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Organic hydroperoxides and PAAs
The only protocol rule for alkyl hydroperoxides is the distinction by branching. The photolysis of peroxyacids (PAAs) is estimated with peracetic acid (CH3CO(OOH)) as surrogate. Details can be found in the table and schematic below.
Further protocol rules for organic compounds with a hydroperoxide group exist for compounds with other polyfunctional chromophores. For rules of compounds with different chromophore types, see the main page.
Hydroperoxide compound class | j value |
---|---|
Linear alkyl hydroperoxides | J(6001) |
Branched alkyl hydroperoxides | J(6002) |
Peroxy acids (PAAs) | J(6004) |
Changes in the MCM/GECKO-A version compared to the original TUV
Adding reactions to TUV
Linking TUV to box models
Mono-aldehydes
Mono-ketones
Ketenes
Polycarbonyls
Organic nitrogen compounds
Organic hydroperoxides and PAAs
Criegee intermediates
Polyfunctional chromophores
MCM/GECKO-A reaction numbers
MCMv3.x reaction numbers
MCM/GECKO-A parameterisations