Peritheos 0.10.0

This release expands the scientific catalog to 612 executable EOS records
across 223 materials, adding 39 records and 14 materials since 0.9.0. The
complete document library contains 614 source records in 225 material cards.
New source observations, independent refits, and pressure-scale comparisons
make the evidence and limitations of the published parameterizations explicit.
Source validation does not imply complete independent refit parity.

Added

• Campbell et al. (2009) Fe–FeO and Ni–NiO source audit, with all 101 Ni–NiO
  observations, official buffer checkpoints and conditional refit diagnostics.
  The published fcc-Fe and FeO parameters are retained as deferred source
  records, excluded from the executable catalog because substantial combined
  refit discrepancies remain unresolved. The Ni and NiO records remain
  executable. No diagnostic refit is promoted to an executable EOS.
  Reconstructs 65 Seagle hcp and 14 conditional fcc pressures, checked against
  54 published pressure benchmarks, with two rows lacking iron volumes.
  Adds pressure/volume protocol comparisons, source and temperature influence
  checks, q profiles and five thermal-correction sensitivities. Removes the
  executable Campbell fcc-Fe calibration link from the Fischer FeO record.
  The catalog exposes 612 EOS records across 223 executable materials; the
  document library retains 614 source records in 225 material documents.
  Catalog loading excludes deferred records while retaining accepted records
  from the same material.

• Eight Sakai et al. (2011) experimental NaCl-B2 BM3/Vinet records on four
  distinct Pt scales, with all 27 new and 29 upstream Sata observations,
  marker readings, uncertainty provenance, staged refits and source benchmarks.
  Exact 300 K Matsui (2009) and Fei (2007) Pt reference-isotherm records enable
  public-API recalibration. A reproducible comparison quantifies conversion
  differences from the published NaCl fits and separates calibrant extrapolation.

• Litasov et al. (2013) natural Fe0.95Mn0.05CO3 siderite 300 K BM3,
  diffraction structure, all 111 paired sample/Au observations, and independent
  RT, joint thermal, staged, and axial diagnostics. An opt-in joint thermal
  refit includes the complete fitted coefficients and covariance; both conflicting
  published thermal versions remain non-executable source evidence.

• Seven Fischer et al. (2014) published experimental Fe–Si EOS records and two
  independently validated Peritheos B2 refits on five materials,
  with all 391 supplementary P–V–T rows, 185 earlier Fe–16Si observations,
  independent BM3/Vinet/MGD checks and explicit crystal occupancies. Both B2
  FeSi published thermal fits remain withheld because their reconstruction
  misses the data; the factor-of-two diagnosis remains a hypothesis. The B2
  refits preserve full covariance, sensitivity results and measured-range limits.

• Nisr et al. (2017) experimental hydrous stishovite and hydrous CaCl2-type
  silica as separate composition/phase cards, plus the source-owned dry
  reference fit. Includes the corrected article audit, all 43 official
  supplement rows, corrected ambient observations, documented diffraction
  peak-position fallbacks, and independent refits within published errors.

• Chidester et al. (2018) experimental thermal EOSs for thorianite and
  cotunnite-type ThO2, with all 100 official observation rows, source exclusions,
  diffraction structures, independent reproduction and weighting diagnostics.

• Lv et al. (2016) synthetic qandilite Mg2.00(1)Ti1.00(1)O4, with separate
  published BM2 and BM3 records, all 18 primary P–V rows and uncertainties,
  independently sourced diffraction structure, and reproducible refit checks.

• Litasov et al. (2007) nominally pure-Mg LT superhydrous phase B: seven
  experimental EOS alternatives, all 69 P–V–T rows with Au observations, 30
  diffraction peaks, corrected independent Pnn2 structure, and reproducible
  refits. Equation-printing issues and incomplete alternatives are documented.

• Incomplete-dataset and author-request tracker, linked to the investigation
  ledger, with a reviewed request for the original Crichton vanadium data.

• Crichton et al. (2016) experimental bcc vanadium thermal BM3, separately
  sourced diffraction structure, digitized observations and independent curve
  reproduction. The original 62-row refit is unavailable; a nominal-temperature
  proxy is documented, and two incomplete fixed-K′ alternatives are withheld.

• Zha et al. (2004) rhenium Equation (6) thermal EOS, all eight paired Au/Re
  observations, derived isotherm tables, and an independent staged refit. The
  continuous Table III branch is distinguished from the authors' preferred
  fixed-volume isotherms.

• Primary-source investigation of Xian et al. (2022), with literal thermal
  polynomial diagnostics. Its Re/Au models remain outside the executable
  catalog because source-specific inputs and printed-equation issues remain
  unresolved.

Fixed

• CI and release wheel smoke checks now verify source-only and executable
  records separately, preserving deferred records in the packaged documents
  without attempting to execute them.
• Bounded platform-dependent numerical drift in the Redfern, Ricolleau,
  Crichton, and Litasov audit checks, with tight fitted-pressure and objective
  checks retained. Siderite equation mapping is checked at identical stored
  coefficients separately from the independent refit's numerical tolerance.
• Stable source ordering for tied pressures in the Fischer FeSi holdout
  diagnostics, preserving the original row selections across NumPy versions.
• Preserved crystallographic archive bytes during Windows checkouts and read
  the investigation ledger as UTF-8 in its regression test.

Compatibility

• Public Python and Rust model APIs and .eosmat format 3 are unchanged.
• Executable catalog loading now excludes deferred records while retaining
  validated records from the same material. Deferred Campbell fcc-Fe and FeO
  parameters remain available through the document API; they are not exposed
  as executable catalog entries. Published coefficients and independent
  Peritheos refits retain distinct identifiers and provenance.