Microsoft launched fullscreen experience, which basically allows windows to be navigated entirely via controller. This is a must for a setup that cannot/shouldn't use touchscreen controls (I.E simulating a console like experience on PC).
Unfortantely, duo inputs do not function in fullscreen experience. The only working input currently is the xbox button, which allows quick navigation, but no input renders that function useless. Isolate Steam toggle has no effect. Duo also disables FSE inputs for all connected instances, including host.