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4 changes: 2 additions & 2 deletions docs/learn/care/gem-care-durability.yaml
Original file line number Diff line number Diff line change
Expand Up @@ -53,7 +53,7 @@ sections:

- title: Hardness Considerations
content: |
The Mohs scale is ordinal, not linearthe jump from 9 to 10 is enormous. Household
The Mohs scale is ordinal, not linearthe jump from 9 to 10 is enormous. Household
dust contains quartz particles (H 7), so gems below 7 will gradually accumulate
scratches during normal wear.
table:
Expand All @@ -72,7 +72,7 @@ sections:

- title: Toughness and Cleavage
content: |
Cleavagethe tendency to break along crystallographic planessignificantly affects
Cleavagethe tendency to break along crystallographic planessignificantly affects
toughness. Even hard gems can be brittle.
subsections:
- title: High-Risk Cleavage Gems
Expand Down
28 changes: 14 additions & 14 deletions docs/learn/equipment/advanced-lab-instruments.yaml
Original file line number Diff line number Diff line change
@@ -1,5 +1,5 @@
title: Advanced Laboratory Instruments
description: Diploma-level awareness of FTIR, UV-Vis-NIR, Raman, EDXRF, LA-ICP-MS, and photoluminescence spectroscopy what each detects and its key gemmological applications.
description: Diploma-level awareness of FTIR, UV-Vis-NIR, Raman, EDXRF, LA-ICP-MS, and photoluminescence spectroscopy what each detects and its key gemmological applications.
order: 12
category: equipment
difficulty: advanced
Expand Down Expand Up @@ -33,7 +33,7 @@ sections:
- title: FTIR Spectroscopy
content: |
**Fourier Transform Infrared (FTIR) spectroscopy** irradiates the sample with a broadband
infrared beam mid-IR (~4000–400 cm⁻¹) or near-IR (~10000–4000 cm⁻¹). Chemical bonds
infrared beam mid-IR (~4000–400 cm⁻¹) or near-IR (~10000–4000 cm⁻¹). Chemical bonds
absorb IR radiation at characteristic frequencies; the resulting absorption pattern identifies
molecular functional groups and crystal lattice vibrations.

Expand All @@ -54,11 +54,11 @@ sections:
untreated (Type A) jadeite. Tan et al. (2013) confirmed FTIR distinguishes treated from
untreated jade: COSMOS journal (DOI: 10.1142/s0219607713500031) [VERIFIED].

- **Diamond type classification:** FTIR distinguishes Type Ia (nitrogen in aggregates
- **Diamond type classification:** FTIR distinguishes Type Ia (nitrogen in aggregates
A and B centres), Type Ib (isolated nitrogen), Type IIa (nitrogen-free), and Type IIb
(boron-bearing, electrically conductive) by nitrogen absorption features in the mid-IR
one-phonon region (~1000–1300 cm⁻¹). Type IIa diamonds lack nitrogen absorptions and
are more likely candidates for HPHT treatment or CVD synthesis triggering further
are more likely candidates for HPHT treatment or CVD synthesis triggering further
investigation.

- **Heat treatment indicator in sapphire:** Delaunay (2024) showed that the 3232 cm⁻¹
Expand All @@ -85,11 +85,11 @@ sections:
- title: Key Gemmological Applications
content: |
- **Beryllium-diffused sapphire detection:** Emmett et al. (2003) described UV-Vis-NIR
signatures associated with beryllium diffusion the process causes orange colouration
signatures associated with beryllium diffusion the process causes orange colouration
in corundum through Fe³⁺–O²⁻ charge transfer bands in the UV, producing a reduction
in blue absorption and strengthening of an absorption feature near 390 nm: Gems &
Gemology 39(2), 84–135 (DOI: 10.5741/gems.39.2.84) [VERIFIED]. Be diffusion is
confirmed definitively only by LA-ICP-MS (see below) UV-Vis-NIR provides supporting
confirmed definitively only by LA-ICP-MS (see below) UV-Vis-NIR provides supporting
evidence.

- **Chromophore quantification:** Distinguishes iron-coloured from chromium-coloured
Expand All @@ -114,7 +114,7 @@ sections:
molecular bond vibrations and lattice phonon modes, providing a unique molecular fingerprint.

Raman is **non-destructive** and can be performed through glass or immersion media using a
confocal micro-probe making it ideal for inclusion identification without opening cavities
confocal micro-probe making it ideal for inclusion identification without opening cavities
or damaging the host.
subsections:
- title: Key Gemmological Applications
Expand Down Expand Up @@ -151,25 +151,25 @@ sections:
and **treatment detection**. They are the workhorses of modern origin determination
at major gem laboratories.
subsections:
- title: EDXRF Non-Destructive Elemental Survey
- title: EDXRF Non-Destructive Elemental Survey
content: |
**Energy-Dispersive X-ray Fluorescence (EDXRF):** An X-ray beam causes emission of
characteristic secondary X-rays from elements in the sample, providing non-destructive
elemental analysis down to ppm levels for elements with atomic number ≥ 11 (sodium).

- Non-destructive; no sample preparation required.
- Cannot detect elements below atomic number ~11 in standard configurations.
- **Cannot detect beryllium (atomic number 4)** this is a critical limitation for
- **Cannot detect beryllium (atomic number 4)** this is a critical limitation for
Be-diffusion treatment detection; only LA-ICP-MS can routinely detect Be.
- Schmetzer et al. (2009) used EDXRF for gem corundum origin fingerprinting: Gems &
Gemology 45(4), 264 (DOI: 10.5741/gems.45.4.264) [VERIFIED].

- title: LA-ICP-MS Ultra-Trace Element Fingerprinting
- title: LA-ICP-MS Ultra-Trace Element Fingerprinting
content: |
**Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS):** A laser
micro-beam ablates a tiny spot (10–100 µm); the ablated material is carried into an ICP
plasma and analysed by mass spectrometry, providing trace and ultra-trace element data
to ppb levels. Micro-destructive leaves a tiny ablation pit.
to ppb levels. Micro-destructive leaves a tiny ablation pit.

- **Origin fingerprinting in corundum:** Basaltic-origin sapphires (Australia,
Thailand/Cambodia, Nigeria) have high Fe (>5000 ppm), high Ga/Al ratios, and are
Expand All @@ -188,7 +188,7 @@ sections:
text: |
EDXRF: £15,000–£100,000. LA-ICP-MS: £150,000–£500,000. Origin determination using these
techniques is performed primarily by GIA, Gübelin, SSEF, and the Gem-A Laboratory. Neither
instrument provides geographic origin assignment alone statistical comparison against a
instrument provides geographic origin assignment alone statistical comparison against a
reference database of stones of known provenance is required.

- title: Photoluminescence at 77 K
Expand All @@ -210,7 +210,7 @@ sections:
Related Materials 19(10), 1254–1258 (DOI: 10.1016/j.diamond.2010.06.007) [VERIFIED].

- **CVD synthetic diamond:** Willems et al. (2011) explored luminescent regions in CVD
synthetic diamond using PL CVD diamonds show characteristically different luminescence
synthetic diamond using PL CVD diamonds show characteristically different luminescence
patterns related to their growth sectors: Gems & Gemology 47(3), 202–207
(DOI: 10.5741/gems.47.3.202) [VERIFIED].

Expand All @@ -225,7 +225,7 @@ sections:
Photoluminescence at 77 K requires liquid nitrogen and a purpose-built cryogenic stage,
costing £50,000–£200,000. This technique is not available outside major gem laboratories
(GIA, Gübelin, SSEF, Gem-A Laboratory). Results require expert interpretation and
comparison against reference databases. Not applicable to most coloured stones it is
comparison against reference databases. Not applicable to most coloured stones it is
primarily a diamond tool.

- title: Sources
Expand Down
42 changes: 21 additions & 21 deletions docs/learn/equipment/chelsea-colour-filter.yaml
Original file line number Diff line number Diff line change
@@ -1,5 +1,5 @@
title: Chelsea Colour Filter
description: Using the Chelsea Colour Filter as a chromium discriminator for gem identification including the species reaction table, lighting requirements, and diagnostic limitations.
description: Using the Chelsea Colour Filter as a chromium discriminator for gem identification including the species reaction table, lighting requirements, and diagnostic limitations.
order: 9
category: equipment
difficulty: beginner
Expand Down Expand Up @@ -27,9 +27,9 @@ sections:
content: |
The CCF is a composite filter containing two glass elements:

- **Didymium glass** absorbs the mid-green and yellow-green region (~540–580 nm), removing
- **Didymium glass** absorbs the mid-green and yellow-green region (~540–580 nm), removing
the wavelengths that would otherwise appear as a green wash.
- **Cobalt-blue glass** absorbs red and part of the blue-green region.
- **Cobalt-blue glass** absorbs red and part of the blue-green region.

The combined result leaves two narrow transmission windows:
1. ~570–580 nm (yellow-green)
Expand All @@ -46,7 +46,7 @@ sections:

- title: How to Use the Filter
content: |
Correct procedure is essential the wrong light source gives unreliable results.
Correct procedure is essential the wrong light source gives unreliable results.
subsections:
- title: Lighting Requirements
content: |
Expand All @@ -60,11 +60,11 @@ sections:
- title: Observation Procedure
content: |
1. Hold the filter close to the eye (as close as comfortable).
2. Hold the stone close to but not touching the incandescent light source,
2. Hold the stone close to but not touching the incandescent light source,
or direct a penlight through or against the stone.
3. Observe the colour and record as one of: strong red / weak red / pink / inert /
weak greenish / green.
4. Always cross-reference with RI and spectroscope data the CCF result alone is
4. Always cross-reference with RI and spectroscope data the CCF result alone is
never diagnostic.

- title: Species Reactions
Expand All @@ -73,7 +73,7 @@ sections:
standard incandescent illumination. Anomalous results require immediate investigation with a
second instrument.

Note: **the CCF does not distinguish natural from synthetic** a chromium-dominated
Note: **the CCF does not distinguish natural from synthetic** a chromium-dominated
synthetic will react identically to a natural stone of the same chromophore.
table:
caption: Chelsea Colour Filter Reaction by Species
Expand All @@ -84,48 +84,48 @@ sections:
- Diagnostic Strength
- Notes
rows:
- ["Emerald Colombian / Brazilian (natural)", "Strong red", "Cr³⁺", "High", "High Cr; classic positive reaction"]
- ["Emerald Zambian (natural)", "Weak red to inert", "Cr³⁺ + Fe", "Moderate", "Elevated Fe suppresses red; less reliable positive"]
- ["Emerald flux-grown synthetic (Chatham, Gilson)", "Strong red", "Cr³⁺", "High", "High-purity Cr; often stronger than many naturals"]
- ["Emerald hydrothermal synthetic (Biron, Tairus)", "Strong red", "Cr³⁺", "High", "Same chromophore; indistinguishable from Cr-rich natural"]
- ["Emerald Colombian / Brazilian (natural)", "Strong red", "Cr³⁺", "High", "High Cr; classic positive reaction"]
- ["Emerald Zambian (natural)", "Weak red to inert", "Cr³⁺ + Fe", "Moderate", "Elevated Fe suppresses red; less reliable positive"]
- ["Emerald flux-grown synthetic (Chatham, Gilson)", "Strong red", "Cr³⁺", "High", "High-purity Cr; often stronger than many naturals"]
- ["Emerald hydrothermal synthetic (Biron, Tairus)", "Strong red", "Cr³⁺", "High", "Same chromophore; indistinguishable from Cr-rich natural"]
- ["Aquamarine", "Inert / weak greenish", "Fe²⁺/Fe³⁺", "High", "No significant Cr"]
- ["Blue sapphire (natural)", "Greenish / inert", "Fe²⁺–Ti⁴⁺ CT", "High", "No Cr; Fe–Ti charge transfer colouring"]
- ["Blue spinel (natural)", "Greenish / inert", "Fe", "High", "Fe-coloured; no Cr"]
- ["Blue spinel (Verneuil synthetic, cobalt-coloured)", "Red", "Co", "Highest", "Cobalt transmits red window strongly diagnostic for synthetic cobalt spinel"]
- ["Blue spinel (Verneuil synthetic, cobalt-coloured)", "Red", "Co", "Highest", "Cobalt transmits red window strongly diagnostic for synthetic cobalt spinel"]
- ["Blue glass (cobalt-coloured)", "Red", "Co", "Highest", "Same cobalt transmission; separates from blue sapphire"]
- ["Green tourmaline (Fe/Mn dominant)", "Greenish / inert", "Fe/Mn", "High", "No significant Cr"]
- ["Chrome tourmaline", "Red", "Cr³⁺", "High", "Strong positive; resembles emerald reaction"]
- ["Tsavorite (V³⁺/Cr³⁺ grossular)", "Inert to weak greenish", "V³⁺", "Moderate", "V³⁺ absorption differs from Cr³⁺; often inert"]
- ["Demantoid garnet (Cr-bearing, Russian)", "Red", "Cr³⁺", "High", "Cr³⁺ colouring in most demantoid"]
- ["Jadeite natural green (Cr-coloured, imperial)", "Weak greenish to inert", "Cr³⁺", "Low–moderate", "Lower Cr content than emerald; often borderline"]
- ["Jadeite dyed green (Type C)", "Red", "Organic dye", "High", "Dye absorbs in yellow-green window; red transmission is diagnostic for dyed jade"]
- ["Jadeite natural green (Cr-coloured, imperial)", "Weak greenish to inert", "Cr³⁺", "Low–moderate", "Lower Cr content than emerald; often borderline"]
- ["Jadeite dyed green (Type C)", "Red", "Organic dye", "High", "Dye absorbs in yellow-green window; red transmission is diagnostic for dyed jade"]
- ["Cobalt glass-filled sapphire", "Strong red", "Co (filler)", "High", "Bexfield 2020 reported this as a new diagnostic technique for detecting cobalt-glass filling (DOI: 10.15506/jog.2020.37.4.357)"]

- title: Vanadium-Coloured Stones
callout:
type: warning
title: Vanadium (V³⁺) Does Not React Like Chromium
text: |
Some stones coloured by vanadium (V³⁺) including many Brazilian emeralds and certain
hydrothermal synthetic emeralds may give a **weak or inert** reaction under the CCF.
Some stones coloured by vanadium (V³⁺) including many Brazilian emeralds and certain
hydrothermal synthetic emeralds may give a **weak or inert** reaction under the CCF.
This is because V³⁺ absorption bands differ from Cr³⁺ and do not match the CCF's
transmission windows in the same way.

A weak or inert reaction from a green stone does **not** rule out emerald it may
A weak or inert reaction from a green stone does **not** rule out emerald it may
simply indicate vanadium rather than chromium colouring. Confirm with the spectroscope.

- title: Limitations
content: |
The CCF has important limitations that must be understood before relying on a result:

- **Incandescent light only** daylight or LED sources shift the colour balance and can
- **Incandescent light only** daylight or LED sources shift the colour balance and can
produce false inert reactions on moderately Cr-coloured stones.
- **Does not distinguish natural from synthetic** both react red if Cr is the chromophore.
- **Does not distinguish natural from synthetic** both react red if Cr is the chromophore.
Anderson (1966) stated this explicitly; it remains the most commonly misunderstood aspect
of the instrument.
- **Modern Cr-doped hydrothermal synthetics** (Biron, Tairus) may give reactions
indistinguishable from high-quality Colombian naturals.
- **Vanadium-coloured emeralds** may give a weaker or inert reaction not all green beryl
- **Vanadium-coloured emeralds** may give a weaker or inert reaction not all green beryl
that is called "emerald" is Cr-dominated.
- **Low-quality lighting** (fluorescent strip) degrades result reliability; repeat under
tungsten if ambiguous.
Expand All @@ -144,4 +144,4 @@ sections:
- Read, P. G. (ed.). *Gems* 7th ed., chapter "The hand lens, microscope and Chelsea filter."
DOI: 10.4324/9780080507224-18 [VERIFIED]
- Nassau, K. (2001). *The Physics and Chemistry of Color* (2nd ed.). Wiley.
ISBN: 978-0-471-39106-7 [PARTIALLY_SUPPORTED ISBN only, no DOI]
ISBN: 978-0-471-39106-7 [PARTIALLY_SUPPORTED ISBN only, no DOI]
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