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The database defines the CL_FCC phase as:

 PHASE CL_FCC % 2 1 1 >
Early metastable Mg-Si Co-Cluster. [REF:C31,C32]
Solely use in thermokinetic precipitation simulations (comment pov23).
>> 4 !

so when you do

possible_phases = database.phases.keys()

it includes this phase in the set of phases PyCalphad considers, even though I don't think the database author intended that to be used when computing normal phase equilibria. If I change your definition of possible_phases, I get the following phase diagram.

# possible_phases = database.phases.keys()
possible_phases = list(set(database.phases.keys()) - {"CL_FCC"})

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Answer selected by ChRen95
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