOH -> NI products
J(82051)	165	(6.708±0.271)·10-5	(1.097±0.044)·10-4	52.56±2.26	(1.308±0.053)·10-4	339.92±14.66	1.139·10-4	0.868±0.064	0.355±0.042	C6nALDpoly
J(83041)	166	(2.252±0.094)·10-5	(9.380±0.392)·10-5	48.35±2.03	(7.838±0.327)·10-5	286.21±12.04	4.566·10-5	1.026±0.063	0.396±0.043	C6nALDOHpoly
J(11071)	167	(1.802±0.077)·10-5	(3.726±0.158)·10-5	52.45±2.24	(4.635±0.197)·10-5	347.50±14.86	3.500·10-5	0.880±0.065	0.417±0.044	n-C6H13CHO -> C6H13 + CHO
J(15061)	170	(3.530±0.161)·10-6	(3.015±0.137)·10-5	48.24±2.21	(2.657±0.121)·10-5	267.34±12.25	1.073·10-5	1.070±0.064	0.612±0.046	C7nALDOH -> NI products
J(82061)	173	(5.846±0.248)·10-5	(1.507±0.064)·10-4	348.69±15.76	(1.214±0.051)·10-4	52.54±2.37	1.138·10-4	0.880±0.065	0.417±0.044	C7nALDpoly
J(83051)	174	(1.412±0.064)·10-5	(1.203±0.055)·10-4	48.39±2.21	(1.061±0.048)·10-4	267.46±12.22	4.287·10-5	1.070±0.064	0.612±0.046	C7nALDOHpoly
J(16021)	175	(1.196±0.048)·10-4	(1.138±0.046)·10-4	60.64±2.62	(1.829±0.073)·10-4	390.46±16.88	1.946·10-4	0.798±0.065	0.348±0.042	Glycidaldehyde -> oxyranyl radical + CHO
J(13021)	177	(7.109±0.253)·10-6	(2.032±0.072)·10-6	572.67±20.42	(5.963±0.212)·10-7	65.94±2.35	8.215·10-6	0.491±0.064	0.302±0.037	CH3CH=CHCHO -> CH3CH=CH + CHO
J(13022)	178	(3.271±0.116)·10-5	(2.741±0.098)·10-6	67.93±2.43	(9.352±0.333)·10-6	578.02±20.68	3.783·10-5	0.492±0.064	0.302±0.037	CH3CH=CHCHO -> CH3CH=CH2 + CO
J(13023)	179	(7.915±0.281)·10-6	(6.786±0.241)·10-7	68.21±2.43	(2.285±0.081)·10-6	590.90±21.02	9.183·10-6	0.492±0.064	0.302±0.037	CH3CH=CHCHO -> CH3CH=CHCO + H
J(13031)	180	(6.721±0.247)·10-6	(5.864±0.216)·10-7	71.64±2.63	(2.112±0.078)·10-6	600.96±22.10	7.905·10-6	0.505±0.065	0.309±0.039	2-hexenal -> 1-pentenyl radical + CHO
J(13032)	181	(3.085±0.113)·10-5	(9.787±0.359)·10-6	613.89±22.65	(2.703±0.099)·10-6	73.17±2.70	3.641·10-5	0.506±0.065	0.308±0.039	2-hexenal -> 1-pentene + CO
J(13033)	182	(7.486±0.275)·10-6	(6.685±0.245)·10-7	73.43±2.70	(2.373±0.087)·10-6	616.53±22.64	8.837·10-6	0.506±0.065	0.309±0.039	2-hexenal -> C3H7CH=CHCO + H
J(12051)	183	(4.616±0.186)·10-5	(7.422±0.299)·10-5	372.96±15.16	(4.989±0.201)·10-5	55.85±2.27	7.529·10-5	0.810±0.065	0.351±0.042	C4H9CH(C2H5)CHO -> C7H15 + CHO
J(15111)	185	(1.715±0.071)·10-5	(4.865±0.202)·10-5	306.94±12.80	(4.839±0.200)·10-5	50.61±2.11	3.275·10-5	0.970±0.064	0.377±0.043	intAldOH -> R + CHO
J(13071)	187	(5.063±0.189)·10-6	(8.529±0.319)·10-7	64.88±2.42	(2.296±0.086)·10-6	527.92±19.73	6.250·10-6	0.560±0.065	0.312±0.039	CH3CH=C(CH3)CHO -> CH3CH=CCH3 + CHO
J(13072)	188	(2.353±0.088)·10-5	(1.053±0.039)·10-5	502.19±18.90	(3.824±0.143)·10-6	61.23±2.30	2.879·10-5	0.560±0.065	0.312±0.039	CH3CH=C(CH3)CHO -> CH3CH=CHCH3 + CO
J(13073)	189	(5.696±0.213)·10-6	(2.556±0.096)·10-6	511.70±19.15	(9.383±0.351)·10-7	63.02±2.36	6.989·10-6	0.560±0.065	0.312±0.039	CH3CH=C(CH3)CHO -> CH3CH=C(CH3)CO + H
J(82131)	193	(5.216±0.195)·10-4	(2.352±0.088)·10-4	514.84±20.82	(8.662±0.324)·10-5	62.74±2.51	6.411·10-4	0.560±0.065	0.312±0.039	genaMeuAld(poly)
J(83131)	194	(3.387±0.130)·10-4	(2.293±0.088)·10-4	454.82±18.60	(1.092±0.042)·10-4	59.17±2.40	4.452·10-4	0.632±0.065	0.319±0.040	genaMeuAldOH(poly)
J(13061)	195	(1.362±0.047)·10-5	(3.039±0.106)·10-6	861.99±30.03	(8.092±0.282)·10-7	91.49±3.19	1.566·10-5	0.444±0.063	0.300±0.037	CH3C(CH3)=CHCHO -> (CH3)2C=CH + CHO
J(13062)	196	(6.480±0.225)·10-5	(1.272±0.044)·10-5	627.94±21.94	(3.173±0.110)·10-6	68.50±2.39	7.210·10-5	0.444±0.063	0.300±0.037	CH3C(CH3)=CHCHO -> (CH3)2C=CH2 + CO
J(13063)	197	(1.576±0.055)·10-5	(7.752±0.269)·10-7	69.27±2.41	(3.059±0.106)·10-6	619.60±21.54	1.750·10-5	0.445±0.063	0.300±0.037	CH3C(CH3)=CHCHO -> (CH3)2C=CHCO + H
J(82121)	201	(1.433±0.050)·10-3	(7.389±0.257)·10-5	74.74±3.40	(2.891±0.100)·10-4	674.57±30.44	1.606·10-3	0.444±0.063	0.300±0.037	genbMeuAld(poly)
J(83121)	202	(1.126±0.041)·10-3	(1.085±0.039)·10-4	72.00±4.60	(3.346±0.120)·10-4	602.04±37.33	1.314·10-3	0.496±0.064	0.304±0.038	genbMeuAldOH(poly)
J(13041)	203	(1.620±0.054)·10-5	(2.618±0.087)·10-6	532.71±17.82	(1.263±0.042)·10-6	57.52±1.92	1.756·10-5	0.423±0.061	0.293±0.035	hexadienal -> 1-pentenyl radical + CHO
J(13042)	204	(7.438±0.248)·10-5	(5.738±0.191)·10-6	58.42±1.96	(1.225±0.041)·10-5	549.99±18.47	8.088·10-5	0.423±0.061	0.293±0.035	hexadienal -> 1,3-pentadiene + CO
J(13043)	205	(1.803±0.060)·10-5	(1.383±0.046)·10-6	58.89±1.97	(2.999±0.100)·10-6	561.53±18.78	1.964·10-5	0.423±0.062	0.293±0.035	hexadienal -> CH3CH=CHCH=CHCO + H
J(82211)	209	(1.652±0.056)·10-3	(1.247±0.042)·10-4	58.97±3.11	(2.785±0.093)·10-4	567.48±28.62	1.803·10-3	0.422±0.062	0.294±0.035	genluuALD(poly)
J(83211)	210	(1.332±0.046)·10-3	(1.239±0.043)·10-4	61.56±2.86	(3.160±0.110)·10-4	571.31±26.22	1.504·10-3	0.464±0.063	0.298±0.036	genluuALD(OHpoly)
J(11081)	212	(6.519±0.265)·10-5	(1.077±0.044)·10-4	52.74±2.28	(1.293±0.053)·10-4	342.66±14.87	1.119·10-4	0.868±0.064	0.359±0.042	n-C7H15CHO -> C7H15 + CHO
J(15071)	215	(5.505±0.230)·10-6	(1.962±0.082)·10-5	282.98±11.90	(2.317±0.097)·10-5	48.36±2.03	1.122·10-5	1.041±0.063	0.392±0.043	C8nALDOH -> NI products
J(82071)	218	(6.649±0.270)·10-5	(1.317±0.054)·10-4	340.49±14.73	(1.095±0.045)·10-4	52.24±2.25	1.137·10-4	0.868±0.064	0.359±0.042	nALDpoly(C>7)
J(83061)	219	(2.209±0.092)·10-5	(7.859±0.329)·10-5	281.91±11.87	(9.265±0.387)·10-5	48.24±2.03	4.486·10-5	1.041±0.063	0.392±0.043	nALDOHpoly(C>7)
J(13081)	220	(6.524±0.234)·10-6	(1.896±0.068)·10-6	582.28±20.94	(5.517±0.198)·10-7	66.55±2.39	7.566·10-6	0.494±0.064	0.304±0.038	luALD -> NI products
J(13082)	221	(3.012±0.108)·10-5	(2.525±0.091)·10-6	64.60±2.33	(8.702±0.312)·10-6	571.03±20.63	3.485·10-5	0.494±0.064	0.304±0.038	luALD -> alkene + CO
J(13083)	222	(7.298±0.262)·10-6	(6.172±0.222)·10-7	66.02±2.37	(2.119±0.076)·10-6	579.72±20.86	8.460·10-6	0.494±0.064	0.304±0.038	luALD -> acyl + H
J(82181)	226	(6.672±0.240)·10-4	(5.705±0.205)·10-5	68.72±2.63	(1.953±0.070)·10-4	595.23±22.87	7.760·10-4	0.494±0.064	0.304±0.038	genluALD(poly)
J(83111)	227	(4.867±0.180)·10-4	(2.108±0.078)·10-4	519.94±20.74	(7.992±0.295)·10-5	63.84±2.53	5.946·10-4	0.554±0.065	0.309±0.039	genluALD(OHpoly)
J(21041)	229	(1.612±0.066)·10-5	(5.897±0.243)·10-5	273.26±11.34	(8.140±0.335)·10-5	46.45±1.93	3.255·10-5	1.052±0.062	0.393±0.042	C2H5COC2H5 -> C2H5CO + C2H5
J(21031)	230	(3.469±0.141)·10-6	(1.194±0.049)·10-5	278.87±11.45	(1.521±0.062)·10-5	49.12±2.02	6.885·10-6	1.047±0.062	0.377±0.042	C3H7COCH3 -> CH3CO + C3H7
J(21032)	232	(9.038±0.355)·10-7	(3.574±0.141)·10-6	246.78±9.70	(6.435±0.253)·10-6	44.14±1.74	1.772·10-6	1.130±0.059	0.353±0.040	C3H7COCH3 -> C3H7 + CO + CH3
J(21033)	233	(4.953±0.201)·10-6	(2.532±0.103)·10-5	45.80±1.87	(1.733±0.070)·10-5	268.30±10.97	9.667·10-6	1.057±0.062	0.374±0.042	C3H7COCH3 -> CH3C(OH)=CH2 + CH2=CH2
J(21051)	234	(8.047±0.337)·10-7	(6.612±0.277)·10-6	202.18±8.46	(1.570±0.066)·10-5	41.17±1.72	1.979·10-6	1.426±0.060	0.380±0.043	C4H9COCH3 -> CH3CH=CH2 + CH2=C(OH)CH3
J(21061)	235	(4.313±0.178)·10-6	(2.508±0.104)·10-5	48.29±2.01	(1.855±0.077)·10-5	262.68±10.95	9.225·10-6	1.145±0.062	0.364±0.042	C3H7COC2H5 -> C2H5CO + C3H7
J(21062)	236	(2.700±0.112)·10-6	(1.160±0.048)·10-5	261.94±10.89	(1.563±0.065)·10-5	48.16±2.00	5.760·10-6	1.146±0.062	0.363±0.042	C3H7COC2H5 -> C3H7CO + C2H5
J(21063)	237	(2.406±0.099)·10-6	(1.641±0.068)·10-5	42.91±1.78	(1.036±0.043)·10-5	251.97±10.46	4.994·10-6	1.145±0.062	0.363±0.042	C3H7COC2H5 -> C3H7 + CO + C2H5
J(21064)	238	(3.248±0.135)·10-6	(1.396±0.058)·10-5	259.38±10.84	(1.960±0.081)·10-5	46.78±1.96	6.880·10-6	1.145±0.062	0.364±0.043	C3H7COC2H5 -> C2H5C(OH)=CH2 + CH2=CH2
J(21081)	239	(1.565±0.064)·10-5	(8.521±0.351)·10-5	46.67±1.94	(6.167±0.254)·10-5	266.12±11.04	3.225·10-5	1.093±0.062	0.383±0.042	4-heptanone -> NI products
J(21091)	241	(1.565±0.064)·10-5	(8.521±0.351)·10-5	46.67±1.94	(6.167±0.254)·10-5	266.12±11.04	3.225·10-5	1.093±0.062	0.383±0.042	4-octanone -> NI products
J(22131)	260	(2.997±0.128)·10-5	(1.196±0.051)·10-4	279.85±12.75	(1.356±0.058)·10-4	49.10±2.23	6.432·10-5	1.075±0.064	0.398±0.044	n-C3H7COCH(CH3)2 -> NI products
J(22141)	261	(2.997±0.128)·10-5	(1.196±0.051)·10-4	279.85±12.75	(1.356±0.058)·10-4	49.10±2.23	6.432·10-5	1.075±0.064	0.398±0.044	n-C3H7COCH(CH3)2 -> i-C3H7COCH3 + C2H4
J(22151)	262	(2.032±0.085)·10-5	(9.473±0.397)·10-5	47.58±2.01	(7.561±0.317)·10-5	275.33±11.63	4.159·10-5	1.067±0.063	0.383±0.043	CH3COCH2C(CH3)3 -> NI products
J(22061)	264	(2.032±0.085)·10-5	(9.473±0.397)·10-5	47.58±2.01	(7.561±0.317)·10-5	275.33±11.63	4.159·10-5	1.067±0.063	0.383±0.043	2-Me-4-heptanone -> NI products
J(22071)	267	(2.997±0.128)·10-5	(1.196±0.051)·10-4	279.85±12.75	(1.356±0.058)·10-4	49.10±2.23	6.432·10-5	1.075±0.064	0.398±0.044	3-Me-4-heptanone -> NI products
J(22081)	269	(2.997±0.128)·10-5	(1.196±0.051)·10-4	279.85±12.75	(1.356±0.058)·10-4	49.10±2.23	6.432·10-5	1.075±0.064	0.398±0.044	2,2-Me-3-hexanone -> NI products
J(22091)	271	(2.032±0.085)·10-5	(9.473±0.397)·10-5	47.58±2.01	(7.561±0.317)·10-5	275.33±11.63	4.159·10-5	1.067±0.063	0.383±0.043	DIBK -> NI products
J(22101)	273	(2.997±0.128)·10-5	(1.196±0.051)·10-4	279.85±12.75	(1.356±0.058)·10-4	49.10±2.23	6.432·10-5	1.075±0.064	0.398±0.044	di-sec-butyl ketone -> NI products
J(22161)	274	(2.997±0.128)·10-5	(1.196±0.051)·10-4	279.85±12.75	(1.356±0.058)·10-4	49.10±2.23	6.432·10-5	1.075±0.064	0.398±0.044	di-sec-butyl ketone -> sec-C4H9COCH2CH3 + C2H4
J(22111)	275	(2.997±0.128)·10-5	(1.196±0.051)·10-4	279.85±12.75	(1.356±0.058)·10-4	49.10±2.23	6.432·10-5	1.075±0.064	0.398±0.044	di-t-butyl ketone -> NI products
J(22011)	244	(1.861±0.080)·10-5	(7.049±0.303)·10-5	294.41±12.76	(6.874±0.296)·10-5	51.54±2.23	4.016·10-5	1.042±0.065	0.405±0.044	MIPK -> CH3CO + i-C3H7
J(22012)	245	(3.105±0.133)·10-6	(1.176±0.050)·10-5	293.74±12.70	(1.149±0.049)·10-5	51.27±2.22	6.690·10-6	1.042±0.065	0.405±0.044	MIPK -> i-C3H7CO + CH3
J(22013)	246	(3.168±0.138)·10-7	(7.535±0.328)·10-6	40.08±1.75	(2.958±0.129)·10-6	201.95±8.80	8.408·10-7	1.387±0.061	0.467±0.044	MIPK -> i-C3H7 + CO + CH3
J(22014)	247	(3.278±0.171)·10-7	(1.090±0.057)·10-5	165.51±8.64	(2.699±0.141)·10-5	39.53±2.06	1.647·10-6	1.483±0.067	0.962±0.053	MIPK -> CH2=CHOH + CH3CH=CH2
J(22021)	248	(2.032±0.085)·10-5	(9.473±0.397)·10-5	47.58±2.01	(7.561±0.317)·10-5	275.33±11.63	4.159·10-5	1.067±0.063	0.383±0.043	MIBK -> CH3CO + i-C4H9
J(22041)	252	(6.529±0.273)·10-6	(2.383±0.099)·10-5	277.66±11.67	(2.923±0.122)·10-5	47.84±2.01	1.330·10-5	1.061±0.063	0.381±0.043	4-Me-2-hexanone -> CH3C(OH)=CH2 + 2-butene
J(22042)	253	(5.724±0.242)·10-7	(3.911±0.166)·10-6	45.57±1.93	(2.647±0.112)·10-6	255.01±10.80	1.245·10-6	1.141±0.063	0.397±0.043	4-Me-2-hexanone -> CH3C(OH)=CH2 + 1-butene
J(22031)	254	(1.591±0.066)·10-5	(5.875±0.243)·10-5	271.29±11.30	(7.563±0.313)·10-5	47.27±1.97	3.213·10-5	1.085±0.063	0.365±0.042	5-Me-2-hexanone -> CH3CO + CH2CH2CH(CH3)2
J(22051)	258	(2.997±0.128)·10-5	(1.196±0.051)·10-4	279.85±12.75	(1.356±0.058)·10-4	49.10±2.23	6.432·10-5	1.075±0.064	0.398±0.044	CH3CH(CH3)COCH(CH3)2 -> i-C3H7CO + i-C3H7
J(24011)	276	(2.951±0.108)·10-4	(8.301±0.303)·10-5	59.31±2.33	(1.553±0.057)·10-4	443.93±17.47	3.659·10-4	0.591±0.064	0.302±0.038	c-C3H4O -> C2H4 + CO
J(24012)	277	(1.619±0.057)·10-4	(1.386±0.049)·10-5	87.60±3.16	(6.335±0.222)·10-5	608.74±22.06	1.978·10-4	0.527±0.063	0.298±0.037	c-C3H4O -> further products
J(84011)	278	(4.813±0.172)·10-4	(2.169±0.078)·10-4	471.45±18.33	(9.432±0.338)·10-5	62.27±2.40	5.849·10-4	0.563±0.063	0.299±0.038	genC3cKet
J(24021)	279	(1.668±0.074)·10-5	(7.729±0.341)·10-5	48.86±2.17	(7.481±0.330)·10-5	291.01±12.93	3.921·10-5	1.026±0.065	0.472±0.045	c-C4H6O -> C2H4 + CH2=C=O
J(24022)	281	(5.534±0.243)·10-6	(2.610±0.114)·10-5	282.94±12.49	(2.958±0.130)·10-5	48.11±2.12	1.313·10-5	1.051±0.064	0.471±0.045	c-C4H6O -> c-C3H6 + CO
J(84021)	282	(2.371±0.104)·10-5	(1.173±0.051)·10-4	48.51±2.14	(1.087±0.048)·10-4	287.52±12.68	5.597·10-5	1.038±0.065	0.471±0.045	genC4cKet
J(24031)	283	(6.474±0.296)·10-6	(4.268±0.195)·10-5	249.87±11.50	(6.009±0.275)·10-5	46.75±2.15	1.702·10-5	1.172±0.066	0.497±0.047	c-C5H8O -> 2 C2H4 + CO
J(24032)	284	(4.143±0.189)·10-6	(2.729±0.125)·10-5	249.86±11.48	(3.831±0.175)·10-5	46.86±2.15	1.089·10-5	1.174±0.066	0.496±0.047	c-C5H8O -> c-C4H8 + CO
J(24033)	285	(3.407±0.146)·10-5	(2.343±0.100)·10-5	84.26±3.64	(6.945±0.297)·10-5	482.80±20.89	6.808·10-5	0.785±0.068	0.404±0.044	c-C5H8O -> CH2=CHCH2CH2CHO
J(84031)	286	(5.341±0.225)·10-5	(1.421±0.060)·10-4	330.35±14.87	(1.202±0.051)·10-4	52.99±2.38	1.028·10-4	0.925±0.065	0.393±0.043	genC5cKet
J(24041)	287	(9.841±0.409)·10-6	(2.189±0.091)·10-5	356.46±14.93	(1.501±0.062)·10-5	56.79±2.38	1.807·10-5	0.881±0.065	0.374±0.043	c-C6H10O -> 5-hexenal
J(24042)	289	(5.156±0.236)·10-7	(2.782±0.128)·10-5	38.60±1.77	(9.073±0.416)·10-6	175.57±8.06	1.755·10-6	1.523±0.061	0.636±0.046	c-C6H10O -> 1-pentene + CO
J(84041)	290	(2.998±0.123)·10-5	(6.861±0.281)·10-5	50.90±2.10	(7.230±0.296)·10-5	318.37±13.14	5.413·10-5	0.928±0.064	0.364±0.042	genC6cKet
J(24051)	291	(5.571±0.232)·10-6	(9.468±0.395)·10-6	56.27±2.36	(1.307±0.055)·10-5	346.25±14.55	1.035·10-5	0.900±0.065	0.376±0.043	c-C7H12O -> 6-heptenal
J(24052)	293	(1.391±0.066)·10-6	(3.413±0.163)·10-5	41.83±2.01	(1.599±0.076)·10-5	199.69±9.57	4.170·10-6	1.445±0.066	0.506±0.048	c-C7H12O -> 1-hexene + CO
J(84051)	294	(2.580±0.107)·10-5	(7.099±0.295)·10-5	309.91±12.96	(7.079±0.294)·10-5	50.70±2.12	4.882·10-5	0.958±0.064	0.377±0.043	genC7cKet
J(23021)	295	(4.826±0.182)·10-6	(4.304±0.162)·10-6	52.65±1.99	(5.334±0.201)·10-6	361.74±13.64	6.859·10-6	0.749±0.063	0.311±0.039	CH3CH2COCH=CH2 -> C2H5 + C2H3CO
J(85011)	298	(6.587±0.238)·10-4	(2.185±0.079)·10-4	551.65±21.36	(7.032±0.254)·10-5	65.19±2.50	7.749·10-4	0.512±0.064	0.304±0.038	genuKet(poly)
J(25021)	299	(2.294±0.081)·10-5	(6.781±0.239)·10-5	45.92±1.63	(4.460±0.157)·10-5	261.00±9.26	3.464·10-5	0.955±0.057	0.267±0.036	CH3COC2H4OH -> CH3 + COCH2CH2OH
J(25031)	301	(6.025±0.219)·10-6	(6.451±0.235)·10-5	42.02±1.54	(2.938±0.107)·10-5	213.72±7.83	1.175·10-5	1.309±0.055	0.265±0.037	CH3COCH(OH)CH3 -> CH3CO + CH3CHOH
J(25041)	303	(3.872±0.138)·10-5	(5.589±0.199)·10-5	45.45±1.64	(3.522±0.126)·10-5	293.03±10.53	4.941·10-5	0.724±0.061	0.288±0.037	CH3COC(CH3)2OH -> CH3 + (CH3)2C(OH)CO
J(25081)	304	(2.075±0.089)·10-5	(1.353±0.058)·10-4	46.84±2.03	(9.967±0.430)·10-5	262.53±11.39	4.710·10-5	1.117±0.064	0.430±0.044	CH3COCH2C(CH3)2OH -> CH3COCH2 + CH3C(OH)CH3
J(26011)	310	(3.752±0.140)·10-4	(5.080±0.190)·10-5	64.66±2.53	(1.535±0.057)·10-4	541.51±21.38	4.559·10-4	0.546±0.066	0.312±0.039	CH2=C=O -> CO2 + CO + H2
J(26012)	311	(5.596±0.199)·10-4	(1.014±0.036)·10-4	689.98±25.81	(2.382±0.085)·10-5	69.47±2.59	6.208·10-4	0.440±0.065	0.305±0.038	CH3CH=C=O -> C2H4 + CO
J(86011)	312	(9.422±0.305)·10-4	(9.862±0.319)·10-5	650.11±23.09	(2.276±0.074)·10-5	64.65±2.25	9.999·10-4	0.376±0.061	0.291±0.034	genKete(poly)
J(33011)	313	(5.168±0.164)·10-6	(2.042±0.065)·10-7	72.57±2.30	(7.889±0.249)·10-7	641.20±20.29	5.627·10-6	0.406±0.059	0.283±0.033	CHOCH=CHCHO -> 3H-furan-2-one
J(88111)	314	(4.316±0.137)·10-4	(6.564±0.208)·10-5	622.08±20.86	(1.721±0.055)·10-5	66.30±2.20	4.691·10-4	0.406±0.059	0.283±0.034	uDICARaa(poly)
J(33021)	315	(6.097±0.172)·10-5	(5.691±0.161)·10-6	613.23±17.39	(1.938±0.055)·10-6	69.53±1.97	6.420·10-5	0.348±0.055	0.268±0.030	CH3COCH=CHCHO -> 5Me-3H-2-furanone
J(33022)	316	(2.905±0.082)·10-4	(3.082±0.087)·10-5	464.21±14.07	(1.064±0.030)·10-5	52.68±1.55	3.050·10-4	0.361±0.055	0.267±0.030	CH3COCH=CHCHO -> CH3 + CHOCH=CHCO
J(33023)	317	(4.089±0.116)·10-4	(1.532±0.043)·10-5	71.67±2.13	(4.344±0.123)·10-5	608.61±17.93	4.335·10-4	0.357±0.055	0.267±0.030	CH3COCH=CHCHO -> CH3COCH=CH2 + CO
J(88121)	319	(1.227±0.035)·10-3	(3.635±0.103)·10-5	64.13±2.38	(1.100±0.031)·10-4	530.09±20.73	1.284·10-3	0.348±0.055	0.268±0.030	uDICARak(poly)
J(33041)	320	(2.882±0.087)·10-3	(2.677±0.080)·10-4	429.80±19.48	(9.718±0.290)·10-4	28.24±1.58	3.001·10-3	0.354±0.057	0.279±0.032	CHOCH=CHCH=CHCHO -> diformyl cyclobutene
J(33031)	321	(3.718±0.125)·10-4	(1.099±0.037)·10-4	527.60±18.88	(4.251±0.143)·10-5	67.38±2.41	4.286·10-4	0.491±0.061	0.289±0.035	CH3COCH=CHCOCH3 -> CH3CO + CH=CHCOCH3
J(34011)	322	(9.447±0.387)·10-5	(2.302±0.094)·10-4	51.08±2.24	(2.393±0.098)·10-4	319.14±14.04	1.746·10-4	0.935±0.064	0.372±0.042	pinonaldehyde -> R + CO + HO2
J(34021)	323	(4.443±0.191)·10-5	(2.020±0.087)·10-4	49.11±2.25	(1.822±0.078)·10-4	291.89±13.42	9.952·10-5	1.018±0.064	0.452±0.044	caronaldehyde -> R + CO + HO2
J(41051)	324	(1.921±0.076)·10-6	(8.130±0.320)·10-6	234.74±9.24	(1.642±0.065)·10-5	41.88±1.65	3.755·10-6	1.181±0.060	0.330±0.040	n-C5H11ONO2 -> n-C5H11O + NO2
J(41131)	325	(2.039±0.081)·10-6	(2.254±0.089)·10-5	41.33±1.65	(1.012±0.040)·10-5	225.31±8.96	4.184·10-6	1.234±0.059	0.341±0.040	2-C5H11ONO2 -> 2-C5H11O + NO2
J(41141)	326	(1.929±0.077)·10-6	(1.087±0.044)·10-5	219.04±8.83	(2.514±0.101)·10-5	40.99±1.65	4.133·10-6	1.280±0.059	0.352±0.041	3-C5H11ONO2 -> 3-C5H11O + NO2
J(41151)	327	(1.969±0.079)·10-6	(2.365±0.094)·10-5	41.24±1.66	(1.043±0.042)·10-5	222.32±8.94	4.134·10-6	1.256±0.059	0.347±0.041	C5H11ONO2 -> C5H11O + NO2
J(44011)	328	(6.283±0.259)·10-7	(1.604±0.066)·10-5	38.73±1.60	(5.458±0.225)·10-6	193.10±7.95	1.521·10-6	1.451±0.059	0.378±0.042	c-C5H11ONO2 -> c-C5H11O + NO2
J(42011)	329	(2.017±0.076)·10-6	(1.585±0.060)·10-5	41.96±1.58	(7.456±0.281)·10-6	234.65±8.84	3.698·10-6	1.148±0.058	0.307±0.039	i-C4H9ONO2 -> i-C4H9O + NO2
J(42031)	330	(4.050±0.157)·10-6	(2.768±0.107)·10-5	43.45±1.69	(1.549±0.060)·10-5	241.30±9.40	7.691·10-6	1.152±0.059	0.320±0.040	i-C5H11ONO2 -> i-C5H11O + NO2
J(45021)	331	(3.423±0.155)·10-8	(9.937±0.450)·10-7	148.52±6.73	(4.731±0.214)·10-6	33.88±1.53	1.285·10-7	1.631±0.059	0.794±0.046	C1(OH)NO3 -> C1(OH)O + NO2
J(45031)	332	(5.530±0.250)·10-8	(1.671±0.076)·10-6	147.15±6.67	(7.760±0.351)·10-6	34.31±1.55	2.105·10-7	1.663±0.059	0.787±0.046	R(OH)NO3 -> R(OH)O + NO2
J(45041)	333	(2.831±1.276)·10-9	(2.296±1.035)·10-5	27.55±12.42	(6.246±2.815)·10-6	69.45±31.31	4.335·10-8	4.091±0.512	1.420±0.452	iR(OH)NO3 -> iR(OH)O + NO2
J(45051)	334	(1.806±0.084)·10-7	(4.469±0.208)·10-6	163.62±7.63	(1.601±0.075)·10-5	36.20±1.69	7.079·10-7	1.500±0.061	0.819±0.047	tR(OH)NO3 -> tR(OH)O + NO2
J(48031)	335	(6.062±0.223)·10-7	(1.650±0.061)·10-6	243.15±8.95	(3.828±0.141)·10-6	40.23±1.48	9.980·10-7	1.036±0.058	0.299±0.038	PAN -> RCO(OO) + NO2
J(48032)	336	(3.873±0.143)·10-7	(2.447±0.090)·10-6	40.36±1.49	(1.053±0.039)·10-6	243.84±8.99	6.384·10-7	1.035±0.058	0.300±0.038	PAN -> RCO(O) + NO3
J(51011)	337	(1.205±0.044)·10-5	(2.077±0.076)·10-5	282.15±10.46	(3.313±0.122)·10-5	44.45±1.65	1.807·10-5	0.885±0.060	0.303±0.038	CH3CH(NO3)CH2NO3 -> CH3CH(NO3)CH2O + NO2
J(51021)	339	(1.663±0.063)·10-5	(3.465±0.131)·10-5	45.20±1.72	(2.474±0.094)·10-5	305.14±11.62	2.450·10-5	0.831±0.062	0.316±0.039	C2H5CH(NO3)CH2NO3 -> C2H5CH(NO3)CH2O + NO2
J(51031)	341	(1.196±0.044)·10-5	(3.658±0.135)·10-5	43.58±1.62	(2.206±0.082)·10-5	275.02±10.24	1.815·10-5	0.905±0.060	0.303±0.038	CH3CH(NO3)CH(NO3)CH3 -> RO. + NO2
J(53011)	342	(8.129±0.313)·10-6	(2.725±0.105)·10-5	45.46±1.76	(1.977±0.076)·10-5	283.63±10.98	1.390·10-5	0.978±0.061	0.318±0.040	CH2(NO3)CH=CHCH2NO3 -> RO. + NO2
J(53021)	343	(7.145±0.264)·10-6	(2.492±0.092)·10-5	43.71±1.63	(1.479±0.055)·10-5	271.87±10.11	1.124·10-5	0.942±0.059	0.302±0.038	CH2=CHCH(NO3)CH2NO3 -> CH2=CHCH(NO3)CH2O + NO2
J(62011)	348	(2.095±0.936)·10-9	(1.166±0.521)·10-5	29.99±13.41	(4.842±2.164)·10-6	73.16±32.71	4.268·10-8	3.915±0.508	1.489±0.448	(CH3)3COOH -> (CH3)3CO + OH
J(81021)	349	(1.839±0.073)·10-5	(6.129±0.244)·10-5	263.30±10.54	(9.168±0.364)·10-5	45.49±1.82	3.465·10-5	1.075±0.061	0.341±0.041	C2H5COCH2NO3 -> C2H5COCH2O + NO2
J(81031)	350	(3.946±0.155)·10-5	(9.607±0.378)·10-5	290.51±12.22	(1.179±0.046)·10-4	47.82±2.02	6.834·10-5	0.969±0.062	0.334±0.041	CH3COCH(NO3)CH3 -> CH3COCH(O.)CH3 + NO2
J(81111)	352	(4.480±0.166)·10-5	(6.160±0.228)·10-5	295.53±10.99	(1.015±0.038)·10-4	43.87±1.63	6.368·10-5	0.820±0.061	0.301±0.038	CH3COCH2CH2CH(OOH)CH3 -> RO. + OH
J(81121)	353	(1.600±0.061)·10-4	(2.245±0.086)·10-4	45.01±1.85	(1.681±0.064)·10-4	336.65±13.66	2.195·10-4	0.736±0.064	0.319±0.040	oxohexyl-hydroperoxide -> RO. + OH
J(71011)	354	(2.572±4.955)·10-1	(3.438±1.779)·10-2	585.87±699.61	(9.798±2.483)·10-3	63.88±62.83	2.762·10-1	0.392±0.059	0.283±0.033	CH2OO -> HCHO + O(3P)
J(71021)	355	(2.012±3.732)·10-1	(1.504±0.531)·10-2	59.86±76.47	(4.202±4.302)·10-2	508.96±821.41	2.224·10-1	0.445±0.060	0.283±0.034	CH3CHOO -> CH3CHO + O(3P)
J(71022)	356	(1.457±2.100)·10-1	(1.530±0.596)·10-2	63.13±99.26	(4.335±4.625)·10-2	529.76±958.63	1.682·10-1	0.498±0.063	0.296±0.037	synCH3CHOO -> CH3CHO + O(3P)
J(71023)	357	(3.998±9.076)·10-1	(3.657±0.327)·10-3	70.39±25.47	(1.989±0.457)·10-2	626.60±347.01	4.112·10-1	0.302±0.054	0.269±0.029	antiCH3CHOO -> CH3CHO + O(3P)
J(71031)	358	(2.593±2.489)·10-1	(1.257±1.054)·10-1	647.50±1403.53	(2.801±0.924)·10-2	74.74±137.57	3.328·10-1	0.555±0.067	0.323±0.040	C2H5CHOO -> C2H5CHO + O(3P)
J(72011)	359	(2.435±2.614)·10-1	(1.113±1.141)·10-1	609.77±1330.30	(2.606±0.791)·10-2	76.17±137.30	3.065·10-1	0.551±0.066	0.315±0.039	(CH3)2COO -> CH3COCH3 + O(3P)
J(46011)	360	(1.077±0.041)·10-5	(2.394±0.090)·10-5	46.00±1.75	(1.771±0.067)·10-5	298.33±11.32	1.626·10-5	0.864±0.061	0.309±0.039	CH3NO2 -> CH3 + NO2
J(46012)	361	(3.033±0.113)·10-5	(3.492±0.130)·10-5	47.96±1.80	(3.166±0.118)·10-5	336.01±12.61	4.153·10-5	0.743±0.063	0.305±0.039	RNO2 -> alkene + HONO
J(46021)	362	(3.607±0.157)·10-6	(2.532±0.110)·10-5	254.09±11.13	(3.958±0.172)·10-5	44.62±1.95	1.001·10-5	1.088±0.062	0.585±0.044	C2H5NO2 -> C2H5 + NO2
J(46022)	363	(6.756±0.298)·10-6	(5.797±0.256)·10-5	46.01±2.04	(4.323±0.190)·10-5	272.78±12.10	1.877·10-5	1.028±0.063	0.591±0.045	C2H5NO2 -> C2H4 + HONO
J(21071)	364	(1.565±0.064)·10-5	(8.521±0.351)·10-5	46.67±1.94	(6.167±0.254)·10-5	266.12±11.04	3.225·10-5	1.093±0.062	0.383±0.042	lKET5 -> products

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